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材料工程  2018, Vol. 46 Issue (5): 139-144    DOI: 10.11868/j.issn.1001-4381.2016.001423
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
CeO2掺杂对Pb0.92Sr0.06Ba0.02-(Sb2/3Mn1/3)0.05Zr0.48Ti0.47O3基压电陶瓷相结构及性能的影响
徐腾威1, 甘国友1, 严继康2, 李震宇2, 郭根生2, 易健宏3
1. 昆明理工大学 材料科学与工程学院, 昆明 650093;
2. 稀贵及 有色金属先进材料教育部重点实验室, 昆明 650093;
3. 云南省新 材料制备与加工重点实验室, 昆明 650500
Effects of CeO2 Addition on Phase Structure and Properties of Pb0.92Sr0.06Ba0.02(Sb2/3Mn1/3)0.05Zr0.48Ti0.47O3 Piezoelectric Ceramics
XU Teng-wei1, GAN Guo-you1, YAN Ji-kang2, LI Zhen-yu2, GUO Gen-sheng2, YI Jian-hong3
1. Faculty of Material and Engineering, Kunming University of Science and Technology, Kunming 650093, China;
2. Key Laboratory of Advanced Materials of Precious-Nonferrous Metals (Ministry of Education), Kunming 650093, China;
3. Key Laboratory of Advanced Materials of Yunnan Province, Kunming 650500, China
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摘要 采用传统固相烧结法制备Pb0.92Sr0.06Ba0.02(Sb2/3Mn1/30.05Zr0.48Ti0.47O3xCeO2(简称PSBSM-PZT)压电陶瓷样品。研究不同CeO2掺杂含量对PSBSM-PZT基陶瓷样品的物相结构、微观形貌、压电及介电性能的影响。结果表明:当CeO2掺杂量x ≤ 0.5%(质量分数,下同)时,陶瓷样品均为纯的钙钛矿结构。随着CeO2掺杂含量的增加,陶瓷样品中四方相结构逐渐向三方相结构转变。随着CeO2掺杂含量的进一步增加,陶瓷中出现焦绿石相,虽然陶瓷中已经出现焦绿石相,但是样品仍没有完全转变为三方相陶瓷; CeO2掺杂具有细化晶粒的作用,当x=0.25%时样品晶粒晶界清晰,晶粒之间的结合相对致密,晶界处气孔率低,陶瓷断裂方式以沿晶断裂为主;当x=0.25%时,陶瓷样品获得最佳的压电与介电性能:d33=346pC/N,kp=0.60,Qm=1396,εr=1309,tanδ=0.474%。
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徐腾威
甘国友
严继康
李震宇
郭根生
易健宏
关键词 压电材料PMS-PZT显微形貌分析掺杂改性    
Abstract:Pb0.92Sr0.06Ba0.02(Sb2/3Mn1/3)0.05Zr0.48Ti0.47O3:xCeO2 piezoelectric ceramics were prepared by a conventional solid state reaction method. The effect of CeO2 addition on the phase transition, microstructure piezoelectric and dielectric performances of samples were systematically investigated. The results show that ceramics are pure perovskite structure when the doping amount of CeO2 is less than or equal to 0.5% (mass faction, the same below), with the CeO2 doping content increasing, the formation of pyrochlore phase will be facilitated, but the samples are still not completely transformed to rhombohedral phases; and CeO2 doping plays the role of grain refinement, when x=0.25% the sample has an even grain size, clear boundary and it also has lower porosity and higher density, the main fracture mode of the sample is intergranular fracture; when x=0.25% ceramic samples obtain the best piezoelectric and dielectric performance:d33=346pC/N, kp=0.60, Qm=1396, εr=1309, tanδ=0.474%.
Key wordspiezoelectric material    PMS-PZT    microstructure analysis    doping modification
收稿日期: 2016-10-29      出版日期: 2018-05-16
中图分类号:  TB34  
  TQ174  
通讯作者: 甘国友(1965-),男,教授,博士,研究方向:功能材料,联系地址:云南省昆明市五华区学府路253号昆明理工大学材料科学与工程学院(650093),E-mail:ganguoyou@kmust.edu.cn     E-mail: ganguoyou@kmust.edu.cn
引用本文:   
徐腾威, 甘国友, 严继康, 李震宇, 郭根生, 易健宏. CeO2掺杂对Pb0.92Sr0.06Ba0.02-(Sb2/3Mn1/3)0.05Zr0.48Ti0.47O3基压电陶瓷相结构及性能的影响[J]. 材料工程, 2018, 46(5): 139-144.
XU Teng-wei, GAN Guo-you, YAN Ji-kang, LI Zhen-yu, GUO Gen-sheng, YI Jian-hong. Effects of CeO2 Addition on Phase Structure and Properties of Pb0.92Sr0.06Ba0.02(Sb2/3Mn1/3)0.05Zr0.48Ti0.47O3 Piezoelectric Ceramics. Journal of Materials Engineering, 2018, 46(5): 139-144.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.001423      或      http://jme.biam.ac.cn/CN/Y2018/V46/I5/139
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