1. School of Materials Science and Engineering, Nanchang University, Nanchang, 330031, China; 2. School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang, 330063, China
Abstract:Effects of P addition on the properties of Sn-9Zn eutectic lead-free solder alloy have been studied.The results show that P could significantly improve the wettability of Sn-9Zn to Cu because P addition can decrease the content of oxygen in Sn-Zn alloy by the application of Secondary Ion Mass Spectrometry(SIMS) analysis.P addition enhances the creep strength of the Sn-9Zn bulk materials and the shear strength of Sn-9Zn/Cu joints,while decreases its ductility.No significant change in the interfacial structure of Sn-9Zn/Cu joints was observed by addition of P.The mechanisms were also discussed.
[1] ABTEW M,SELVADURAY G.Lead-free solders in Microelectronics[J].Materials Science and Engineering,2000,27:95-141. [2] VAYNMAN S,FINE M E.Development of fluxes for lead-free solders containing zinc[J].Scripta Materialia,1999,41(12):1269-1271. [3] 金泉军,周浪,孙韡,等.Sn-9Zn无铅电子钎料助焊剂研究[J].电子元件与材料,2005,24(5):27-29. [4] WU C M L,LAW C M T,YU D Q,etal.The wettability and microstructure of Sn-Zn-RE alloys[J].Journal of Electronic Materials 2003,32(2):63-69. [5] KIM Y S,KIM K S,HWANG C W,etal.Effect of composition and cooling rate on microstructure and tensile properties of Sn-Zn-Bi alloys[J].Journal of Alloys and Compounds,2003,352:237-245. [6] LIN K L,WANG Y C.Wetting interaction of Pb-free SnZnAl solders on metal plated substrate[J].Journal of Electronic Materials,1998,27(11):1205-1210. [7] PRASAD L C,XIE Y,MIKULA A.Lead free solder materials In-Sn-Zn system[J].Journal of Non-Crystalline Solids,1999,250-252:316-320. [8] YU D Q,XIE H P,WANG L.Investigation of interfacial microstructure and wetting property of newly developed Sn-Zn-Cu solders with Cu substrate[J].Journal of Alloys and Compounds,2004,385:119-125. [9] 刘月梅,黄亚飞.ACR管材专用磷脱氧铜圆锭表面质量改进[J].特种铸造及有色合金,2003,(6):60-61. [10] 廖福平,周浪,黄惠珍,等.无铅电子钎料合金蠕变性能研究[J].电子元件与材料,2005,24(4):65-67. [11] 黄希祜.钢铁冶金原理[M].第3版.北京:冶金工业出版社,2002. [12] MASSALSKI T B.Binary alloy phase diagrams[M].Ohio:ASM International,1996. [13] SONG H G,MORRIS Jr J W,HUA F.The creep properties of lead-free solder joints[J].JOM,2002,54(6):30-32. [14] WADE N,WU K,KUNII J,etal.Effect of Cu,Ag and Sb on the creep-rupture strength of lead-free solder alloys[J].Journal of Electronic Materials,2001,30(9):1228-1231. [15] CHOI S,LEE J G,GUO F,etal.Creep properties of Sn-Ag solder joints containing intermetallic particles[J].JOM,2001,53(6):22-26. [16] 胡壮麒,孙文儒,郭守仁,等.微量元素磷在铁镍基变形高温合金中的作用[J].中国有色金属学报,2001,11(6):947-959. [17] 宋洪伟,郭守仁,卢德忠,等.磷对IN718合金蠕变性能的影响[J].材料研究学报,1999,13(5):523-526. [18] HUANG H Z,WEI X Q,ZHOU L,etal.Effects of Zn concentration on wettability of Sn-Zn alloy on Cu and the interfacial microstructure between Sn-Zn alloy and Cu[J].Acta Metall Sin (Engl Lett),2006,19(4):251-257.