Please wait a minute...
 
材料工程  2014, Vol. 0 Issue (10): 71-74    DOI: 10.11868/j.issn.1001-4381.2014.10.013
  材料与工艺 本期目录 | 过刊浏览 | 高级检索 |
棕榈酸-十六醇/二氧化硅相变储能材料的低热固相合成与表征
马烽, 秦岩, 陆丰艳, 王晓燕
齐鲁工业大学 化学与制药工程学院, 济南 250353
Synthesis and Characterization of Palmitic Acid-hexadecanol/SiO2 Phase Change Energy Storage Materials by Solid-state Chemical Reaction at Low Temperature
MA Feng, QIN Yan, LU Feng-yan, WANG Xiao-yan
School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, China
全文: PDF(1581 KB)   HTML()
输出: BibTeX | EndNote (RIS)      
摘要 以棕榈酸-十六醇(PA-HD)低共熔物为相变材料,硅酸钠为硅源,通过低热固相化学合成方法制备出棕榈酸-十六醇/二氧化硅相变储能材料(PA-HD/SiO2)。利用FT-IR,ESEM,DSC,融化-凝固曲线测试对材料的结构、形貌和性能进行表征。结果表明:当相变材料与硅酸钠质量比为2:1时可实现相变材料的有效包覆,PA-HD/SiO2相变焓值和相变温度分别为102.35J·g-1和53.69℃,该定形复合相变材料具有良好的传热性能,因为包覆作用,使得相变材料的相变温度有所升高。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
马烽
秦岩
陆丰艳
王晓燕
关键词 棕榈酸十六醇二氧化硅固相合成反应相变储能    
Abstract:Palmitic acid-hexadecanol/silicon dioxide (PA-HD/SiO2) phase change energy storage materials were prepared by low-temperature solid-state reaction using the eutectic mixture of palmitic acid and hexadecanol(PA-HD) as phase change component and sodium silicate as silicon source. The structure,morphology,and thermal performance of the composite were characterized by Fourier transform infrared spectrometer (FT-IR),environmental scanning electron microscopy (ESEM),differential scanning calorimetry (DSC),and the test of melting and solidification process. The results show that when the ratio of mass fraction between phase change component and sodium silicate is 2,the eutectic mixture of palmitic acid and hexadecanol are effectively imbedded into the net of silicon dioxide by low-temperature solid-state reaction. The latent heat and melting temperature of the composite are 102.35J·g-1 and 53.69℃,respectively,and the composite has good thermal conductivity. Furthermore,the phase transition temperature of the eutectic mixture is improved owing to the coating effect of silicon dioxide.
Key wordspalmitic acid    hexadecanol    silicon dioxide    solid-state reaction    phase change    energy storage
收稿日期: 2014-04-09     
1:  TB33  
基金资助:山东省科技计划资助项目(2010G0020324)
通讯作者: 马烽(1967-), 男, 教授, 博士, 从事多相传热与化工新材料方面研究工作, 联系地址: 山东省济南市长清区大学路3501号齐鲁工业大学化学与制药工程学院(250353), E-mail: mafengch@163.com     E-mail: mafengch@163.com
引用本文:   
马烽, 秦岩, 陆丰艳, 王晓燕. 棕榈酸-十六醇/二氧化硅相变储能材料的低热固相合成与表征[J]. 材料工程, 2014, 0(10): 71-74.
MA Feng, QIN Yan, LU Feng-yan, WANG Xiao-yan. Synthesis and Characterization of Palmitic Acid-hexadecanol/SiO2 Phase Change Energy Storage Materials by Solid-state Chemical Reaction at Low Temperature. Journal of Materials Engineering, 2014, 0(10): 71-74.
链接本文:  
http://jme.biam.ac.cn/jme/CN/10.11868/j.issn.1001-4381.2014.10.013      或      http://jme.biam.ac.cn/jme/CN/Y2014/V0/I10/71
[1] ZALBA B,MARIN J M,CABEZA L F,et al.Review on thermal energy storage with phase change:materials,heat transfer analysis and applications[J].Appl Therm Eng,2003,23(3):251-283.
[2] MOHAMMED M F,AMAR M K,SIDDIQUE A K,et al.A review on phase change energy storage:materials and applications [J].Energy Convers Manage,2004,45(9-10):1597-1615.
[3] KHUDHAIR M A,FARID M M,SAID A H.A review on energy conservation in building applications with thermal storage by latent heat using phase change materials [J].Energy Convers Manage,2004,45(2):263-275.
[4] KOSCHENZ M,LEHMANN B.Development of a thermally activated ceiling panel with PCM for application in lightweight and retrofitted buildings [J].Energy and Buildings,2004,36 (6):567-578.
[5] SHAZIM A M,TOMMY Y L,SHI Xian,et al.Preparation,characterization and thermal properties of Lauryl alcohol/Kaolin as novel form-stable composite phase change material for thermal energy storage in buildings [J].Applied Thermal Engineering,2013,59(1-2):336-347.
[6] MOHAMMAD M,SARA T L,MEHDI M,et al.Preparation and properties of highly conductive palmitic acid/graphene oxide composites as thermal energy storage materials [J].Energy,2013,58(1):628-634.
[7] DIMAANO M N R,WATANABE T.The capric-lauric acid and pentadecane combination as phase change material for cooling applications [J].Applied Thermal Engineering,2002,22(4):365-377.
[8] 陈中华,肖春香,冯润财.CA-SA分子合金的制备及储热性能研究 [J].应用化工,2008,37(1):1-3.CHEN Zhong-hua,XIAO Chun-xiang,FENG Run-cai.Preparation of CA-SA and its thermal reliability [J].Applied Chemical Industry,2008,37(1):1-3.
[9] 李辉,方贵银.具有多孔基体复合相变储能材料研究 [J].材料科学与工程学报,2003,21(6):842-844.LI Hui,FANG Gui-yin.Study on the thermal energy storage phase change composite material with porous skeleton [J].Journal of Materials Science & Engineering,2003,21(6):842-844.
[10] AHMET S.Form-stable paraffin/high density polyethylene composites as solid-liquid phase change material for thermal energy storage:preparation and thermal properties [J].Energy Convers Manage,2004,45(13-14):2033-2042.
[11] XAVIER P,REGIS O,MAURAN S.Paraffin/porous-graphite-matrix composite as a high and constant power thermal storage material [J].Int J Heat Mass Transfer,2001,44(14):2727-2737.
[12] 马烽,宗学刚,陈明辉,等.月桂酸/二氧化硅复合相变储能材料的制备与性能 [J].材料工程,2010,(4):15-17.MA Feng,ZONG Xue-gang,CHEN Ming-hui,et al.Preparation and properties of lauric acid/SiO2 phase change energy storage composite materials [J].Journal of Materials Engineering,2010,(4):15-17.
[13] 李忠,井波,于少明.CA-SA/蒙脱土复合相变贮能材料的制备、结构与性能 [J].化工新型材料,2007,35(3):42-44.LI Zhong,JING Bo,YU Shao-ming.Preparation,structure and properties of CA-SA/montmorillonite composite phase-change energy storage materials [J].New Chemical Materials,2007,35(3):42-44.
[14] 唐新村,黄伯云,贺跃辉.低热固相反应的反应机理研究 [J].无机化学学报,2004,20(7):795-801.TANG Xin-cun,HUANG Bo-yun,HE Yue-hui,et al.Studies on the mechanism of the low-heating solid-state reaction [J].Chinese Journal of Inorganic Chemistry,2004,20(7):795-801.
[15] 许川,马爱琼,刘民生,等.固相反应法合成锌铝尖晶石 [J].硅酸盐通报,2012,31(2):455-463.XU Chuan,MA Ai-qiong,LIU Min-sheng,et al.ZnAl2O4 spinel powder synthesized by solid phase reaction method [J].Bulletin of the Chinese Ceramic Society,2012,31(2):455-463.
[16] 张帅国,米杰,尚素利,等.固相反应法制备纳米ZnO及其晶粒生长动力学 [J].化工进展,2014,33(3):710-719.ZHANG Shuai-guo,MI Jie,SHANG Su-li,et al.Grain growth kinetics study on ZnO nanoparticles prepared by solid state reaction [J].Chemical Industry and Engineering Progress,2014,33(3):710-719.
[1] 喻胜飞, 罗武生. 石蜡/聚脲相变微胶囊的制备及表征[J]. 材料工程, 2015, 43(7): 100-104.
[2] 刘菁伟, 杨文彬, 谢长琼, 张凯, 范敬辉. HDPE/EG/石蜡导热定形相变材料的制备及性能[J]. 材料工程, 2015, 43(4): 42-46.
[3] 高玉魁. 冲击强化对304奥氏体不锈钢拉伸性能的影响[J]. 材料工程, 2014, 0(8): 36-40.
[4] 彭宁琦, 唐广波, 刘正东. 奥氏体高温转变区二段冷却速率对铁素体相变的影响[J]. 材料工程, 2013, 0(9): 11-15.
[5] 廖娟, 凌泽民, 彭小洋. 考虑相变的铝合金管焊接残余应力数值模拟[J]. 材料工程, 2013, 0(4): 34-38.
[6] 李凌云, 刘璐琪, 汤龙程, 高云, 张忠. 二氧化硅纳米颗粒增强炭纤维/环氧树脂界面性能[J]. 材料工程, 2012, 0(6): 32-36.
[7] 尚继武, 张以河, 吕凤柱. 高介电常数聚合物基复合材料研究进展[J]. 材料工程, 2012, 0(5): 87-92.
[8] 刘昆鹏, 赵子华, 张峥. 321不锈钢疲劳早期损伤的涡流评估[J]. 材料工程, 2012, 0(11): 61-65.
[9] 张明灿, 曾人杰. 注浆成型-常温常压干燥制备隔热块体材料[J]. 材料工程, 2011, 0(9): 33-38.
[10] 司乃潮, 郑利波, 司松海, 李镭, 翟玉敬. 冷变形和中温处理对TiNiCr形状记忆合金相变的影响[J]. 材料工程, 2011, 0(7): 20-25.
[11] 梁继然, 胡明, 阚强, 陈涛, 梁秀琴, 陈弘达. 晶粒尺寸对氧化钒薄膜电学与光学相变特性的影响[J]. 材料工程, 2011, 0(4): 58-62,74.
[12] 朱国明, 邝霜, 陈贵江, 陈波, 任君茹. 马氏体对C-Si-Mn冷轧双相钢屈服特性的影响[J]. 材料工程, 2011, 0(4): 66-70.
[13] 王立军, 蔡庆伍, 余伟, 武会宾, 雷爱娣. 低碳低合金钢的连续冷却相变组织特征及其形成机制[J]. 材料工程, 2010, 0(8): 29-33.
[14] 马烽, 李永超, 陈明辉, 宗学刚. 蜜胺树脂/硬脂酸丁酯相变微胶囊的制备[J]. 材料工程, 2010, 0(7): 42-45,77.
[15] 马烽, 王晓燕, 李飞, 陈明辉. 定形相变储能建筑材料的制备与热性能研究[J]. 材料工程, 2010, 0(6): 54-58.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn