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材料工程  2017, Vol. 45 Issue (6): 138-146    DOI: 10.11868/j.issn.1001-4381.2014.001463
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锂离子电池Sn基负极材料研究进展
马昊, 刘磊, 苏杰, 路雪森
河北大学 电子信息工程学院, 河北 保定 071002
Research Progress on Tin-based Anode Materials for Lithium Ion Batteries
MA Hao, LIU Lei, SU Jie, LU Xue-sen
College of Electronic and Information Engineering, Hebei University, Baoding 071002, Hebei, China
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摘要 综述了锂电池用Sn基负极材料近年来的发展现状,着重讨论了Sn基氧化物、Sn基复合氧化物、Sn基合金以及Sn基复合物等Sn基负极材料的制备方法、性能特点、存在问题以及改善途径。指出单一方法难以全面改善Sn基负极材料的性能,综合运用结构优化、成分控制、掺入基质以及优化还原剂、黏合剂和电解质添加剂等途径才能更好地改善Sn基负极材料的电化学性能。最后,对Sn基负极材料的研究趋势进行了展望,并指出以石墨烯为基质的Sn基复合材料是今后研究的重要方向。
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马昊
刘磊
苏杰
路雪森
关键词 锂离子电池Sn基负极材料电化学性能    
Abstract:The status of development on anode materials for lithium ion batteries in recent years were summarized,focusing on the preparation methods, characteristics, problems and improvement ways of tin-based oxide, tin-based composite oxide, tin-based alloy and tin-based composite, respectively. It indicates that a single approach is difficult to comprehensively improve the performance of the tin-based materials, and an integrated application of various methods such as optimizing the structure, controlling components of the materials, incorporating matrix into the tin-based materials as well as optimizing the reducing agent, binder and electrolyte additives can improve the electrochemical performance of the anode materials. Finally, the research trend in tin-based anode materials is prospected,and also it is pointed out that the tin-based composite materials with graphene as matrix may be one of the most promising research directions for future.
Key wordslithium ion battery    tin-based anode material    electrochemical performance
收稿日期: 2014-12-04      出版日期: 2017-06-20
中图分类号:  TM912  
通讯作者: 刘磊(1979-),男,副教授,博士,主要从事锂离子电池用正极材料与电解质材料的研究工作,联系地址:河北省保定市五四东路甲180号河北大学电子信息工程学院(071002),E-mail:thesisliu@163.com     E-mail: thesisliu@163.com
引用本文:   
马昊, 刘磊, 苏杰, 路雪森. 锂离子电池Sn基负极材料研究进展[J]. 材料工程, 2017, 45(6): 138-146.
MA Hao, LIU Lei, SU Jie, LU Xue-sen. Research Progress on Tin-based Anode Materials for Lithium Ion Batteries. Journal of Materials Engineering, 2017, 45(6): 138-146.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2014.001463      或      http://jme.biam.ac.cn/CN/Y2017/V45/I6/138
[1] IDOTA Y,KUBOTA T,MATSUFUJI A,et al.Tin-based amorphous oxide:a high-capacity lithium-ion-storage material[J].Science,1997,276(5317):1395-1397.
[2] TATSUMA T,TAGUCHI M,OYAMA N.Inhibition effect of covalently cross-linked gel electrolytes on lithium dendrite formation[J].Electrochimica Acta,2001,46(8):1201-1205.
[3] COURTNEY I A,DAHN J R.Electrochemical and in situ X-ray diffraction studies of the reaction of lithium with tin oxide composites[J].Journal of the Electrochemical Society,1997,144(6):2045-2052.
[4] MEGAHED S,SCROSATI B.Lithium-ion rechargeable batteries[J].Journal of Power Sources,1994,51(1-2):79-104.
[5] BESENHARD J O,YANG J,WINTER M.Will advanced lithium-alloy anodes have a chance in lithium-ion batteries?[J].Journal of Power Sources,1997,68(1):87-90.
[6] LI J,LI H,WANG Z,et al.The interaction between SnO anode and electrolytes[J].Journal of Power Sources,1999,81-82(9):346-451.
[7] HARRELD J H,SAKAMOTO J,DUNN B.Non-hydrolytic sol-gel synthesis and electrochemical characterization of tin-based oxide aerogels[J].Journal of Power Sources,2003,115(1):19-26.
[8] MUKAIBO H,SUMI T,YOKOSHIMA T,et al.Electrodeposited Sn-Ni alloy film as a high capacity anode material for lithium-ion secondary batteries[J].Electrochemical and Solid-State Letters,2003,6(10):218-220.
[9] KAMALI A R,FRAY D J.Tin-based materials as advanced anode materials for lithium ion batteries:a review[J].Reviews on Advanced Materials Science,2011,27(1):14-24.
[10] WINTER M,BESENHARD J O.Electrochemical lithiation of tin and tin-based intermetallics and composites[J].Electrochimica Acta,1999,45(1-2):31-50.
[11] COURTENY I A,DAHN J R.Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass[J].Journal of the Electrochemical Society,1997,144(9):2943-2948.
[12] FU Y,MA R,SHU Y,et al.Preparation and characterization of SnO2/carbon nanotube composite for lithium ion battery applications[J].Materials Letters,2009,63(22):1946-1948.
[13] WEN Z,ZHENG F,LIU K.Synthesis of porous SnO2 nanospheres and their application for lithium-ion battery[J].Materials Letters,2012,68(2):469-471.
[14] COURTEL F M,BARANOVA E A,ABU-LEBDEH Y,et al.In situ polyol-assisted synthesis of nano-SnO2/carbon composite materials as anodes for lithium-ion batteries[J].Journal of Power Sources,2010,195(8):2355-2361.
[15] XU M,ZHAO M,WANG F,et al.Facile synthesis and electrochemical properties of porous SnO2 micro-tubes as anode material for lithium-ion battery[J].Materials Letters,2010,64(8):921-923.
[16] ZHOU X,ZOU Y,YANG J.Carbon supported tin-based nanocomposites as anodes for Li-ion batteries[J].Journal of Solid State Chemistry,2013,198(2):231-237.
[17] LI Z,WU G,LIU D,et al.Graphene enhanced carbon-coated tin dioxide nanoparticles for lithium-ion secondary batteries[J].Journal of Materials Chemistry A,2014,2(20):7471-7477.
[18] 王亚丽,于晶,李榕,等.锂离子电池负极材料SnO2的形貌调控合成[J].化学进展,2012,24(11):2132-2142. WANG Y L,YU J,LI R,et al.Morphology-controlled synthesis of SnO2 as lithium ion batteries anode materials[J].Progress in Chemistry,2012,24(11):2132-2142.
[19] LIN Y M,NAGARALE R K,KLAVETTER K C,et al.SnO2 and TiO2-supported-SnO2 lithium battery anodes with improved electrochemical performance[J].Journal of Materials Chemistry,2012,(22):11134-11139.
[20] 吕成学,褚嘉宜,翟玉春,等.锡基复合氧化物负极材料的研究[J].东北师大学报(自然科学版),2006,36(4):66-70. LV C X,CHU J Y,ZHAI Y C,et al.Study on the tin-based composite oxide as anode materials for lithium ion batteries[J].Journal of Northeast Normal University(Natural Science Edition),2006,36(4):66-70.
[21] LEE S H,JEE S H,KANG S L,et al.Enhanced cycling performance in heat-treated tin-based composite oxide anode for lithium-ion batteries[J].Electrochimica Acta,2013,87(1):905-911.
[22] ZHOU Y,JO C,LEE J,et al.Development of novel mesoporous C-TiO2-SnO2 nanocomposites and their application to anode materials in lithium ion secondary batteries[J].Microporous & Mesoporous Materials,2012,151(11):172-179.
[23] YU Y,CHEN C H,SHI Y.A tin-based amorphous oxide composite with a porous,spherical,multideck-cage morphology as a highly reversible anode material for lithium-ion batteries[J].Advanced Materials,2007,19(7):993-997.
[24] YANG H,SONG T,LEE S,et al.Tin indium oxide/graphene nanosheet nanocomposite as an anode material for lithium ion batteries with enhanced lithium storage capacity and rate capability[J].Electrochimica Acta,2013,91(3):275-281.
[25] 何则强,熊利芝,麻明友,等.新型锂离子电池CaSnO3负极材料的湿化学制备与电化学性能[J].无机化学学报,2005,21(9):1311-1315. HE Z Q,XIONG L Z,MA M Y,et al.Electrochemical characterization of novel CaSnO3 anode material for lithium ion batteries prepared by wet chemical route[J].Chinese Journal of Inorganic Chemistry,2005,21(9):1311-1315.
[26] 褚道葆,李建,袁希梅,等.锂离子电池Sn基合金负极材料[J].化学进展,2012,24(8):1466-1473. CHU D B,LI J,YUAN X M,et al.Tin-based alloy anode materials for lithium ion batteries[J].Progress in Chemistry,2012,24(8):1466-1473.
[27] DUA Z,ZHANG S,XINGA Y,et al.Nanocone-arrays supported tin-based anode materials for lithium-ion battery[J].Journal of Power Sources,2011,196(22):9780-9785.
[28] 冯立明,魏雪.Sn-Cu合金电沉积制备工艺及结构研究[J].材料工程,2010,(9):29-32. FENG L M,WEI X.Preparation and structure of Sn-Cu alloys by electrochemical deposition[J].Journal of Materials Engineering,2010,(9):29-32.
[29] ZHANG W J.A review of the electrochemical performance of alloy anodes for lithium-ion batteries[J].Journal of Power Sources,2011,196(1):13-24.
[30] WANG L,KITAMURA S,OBATA K,et al.Multilayered Sn-Zn-Cu alloy thin-film as negative electrodes for advanced lithium-ion batteries[J].Journal of Power Sources,2006,141(2):286-292.
[31] JIANG D,MA X,FU Y.High-performance Sn-Ni alloy nanorod electrodes prepared by electrodeposition for lithium ion rechargeable batteries[J].Journal of Applied Electrochemistry,2012,42(8):555-559.
[32] WANG Y X,HUANG L,CHANG Y Q,et al.Fabrication and electrochemical properties of the Sn-Ni-P alloy rods array electrode for lithium-ion batteries[J].Electrochemistry Communications,2010,12(9):1226-1229.
[33] 何见超,赵海雷,王捷,等.纳米Co-Sn合金负极材料的制备和电化学性能[J].稀有金属材料与工程,2011,40(2):452-456. HE J C,ZHAO H L,WANG J,et al.Preparation and electrochemical properties of nano-sized Co-Sn alloy anode for lithium ion batteries[J].Rare Metal Materials and Engineering,2011,40(2):452-456.
[34] 刘欣,解晶莹,赵海雷,等.锂离子电池Sn30Co30C40三元合金负极材料的制备与性能研究[J].化学学报,2013,71(7):1011-1016. LIU X,XIE J Y,ZHAO H L,et al.Synthesis and properties of Sn30Co30C40 ternary alloy anode material for lithium ion battery[J].Acta Chimica Sinica,2013,71(7):1011-1016.
[35] 周稳,潘勇,雷斯新,等.分步电沉积法制备Cu-Sn-Sb合金负极材料[J].电源技术,2015,39(11):2351-2354. ZHOU W,PAN Y,LEI S X,et al.Preparation of Cu-Sn-Sb alloy anode by layered electrodeposition[J].Chinese Journal of Power Sources,2015,39(11):2351-2354.
[36] TABUCHI T,HOCHGATTERER N,OGUMI Z,et al.Ternary Sn-Sb-Co alloy film as new negative electrode for lithium-ion cells[J].Journal of Power Sources,2009,188(2):552-557.
[37] YANG H,LI L.Tin-indium/graphene with enhanced initial coulombic efficiency and rate performance for lithium ion batteries[J].Journal of Alloys & Compounds,2014,584:76-80.
[38] TRIFONOVA A,WACHTLER M,WINTER M,et al.Sn-Sb and Sn-Bi alloys as anode materials for lithium-ion batteries[J].Ionics,2002,8(5):321-328.
[39] ZHANG R,UPRETI S,WHITTINGHAM M S.Tin-iron based nano-materials as anodes for Li-ion batteries[J].Journal of Electrochemical Society,2011,158(12):1498-1504.
[40] JANG J Y,PARK G,LEE S M,et al.Functional electrolytes enhancing electrochemical performance of Sn-Fe-P alloy as anode for lithium-ion batteries[J].Electrochemistry Communications,2013,35(10):72-75.
[41] GNANAMUTHU RM,CHANG W L.Electrodeposition and electrochemical investigation of thin film Sn-Co-Ni alloy anode for lithium-ion batteries[J].Materials Science & Engineering B,2011,176(16):1329-1332.
[42] 周冠蔚,何雨石,杨晓伟,等.石墨烯及其复合材料在锂离子电池中的应用[J].化学进展,2012,24(2):235-245. ZHOU G W,HE Y S,YANG X W,et al.Graphene-containing composite materials for lithium-ion batteries applications[J].Progress in Chemistry,2012,24(2):235-245.
[43] 李健,官亦标,傅凯,等.碳纳米管与石墨烯在储能电池中的应用[J].化学进展,2014,26(7):1233-1243. LI J,GUAN Y B,FU K,et al.Applications of carbon nanotubes and graphene in the energy storage batteries[J].Progress in Chemistry,2014,26(7):1233-1243.
[44] 闻雷,刘成名,宋仁升,等.石墨烯材料的储锂行为及其潜在应用[J].化学学报,2014,72(3):333-344. WEN L,LIU C M,SONG R S,et al.Lithium storage characteristics and possible applications of graphene materials[J].Acta Chimica Sinica,2014,72(3):333-344.
[45] YUE W,YANG S,LIU Y,et al.A facile synthesis of mesoporous graphene-tin composites as high-performance anodes for lithium-ion batteries[J].Materials Research Bulletin,2013,48(4):1575-1580.
[46] SONG W,HOU X,WANG X,et al.Tin microspheres grown on carbon cloth as binder-free integrated anode for high capacity lithium storage[J].Energy Technology,2014,2(4):370-375.
[47] BRESSER D,MUELLER F,BUCHHOLZ D,et al.Embedding tin nanoparticles in micron-sized disordered carbon for lithium-and sodium-ion anodes[J].Electrochimica Acta,2014,128(5):163-171.
[48] 季晶晶,王红强,张经济,等.水热法制备Sn/C球复合材料及其电化学性能[J].粉末冶金材料科学与工程,2013,18(4):599-603. JI J J,WANG H Q,ZHANG J J,et al.Electrochemical performance of Sn/C ball composite materials prepared by hydrothermal method[J].Materials Science and Engineering of Powder Metallurgy,2013,18(4):599-603.
[49] 王刚,高明霞,唐渊波,等.超细Sn和SnO2与碳复合的锂离子电池负极材料的制备及其电化学性能[J].材料科学与工程学报,2012,30(4):556-605. WANG G,GAO M X,TANG Y B,et al.Synthesis and electrochemical properties of ultrafine Sn and SnO2 dispersed carbon matrix composite anode materials for Li-ion batteries[J].Journal of Materials Science & Engineering,2012,30(4):556-605.
[50] LI Y,TU J P,WU H M,et al.Mechanochemical synthesis and electrochemical properties of nanosized SnS as an anode material for lithium ion batteries[J].Materials Science & Engineering B,2006,128(1):75-79.
[51] LI Y,TU J P,HUANG X H,et al.Nanoscale SnS with and without carbon-coatings as an anode material for lithium ion batteries[J].Electrochimica Acta,2006,52(3):1383-1389.
[52] LI Y,TU J P,HUANG X H,et al.Net-like SnS/carbon nanocomposite film anode material for lithium ion batteries[J].Electrochemistry Communications,2007,9(1):49-53.
[53] LEI D,ZHANG M,QU B,et al.Hierarchical tin-based microspheres:solvothermal synthesis,chemical conversion,mechanism and application in lithium ion batteries[J].Electrochimica Acta,2013,106(9):386-391.
[54] 白红美,陶占良,程方益,等.锂离子电池锡薄膜负极制备及电化学性能研究[J].电化学,2011,17(1):43-47. BAI H M,TAO Z L,CHENG F Y,et al.Preparation and electrochemical properties of Sn thin film as anode materials for lithium-ion batteries[J].Electrochemistry,2011,17(1):43-47.
[55] 刘欣,赵海雷,解晶莹,等.锂离子电池高比容量负极用粘结剂[J].化学进展,2013,25(8):1401-1410. LIU X,ZHAO H L,XIE J Y,et al.Polymer binders for high capacity electrode of lithium-ion battery[J].Progress in Chemistry,2013,25(8):1401-1410.
[56] CHOU S L,GAO X W,WANG J Z,et al.Tin/polypyrrole composite anode using sodium carboxymethyl cellulose binder for lithium-ion batteries[J].Dalton Transactions,2011,40(48):12801-12807.
[57] XUN S,SONG X,BATTAGLIA V,et al.Conductive polymer binder-enabled cycling of pure tin nanoparticle composite anode electrodes for a lithium-ion battery[J].Journal of the electrochemical Society,2013,160(6):849-855.
[58] LI J,LE D B,FERGUSON P P,et al.Lithium polyacrylate as a binder for tin-cobalt-carbon negative electrodes in lithium-ion batteries[J].Electrochimica Acta,2010,55(8):2991-2995.
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