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材料工程  2018, Vol. 46 Issue (5): 1-10    DOI: 10.11868/j.issn.1001-4381.2016.001341
  石墨烯专栏 本期目录 | 过刊浏览 | 高级检索 |
拉曼光谱表征石墨烯结构的研究进展
郝欢欢1, 刘晶冰1, 李坤威2, 汪浩1, 严辉1
1. 北京工业大学 材料科学与工程学院, 北京 100124;
2. 中国标准化研究院, 北京 100142
Research Progress on Characterization of Graphene Structure by Raman Spectroscopy
HAO Huan-huan1, LIU Jing-bing1, LI Kun-wei2, WANG Hao1, YAN Hui1
1. College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China;
2. China National Institute of Standardization, Beijing 100142, China
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摘要 石墨烯是一种只有一个原子层的二维原子晶体,它是构成零维富勒烯、一维碳纳米管和三维石墨等其他碳同素异形体的基本结构单元,具有很多独特的电子及力学性能,因而吸引了化学、材料及其他领域众多科学家的高度关注。拉曼光谱作为一种灵敏便捷的表征方法,在石墨烯的研究中起到重要的作用。该综述总结了近年来拉曼光谱在石墨烯表征中的应用,在对单层石墨烯的典型特征峰作详细介绍的基础上,通过对拉曼谱图中D峰、G峰和2D峰的强度、位置和半峰宽变化情况的分析,可以快速而准确地表征出石墨烯的层数,并可以对石墨烯的堆垛方式、边缘手性和掺杂程度进行判定。同时,也系统地分析了在石墨烯制备与测试过程中基底、掺杂、温度和激光功率等因素对拉曼谱图中D峰、G峰和2D峰的强度、位置和半峰宽的影响。
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郝欢欢
刘晶冰
李坤威
汪浩
严辉
关键词 石墨烯拉曼光谱层数效应堆垛方式边缘手性掺杂程度    
Abstract:Graphene is a kind of two-dimensional atomic crystal with one atomic layer, which is the basic structure unit of other dimensions of graphite materials, such as zero dimensional fullerenes, one-dimensional carbon nanotubes and three-dimensional graphite. Graphene has a lot of unique electronic and mechanical properties, which have attracted high attention of many scientists in the field of chemistry, materials and other fields. Raman spectroscopy as a sensitive and convenient characterization method, has played a very important role in the study of graphene. Raman spectroscopy is an integral part of graphene research. The application of Raman spectroscopy in graphene characterization in recent years is reviewed in this paper. The characteristic peak of monolayer graphene was first intnduced. Then, through the analysis of the changes of D peak, G peak and 2D peak intensity, position and half peak width of Raman spectra, the number of graphene layers can be quickly and accurately characterized, as well as, the stacking orders, edge chirality and doping degree of graphene were defined. At the same time, the effects of substrate, doping, temperature and laser power on the intensity, position and half width of D peak, G peak and 2D peak of Raman spectra in the process of preparing graphene were also systematically analyzed.
Key wordsgraphene    Raman spectroscopy    layer effect    stacking order    edge chirality    doping degree
收稿日期: 2016-09-10      出版日期: 2018-05-16
中图分类号:  O657.37  
通讯作者: 刘晶冰(1978-),女,副教授,博士研究生,从事材料化学研究,联系地址:北京市北京工业大学材料楼229室(100124),E-mail:liujingbing@bjut.edu.cn     E-mail: liujingbing@bjut.edu.cn
引用本文:   
郝欢欢, 刘晶冰, 李坤威, 汪浩, 严辉. 拉曼光谱表征石墨烯结构的研究进展[J]. 材料工程, 2018, 46(5): 1-10.
HAO Huan-huan, LIU Jing-bing, LI Kun-wei, WANG Hao, YAN Hui. Research Progress on Characterization of Graphene Structure by Raman Spectroscopy. Journal of Materials Engineering, 2018, 46(5): 1-10.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.001341      或      http://jme.biam.ac.cn/CN/Y2018/V46/I5/1
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