Effect of Heat Treatment on Microstructures and Mechanical Properties of Extruded GWZ661 Alloy
ZHEN Rui1,2, SUN Yang-shan2, WANG Zhang-zhong1, FANG Xin-xian1, SHI Wei1
1. Department of Materials Science and Engineering,Nanjing Institute of Technology, Nanjing 211167,China;
2. Jiangsu Key Lab of Advanced Metallic Materials,School of Materials Engineering,Southeast University,Nanjing 211189,China
Abstract:A quaternary alloy with composition of Mg-6Gd-6Y-1Zn (mass fraction/%) was prepared by conventional casting and extrusion. The microstructure and aging behavior of the alloy were investigated. The results showed that the as-cast microstructure of the alloy consisted of the α-Mg matrix, Mg24(GdYZn)5 eutectic and Mg12Y1Zn1 phase. After extrusion the Mg12Y1Zn1 phase were stretched along the direction of extrusion, and the 14H-LPSO phase distributed between Mg12Y1Zn1 strips. Solid solution treatment at high temperature above 500℃ resulted in the dissolution of Mg12Y1Zn1 phase into the matrix and increase of the 14H-LPSO phase. When solution treated alloys was aged at temperature of 225℃ (T6 treatment), the 14H-LPSO phase and β' precipitated appear in microstructure. Aging of as extruded alloys (T5 treatment) also caused the formation of β' precipitates,however the volume fraction of 14H-LPSO phase was lower than that in specimens after T6 treatment. High tensile strength combined with good ductility was obtained from the alloy after T6-aging.
甄睿, 孙扬善, 王章忠, 方信贤, 石卫. 热处理对GWZ661变形镁合金组织与性能的影响[J]. 材料工程, 2012, 0(12): 39-44.
ZHEN Rui, SUN Yang-shan, WANG Zhang-zhong, FANG Xin-xian, SHI Wei. Effect of Heat Treatment on Microstructures and Mechanical Properties of Extruded GWZ661 Alloy. Journal of Materials Engineering, 2012, 0(12): 39-44.
[1] KAWAMURA Y,HAYASHI K,INOUE A,et al. Rapidly solidified powder metallurgy Mg97Zn1Y2 alloys with excellent tensile yield strength above 600MPa[J]. Materials Transaction,2001,42(7):1172-1176.[2] LUO Z P,ZHANG S Q. High-resolution electron microscopy on the X-Mg12ZnY phase in a high strength Mg-Zn-Zr-Y magnesium alloy[J]. Journal of Materials Science Letters,2000,19(9):813-815.[3] ABE E,KAWAMURA Y,HAYASHI K,et al. Long-period ordered structure in a high-strength nanocrystalline Mg-1at%Zn-2at%Y alloy studied by atomic-resolution Z-contrast STEM[J]. Acta Materialia,2002,50:3845-3857.[4] ITOI T,SEIMIYA T,KAWAMURA Y,et al. Long period stacking structures observed in Mg97Zn1Y2 alloy[J]. Scr Mater,2004,51(2):107-111.[5] YAMASAKI M, ANAN T, YOSHIMOTO S, et al. Mechanical properties of warm-extruded Mg-Zn-Gd alloy with coherent 14H long periodic stacking ordered structure precipitate[J]. Scr Mater,2005,53(7):799-803.[6] KAWAMURA Y,YAMASAKI M. Formation and mechanical properties of Mg97Zn1RE2 alloys with long-period stacking ordered structure[J]. Materials Transaction,2007,48(11):2986-2992.[7] YAMASAKI M, SASAKI M, NISHIJIMA M, et al. Formation of 14H long period stacking ordered structure and profuse stacking faults in Mg-Zn-Gd alloys during isothermal aging at high temperature[J]. Acta Mater,2007,55(20):6798-6805.[8] HONMA T,OHKUBO T,KAMADO S,et al. Effect of Zn additions on the age-hardening of Mg-2.0Gd-1.2Y-0.2Zr alloys[J].Acta Mater,2007,55(12):4137-4150.[9] GAO Y,WANG Q D,GU J H,et al. Comparison of microstructure in Mg-10Y-5Gd-0.5Zr and Mg-10Y-5Gd-2Zn-0.5Zr alloys by conventional casting[J]. Journal of Alloys and Compounds,2009,477(1-2):374-378.[10] WU Y J, ZENG X Q, LIN D L, et al. The microstructure evolution with lamellar 14H-type LPSO structure in an Mg96.5Gd2.5Zn1 alloy during solid solution heat treatment at 773K[J]. Alloy Compd,2009,477(1-2):193-197.[11] LIU K, ZHANG J H, SU G H, et al. Influence of Zn content on the microstructure and mechanical properties of extruded Mg-5Y-4Gd-0.4Zr alloy[J]. Alloy Compd,2009,481(1-2):811-818.[12] ZHU Y M,MORTON AJ,NIE J F. The 18R and 14H long-period stacking ordered structures in Mg-Y-Zn alloys[J]. Acta Materialia,2010,58(8):2936-2947.[13] ZHANG S, YUAN G Y, LU C, et al. The relationship between (Mg,Zn)3RE phase and 14H-LPSO phase in Mg-Gd-Y-Zn-Zr alloys solidified at different cooling rates[J]. Alloy Compd,2011, 509(8):3515-3521.[14] YANG Z, LI J P, GUO Y C, et al. Precipitation process and effect on mechanical properties of Mg-9Gd-3Y-0.6Zn-0.5Zr alloy[J].Mater Sci Eng:A,2007,454-455:274-280.[15] ZHENG L, LIU C M, WAN Y C, et al. Microstructures and mechanical properties of Mg-10Gd-6Y-2Zn-0.6Zr(wt.%) alloy[J].Alloy Compd,2011,509(35):8832-8839.[16] LIU K, ROKHLIN L L, ELKIN F M, et al. Effect of ageing treatment on the microstructures and mechanical properties of the extruded Mg-7Y-4Gd-1.5Zn-0.4Zr alloy[J].Mater Sci Eng:A,2010,527(3):828-834.[17] LIU X B, CHEN R S, HAN E H. Effects of ageing treatment on microstructures and properties of Mg-Gd-Y-Zr alloys with and without Zn additions[J]. Alloy Compd,2008,465(1-2):232-238.[18] ZHEN R,SUN Y S,BAI J,et al. Microstructures and mechanical properties of Mg-(11-13)Gd-1Zn alloys[J]. Acta Metall Sin, 2012,48(6):733-738.[19] 陈振华,周涛,陈鼎. 快速凝固性能镁合金研究进展——长周期堆垛有序结构镁合金[J].材料导报,2007,21(11):50-55.[20] 高岩. Mg-Y-Gd-Zn-Zr镁合金组织、性能及其蠕变行为研究.上海:上海交通大学,2009.