Please wait a minute...
 
材料工程  2020, Vol. 48 Issue (10): 163-168    DOI: 10.11868/j.issn.1001-4381.2018.000749
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
TiO2基底对MoO3/TiO2复合薄膜电致变色性能的影响
成明, 杨继凯, 郝志旭, 亢嘉琪, 王新, 王国政, 宦克为
长春理工大学 理学院, 长春 130022
Effect of TiO2 substrate on electrochromic properties of MoO3/TiO2 composite films
CHENG Ming, YANG Ji-kai, HAO Zhi-xu, KANG Jia-qi, WANG Xin, WANG Guo-zheng, HUAN Ke-wei
School of Science, Changchun University of Science and Technology, Changchun 130022, China
全文: PDF(2090 KB)   HTML()
输出: BibTeX | EndNote (RIS)      
摘要 采用水热法首先在导电玻璃上制备TiO2纳米线,随后电沉积涂覆MoO3薄膜,成功制备MoO3/TiO2复合薄膜。利用电化学测试与光谱测试,得到MoO3/TiO2复合薄膜的扩散系数、着色/退色的响应时间、光密度、电致变色可逆性和着色效率等参数,研究不同水热生长时长TiO2纳米线基底对MoO3/TiO2复合薄膜的电致变色性能的影响。结果表明:水热生长6 h TiO2纳米线的MoO3/TiO2复合薄膜具有最佳的电致变色性能,扩散系数为2.86×10-12 cm2·s-1,可逆性值为60.88%,光密度为0.41,着色效率达到124.49 cm2·C-1,着色和退色响应时间分别为13.53 s和12.65 s。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
成明
杨继凯
郝志旭
亢嘉琪
王新
王国政
宦克为
关键词 薄膜电致变色电化学测试TiO2MoO3    
Abstract:TiO2 nanowires were prepared on fluorine-doped tin oxide(FTO) glass by hydrothermal synthesis, and then the MoO3/TiO2 composite films were prepared by electrodepositing MoO3 films onto TiO2 nanowire arrays. The parameters such as diffusion coefficient(D), the responding time of colored and bleached, optical density(ΔOD), electrochromic reversibility and coloration efficiency of MoO3/TiO2 composite film were obtained by electrochromical measurement technologies and spectrum tests. The effect of TiO2 nanowire substrates with different hydrothermal growth time on the electrochromic properties of MoO3/TiO2 composite films was studied. The results show that the MoO3/TiO2 composite films with 6 hours of hydrothermal growth TiO2 nanowires have the best electrochromic properties. The diffusion coefficient is 2.86×10-12 cm2·s-1, the cyclic reversibility is 60.88%, the optical density is 0.41, the coloring efficiency reaches 124.49 cm2·C-1, and its responding time of colored and bleached is 13.53 s and 12.65 s.
Key wordsthin film    electrochromism    electrochromic measurement    TiO2    MoO3
收稿日期: 2018-06-20      出版日期: 2020-10-17
中图分类号:  O646  
  O614  
通讯作者: 杨继凯(1982-),男,副教授,博士,研究方向为光催化、电致变色等,联系地址:吉林省长春市长春理工大学东校区二教503(130022),E-mail:jikaiyang0625@163.com     E-mail: jikaiyang0625@163.com
引用本文:   
成明, 杨继凯, 郝志旭, 亢嘉琪, 王新, 王国政, 宦克为. TiO2基底对MoO3/TiO2复合薄膜电致变色性能的影响[J]. 材料工程, 2020, 48(10): 163-168.
CHENG Ming, YANG Ji-kai, HAO Zhi-xu, KANG Jia-qi, WANG Xin, WANG Guo-zheng, HUAN Ke-wei. Effect of TiO2 substrate on electrochromic properties of MoO3/TiO2 composite films. Journal of Materials Engineering, 2020, 48(10): 163-168.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2018.000749      或      http://jme.biam.ac.cn/CN/Y2020/V48/I10/163
[1] KUMAR A,AHLUWALIA P K.Electronic structure of transition metal dichalcogenides monolayers 1H-MX2(M=Mo, W; X=S, Se, Te) from ab-initio theory:new direct band gap semiconductors[J].European Physical Journal B,2012,85:186-192.
[2] RAMASUBRAMANIAM A,NAVEH D,TOWE E.Tunable band gaps in bilayer transition-metal dichalcogenides[J].Physical Review:B,2011,84(20):3239-3247.
[3] KAMALISARVESTANI M,SAIDUR R,MEKHILEF S,et al.Performance,materials and coating technologies of thermochromic thin films on smart windows[J].Renewable and Sustainable Energy Reviews,2013,26:353-364.
[4] VASILYEVA S V,BEAUJUGE P M,WANG S,et al.Material strategies for black-to-transmissive window-type polymer electrochromic devices[J].ACS Applied Materials & Interfaces,2011,3(4):1022-1032.
[5] ROSSEINSKY D R,MORTIMER R J.Electrochromic systems and the prospects for devices[J].Advanced Materials,2001,13(11):783-793.
[6] WANG J,KHOO E,LEE P S,et al.Synthesis, assembly, and electrochromic properties of uniform crystalline WO3 nanorods[J].The Journal of Physical Chemistry C,2008,112(37):14306-14312.
[7] YANG Y A,CAO Y W,LOO B H,et al.Microstructures of electrochromic MoO3 thin films colored by injection of different cations[J].The Journal of Physical Chemistry B,1998,102(47):9392-9396.
[8] LI H,VIENNEAU G,JONES M,et al.Crack-free 2D-inverse opal anatase TiO2 films on rigid and flexible transparent conducting substrates:low temperature large area fabrication and electrochromic properties[J].Journal of Materials Chemistry C,2014,2(37):7804-7810.
[9] 张曼莉,邱长军,蒋艳林,等.激光原位合成Al2O3-TiO2复合陶瓷涂层组织结构与性能[J].材料工程,2018,46(2):57-65. ZHANG M L,QIU C J,JIANG Y L,et al.Microstructure and properties of laser in-situ synthesized Al2O3-TiO2 composite ceramic coating[J].Journal of Materials Engineering,2018,46(2):57-65.
[10] 陈翔,燕绍九,王楠,等.δ-MnO2纳米片的制备、表征及电化学性能[J].材料工程,2019,47(2):49-55. CHEN X,YAN S J,WANG N,et al.Fabrication,characterization and electrochemical behavior of δ-MnO2 nanoflakes[J].Journal of Materials Engineering,2019,47(2):49-55.
[11] GHICOV A,YAMAMOTO M,SCHMUKI P.Lattice widening in niobium-doped TiO2 nanotubes:efficient ion intercalation and swift electrochromic contrast[J].Angewandte Chemie International Edition,2008,47(41):7934-7937.
[12] SHIN J Y,JOO J H,SAMUELIS D,et al.Oxygen-deficient TiO2-δ nanoparticles via hydrogen reduction for high rate capability lithium batteries[J].Chemistry of Materials,2012,24(3):543-551.
[13] OU J Z,CAMPBELL J L,YAO D,et al. In situ Raman spectroscopy of H2 gas interaction with layered MoO3[J].The Journal of Physical Chemistry C,2011,115(21):10757-10763.
[14] 李高锋,李智敏,宁涛,等.锂离子电池正极材料表面包覆改性研究进展[J].材料工程,2018,46(9):23-30. LI G F,LI Z M,NING T,et al.Research progress of cathode materials modified by surface coating for lithium ion batteries[J].Journal of Materials Engineering,2018,46(9):23-30.
[15] PRASAD A K,KUBINSKI D J,GOUMA P I.Comparison of sol-gel and ion beam deposited MoO3 thin film gas sensors for selective ammonia detection[J].Sensors and Actuators:B,2003,93(1):25-30.
[16] NAVAS I,VINODKUMAR R,LETHY K J,et al.Growth and characterization of molybdenum oxide nanorods by RF magnetron sputtering and subsequent annealing[J].Journal of Physics:D,2009,42(17):175305-175313.
[17] SICILIANO T,TEPORE A,FILIPPO E,et al.Characteristics of molybdenum trioxide nanobelts prepared by thermal evaporation technique[J].Materials Chemistry and Physics,2009,114(2):687-691.
[18] YAO D D,OU J Z,LATHAM K,et al.Electrodeposited α-and β-phase MoO3 films and investigation of their gasochromic properties[J].Crystal Growth & Design,2012,12(4):1865-1870.
[19] SHRESTHA N K,NAH Y C,TSUCHIYA H,et al.Self-orga-nized nano-tubes of TiO2-MoO3 with enhanced electrochromic properties[J].Chemical Communications,2009,2009(15):2008-2010.
[20] LI N,LI Y,LI W,et al.One-step hydrothermal synthesis of TiO2@MoO3 core-shell nanomaterial:microstructure, growth mechanism, and improved photochromic property[J].The Journal of Physical Chemistry C,2016,120(6):3341-3349.
[21] SUN P,ZHANG X,LIU X,et al.Growth of single-crystalline rutile TiO2 nanowire array on titanate nanosheet film for dye-sensitized solar cells[J].Journal of Materials Chemistry,2012,22(13):6389-6393.
[22] KHARADE R R,PATIL S P,MANE R M,et al.Synthesis and electrochromic application of surfactants tailored WO3 nanostructures[J].Optical Materials,2011,34(1):322-326.
[23] BRIGOULEIX C,TOPART P,BRUNETON E,et al.Roll-to-roll pulsed dc magnetron sputtering deposition of WO3 for electrochromic windows[J].Electrochimica Acta,2001,46(13/14):1931-1936.
[24] KHARADE R R,MALI S S,PATIL S P,et al.Enhanced electrochromic coloration in Ag nanoparticle decorated WO3 thin films[J].Electrochimica Acta,2013,102:358-368.
[25] KHARADE R R,MALI S S,MOHITE S S,et al.Hybrid physicochemical synthesis and electrochromic performance of WO3/MoO3 thin films[J].Electroanalysis,2014,26(11):2388-2397.
[1] 刘欢, 张瑞英, 李金轩, 杨森, 闫晗. TiO2粒径对Al-TiO2-C细化剂组织及细化效果的影响[J]. 材料工程, 2020, 48(8): 126-133.
[2] 刘峰峰, 李玉雄, 隋展鹏, 蔡勇, 张永红, 蒋春萍. 非晶AlBN介质薄膜的制备及相关特性研究[J]. 材料工程, 2020, 48(6): 112-117.
[3] 杜晶晶, 赵军伟, 程晓民, 施飞. 高效光催化降解气相苯纳米TiO2微球的制备[J]. 材料工程, 2020, 48(5): 100-105.
[4] 邓培淼, 宁洪龙, 谢伟广, 刘贤哲, 邓宇熹, 姚日晖, 彭俊彪. 氧化亚锡薄膜晶体管的研究进展[J]. 材料工程, 2020, 48(4): 83-88.
[5] 杨伸勇, 张丛春, 杨卓青, 李红芳, 姚锦元, 黄漫国, 汪红, 丁桂甫. 高温ITO薄膜应变计制备及压阻性能[J]. 材料工程, 2020, 48(4): 145-150.
[6] 李淑文, 赵孔银, 陈康, 李金刚, 赵磊, 王晓磊, 魏俊富. TiO2共混丝朊接枝聚丙烯腈过滤膜制备及性能研究[J]. 材料工程, 2020, 48(3): 47-52.
[7] 朱晓东, 王尘茜, 雷佳浩, 裴玲秀, 朱然苒, 冯威, 孔清泉. 锐钛矿型银掺杂二氧化钛紫外光及模拟太阳光光催化性能[J]. 材料工程, 2020, 48(2): 59-64.
[8] 金嘉炜, 李国臣, 张冶, 李公义, 楚增勇. TiO2薄膜型气敏传感器研究进展[J]. 材料工程, 2020, 48(10): 28-38.
[9] 曾宝平, 贾瑛, 许国根, 李明, 冯锐. CTAB作用下TiO2/g-C3N4的制备及光催化降解偏二甲肼废水[J]. 材料工程, 2019, 47(9): 139-144.
[10] 刘凯, 崔荣洪, 侯波, 何宇廷, 牛欢. PVD薄膜传感器裂纹检测概率测定与分析[J]. 材料工程, 2019, 47(9): 160-166.
[11] 赵斌, 张芮境, 申倩倩, 王羿, 薛晋波, 张爱琴, 贾虎生. TiO2纳米管阵列基底退火温度对CdSe/TiO2异质结薄膜光电化学性能的影响[J]. 材料工程, 2019, 47(8): 90-96.
[12] 黄骏逸, 方向, 李裕春, 刘强, 武双章, 宋佳星. PTFE/Al/MoO3复合材料的力学和反应性能[J]. 材料工程, 2019, 47(7): 92-98.
[13] 李妍, 付东旭, 张青松, 竺云. 单/双离子替代对铁酸铋薄膜性能影响的研究进展[J]. 材料工程, 2019, 47(5): 10-17.
[14] 张明艳, 高升, 吴子剑, 崔宏玉, 高岩. 共聚低热膨胀聚酰亚胺薄膜的制备与表征[J]. 材料工程, 2019, 47(5): 153-158.
[15] 李曦. 二维和零维纳米材料协同增强的高性能纳米复合材料[J]. 材料工程, 2019, 47(4): 47-55.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn