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材料工程  2020, Vol. 48 Issue (2): 22-31    DOI: 10.11868/j.issn.1001-4381.2019.000553
  综述 本期目录 | 过刊浏览 | 高级检索 |
金属表面制备绿色环保防腐膜技术的研究进展
杜娟1, 魏子明1, 郑世辑2, 陈亚军1, 胡雪兰1, 汪睿1
1. 中国民航大学, 天津 300300;
2. 天津航天长征火箭制造有限公司, 天津 300462
Research progress in preparation technology of green environmental anticorrosion coating on metal surface
DU Juan1, WEI Zi-ming1, ZHENG Shi-ji2, CHEN Ya-jun1, HU Xue-lan1, WANG Rui1
1. Civil Aviation University of China, Tianjin 300300, China;
2. Tianjin Long March Launch Vehicle Manufacturing Co., Ltd., Tianjin 300462, China
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摘要 金属表面防腐技术一直是工业工程领域的关注重点。随着科技进步和对环境保护的关注,对绿色环保的要求也逐渐成为当前金属表面防腐技术的重要指标之一。本文综述了近年来金属表面绿色环保防腐涂层制备技术的研究进展。在综合国内外文献基础上,对金属表面防腐涂层中3种典型新技术,即自组装膜技术、缓蚀剂以及分子筛膜技术的分类、特点和应用、防腐机理等进行了讨论。指出了涂层添加剂和石墨烯涂层等其他可行的绿色环保防腐涂层技术,以及自组装膜技术、缓蚀剂以及分子筛膜技术在体系构建、工艺优化以及复合涂层设计等方面的发展趋势。
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杜娟
魏子明
郑世辑
陈亚军
胡雪兰
汪睿
关键词 防腐涂层自组装膜缓蚀剂分子筛膜    
Abstract:The metal surface anti-corrosion technology has always been the focus of attention in the field of industrial engineering. With the advancement of science and technology and the consideration of environmental protection, its green environmental protection requirements have gradually become one of the important indicators of the current metal surface anti-corrosion technology. In this paper, in order to study the research progress of green anti-corrosion coating technology on metal surface in recent years, based on a large number of domestic and foreign literatures, the classification, characteristics and application of membrane technology and anti-corrosion mechanism of three typical new technologies in metal surface anti-corrosion coating, i.e. self-assembled monolayers(SAMs) technology, corrosion inhibitor and molecular sieve membrane technology were reviewed. At the same time, other feasible green anti-corrosion coating technologies such as coating additives and graphene coatings and the developing trend of self-assembled monolayers, corrosion inhibitor and molecular sieve membrane technology in system construction, process optimization and composite coating design and etc are pointed out.
Key wordsanti-corrosion coating    self-assembled monolayer    corrosion inhibitor    zeolite membrane
收稿日期: 2019-06-11      出版日期: 2020-03-03
中图分类号:  TB37  
通讯作者: 杜娟(1982-),女,讲师,博士,主要从事航空材料腐蚀与防护方面的研究工作,联系地址:天津市中国民航大学中欧航空工程师学院(300300),E-mail:dujuan247@163.com     E-mail: dujuan247@163.com
引用本文:   
杜娟, 魏子明, 郑世辑, 陈亚军, 胡雪兰, 汪睿. 金属表面制备绿色环保防腐膜技术的研究进展[J]. 材料工程, 2020, 48(2): 22-31.
DU Juan, WEI Zi-ming, ZHENG Shi-ji, CHEN Ya-jun, HU Xue-lan, WANG Rui. Research progress in preparation technology of green environmental anticorrosion coating on metal surface. Journal of Materials Engineering, 2020, 48(2): 22-31.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000553      或      http://jme.biam.ac.cn/CN/Y2020/V48/I2/22
[1] MASSIMILIANO B,ROBERTO G.Hard anodizing of AA2011-T3 Al-Cu-Pb-Bi free-cutting alloy:improvement of the process parameters[J].Corrosion Science,2018,141:63-71.
[2] SONG D L,JING X Y,WANG J,et al.Microwave-assisted synthesis of lanthanum conversion coating on Mg-Li alloy and its corrosion resistance[J].Corrosion Science,2011,53:3651-3656.
[3] YANG W,XU D P,WANG J L,et al.Microstructure and corrosion resistance of micro arc oxidation plus electrostatic powder spraying composite coating on magnesium alloy[J].Corrosion Science,2018,136:174-179.
[4] IMAZ N,OSTRA M,VIDAL M,et al.Corrosion behaviour of chromium coatings obtained by direct and reverse pulse plating electrodeposition in NaCl aqueous solution[J].Corrosion Science,2014,78:251-259.
[5] 王慧婷,史娜,刘章,等.6×××系铝合金表面腐蚀及其防腐的研究现状[J].表面技术,2018,47(1):160-167. WANG H T,SHI N,LIU Z,et al.Surface corrosion and corrosion prevention of 6XXX-series aluminium alloy[J].Surface Technology,2018,47(1):160-167.
[6] LAIBINIS P E,WHITESIDES G M.ω-terminated alkanethiolate monolayers on surfaces of copper, silver and gold have similar wet-tabilities[J].Journal of the American Chemical Society,1990,114(6):2000-2002.
[7] ASHASSI-SORKHABI H,SEIFZADEH D,HOSSEINI M.EN, EIS and polarization studies to evaluate the inhibition effect of 3H-phenothiazin-3-one,7-dimethylamin on mild steel corrosion in 1 M HCl solution[J].Corrosion Science,2008,50:3363-3370.
[8] SONG D L,JING X Y,WANG J,et al.Corrosion-resistant ZSM-5 zeolite coatings formed on Mg-Li alloy by hot-pressing[J].Corrosion Science,2011,53:1732-173.
[9] ZERJAV G,MILOSEV I.Protection of copper against corrosion in simulated urban rain by the combined action of benzotriazole,2-mercaptobenzimidazole and stearic acid[J].Corrosion Science,2015,98:180-191.
[10] DENAYER J,VOLCKE C,DELHALLE J,et al.Formation on copper of perfluoroetheralkyl-thiol and dithiol self-assembled monolayers with a perfluoropolyether overlayer[J].Electrochim Acta,2012,63:269-276.
[11] 鲁文晔,陈蝶依,汤涛,等.HDT自组装膜对银的缓蚀作用[J].材料研究学报,2016,30(9):697-702. LU W Y,CHEN D Y,TANG T,et al.Corrosion inhibition of silver by HDT self-assembled monolayers[J].Chinese Journal of Materials Research,2016,30(9):697-702.
[12] LI J,CHEN D H,ZHANG D Q,et al.Preparation of triazole compounds via click chemistry reaction and formation of the protective self-assembled membrane against copper corrosion[J].Colloids and Surfaces:A,2018,550:145-154.
[13] ZHANG D Q,LIU P H,GAO L X,et al.Photosensitive self-assembled membrane of cysteine against copper corrosion[J].Materials Letters,2011,65(11):1636-1638.
[14] LI L,LI B,DONG J,et al.Roles of silanes and silicones in forming superhydrophobic and superoleophobic materials[J].J Mater Chem A,2016,4(36):13677-13725.
[15] MRAD M,AMOR Y B,DHOUIBI L,et al.Corrosion prevention of AA2024-T3 aluminum alloy with a polyaniline/poly(γ-glycidoxypropyltrimethoxysilane) bi-layer coating:comparative study with polyaniline mono-layer feature[J].Surf Coat Technol,2018,337:1-11.
[16] WEN Y Q,KONG D,SHANG W,et al.Corrosion resistance performance of the self-assembled reduction of graphene/silane composite films[J].Colloids and Surfaces:A,2019,562:247-254.
[17] EMREGUL K C,HAYVALI M.Studies on the effect of a newly synthesized Schiff base compound from phenazone and vanillin on the corrosion of steel in 2 M HCl[J].Corrosion Science,2006,48:797-812.
[18] FANG Y,BAVITHTHIRA S,RAMARAJA P R.Electrochemical characterization of aromatic corrosion inhibitors from plant extracts[J].Journal of Electroanalytical Chemistry,2019,840:74-83.
[19] DU J,JIA S.The preparation of a novel corrosion inhibitor and its corrosion inhibition behavior on 2024 Al-Cu-Mg alloy in acid solution[J].Journal of Surfactants and Detergents,2019,22(4):833-843.
[20] BADR E A.Inhibition effect of synthesized cationic surfactant on the corrosion of carbon steel in 1 M HCl[J].J Ind Eng Chem,2014,20:3361-3366.
[21] HEGAZY M A,BADAWI A M,REHIM S S,et al.Corrosion inhibition of carbon steel using novel N-(2-(2-mercaptoacetoxy)ethyl)-N,N-dimethyl dodecan-1-aminium bromide during acid pickling[J].Corrosion Science,2013,69:110-122.
[22] MOHAMMAD M,TEHRANI-BAGHA A R,ALIBAKHSHI E,et al. Corrosion of mild steel in hydrochloric acid solution in the presence of two cationic gemini surfactants with and without hydroxyl substituted spacers[J].Corrosion Science,2018,137:62-75.
[23] WU L K,LIU L,LI J,et al.Electrodeposition of cerium (Ⅲ)-modified bis-[triethoxysilypropyl] tetra-sulphide films on AA2024-T3(aluminum alloy) for corrosion protection[J].Surf Coat Technol,2010,204:3920-3926.
[24] NADERI R,FEDEL M,DEFLORIAN F,et al.Synergistic effect of clay nanoparticles and cerium component on the corrosion behavior of eco-friendly silane sol-gel layer applied on pure aluminum[J].Surf Coat Technol,2013,224:93-100.
[25] RAMEZANZADEH B,RASI E,MAHDAVIAN M.Studying various mixtures of 3-aminopropyltriethoxysilane (APS) and tetraethylorthosilicate (TEOS) silanes on the corrosion resistance of mild steel and adhesion properties of epoxy coating[J].Int J Adhes Adhes,2015,63:166-176.
[26] PALANIVEL V,HUANG Y.Effects of addition of corrosion inhibitors to silane films on the performance of AA2024-T3 in a 0.5 M NaCl solution[J].Prog Org Coat,2005,53:153-168.
[27] DEFLORIAN F,ROSSI S,FEDEL M,et al.Electrochemical investigation of high-performance silane sol-gel films containing clay nanoparticles[J].Prog Org Coat,2010,69:158-166.
[28] CALABRESE L,BONACCORSI L,PROVERBIO E.Corrosion protection of aluminum 6061 in NaCl solution by silane-zeolite composite coatings[J].J Coat Technol Res,2012,9(5):597-607.
[29] GHARAGOZLOU M,NADERI R,BARADARAN Z.Effect of synthesized NiFe2O4-silica nanocomposite on the performance of an ecofriendly silane sol-gel coating[J].Prog Org Coat,2016,90:407-413.
[30] DIAS S A S,LAMAKA S V,NOGUEIRA C A,et al.Sol-gel coatings modified with zeolite fillers for active corrosion protection of AA2024[J].Corrosion Science,2012,62:153-162.
[31] SNIHIROVA D,LAMAKA S V,MONTEMOR M F."SMART" protective ability of water based epoxy coatings loaded with CaCO3 microbeads impregnated with corrosion inhibitors applied on AA2024 substrates[J].Electrochim Acta,2012,83:439-447.
[32] FROLICH K,BULANEK R,FRYDOVA E.Interaction of CO probe molecules with Cu+ in MCM-22 zeolite[J].Microporous Mesoporous Mater,2014,186:37-45.
[33] WANG Y L,ZHU Y H,LI C,et al.Smart epoxy coating containing Ce-MCM-22 zeolites for corrosion protection of Mg-Li alloy[J].Applied Surface Science,2016,369:384-389.
[34] CHO K,CHO H S,MENORVAL L C,et al.Generation of mesoporosity in LTA zeolites by organosilane surfactant for rapid molecular transport in catalytic application[J].Chem Mater,2009,21:5664-5665.
[35] MOSCA A,HEDLUND J,WEBLEY P A,et al.Structured zeolite NaX coatings on ceramic cordierite monolith supports for PSA applications[J].Micropor Mesopor Mater,2010,130:38-39.
[36] TERAOKA Y,MOTOI Y,YAMASAKI H,et al.Progress in zeolite and microporous materials[J].Stud Surf Sci,Catal, 1997,105:1787-1788.
[37] CAMBLOR M A,CORMA A,VALENCIA S.synthesis in fluoride media and characterisation of aluminosilicate zeolite beta[J].J Mater Chem,1998,8(9):2137-2138.
[38] SANG S Y,CHANG F X,LIU Z M,et al.Difference of ZSM-5 zeolites synthesized with various templates[J].Catal Today,2004,93:719-720.
[39] FLANIGEN E M,BENNETT J M,ROSE W G,et al.Silicalite, a new hydrophobic crystalline silicamolecular-sieve[J].Nature,1978,271(5645):512-516.
[40] LEW C M,CAI R,YAN Y.Zeolite thin films:from computer chips to space stations[J].Chem Res,2010,43(2):197-210.
[41] BEDI R S,ZANELLO L P,YAN Y S.Osteoconductive and osteoinductive properties of zeolite MFI coatings on titanium alloys[J].Adv Funct Mater,2009,19:3856-3861.
[42] WANG N,CHENG K,WU H,et al.Effect of nano-sized mesoporous silica MCM-41 and MMT on corrosion properties of epoxy coating[J].Progr Org Coat,2012,75:386-391.
[43] CHAKRABORTY B P,REN P W,GRAYSON S M,et al.Influence of zeolite coating on the corrosion resistance of AZ91D magnesium alloy[J].Materials,2014,7(8):6092-6104.
[44] CHENG X,WANG Z,YAN Y.Corrosion-resistant zeolite coatings by in situ crystallization[J].Electrochem Solid-State Lett,2001,4:23-26.
[45] SONG D,JING X,WANG J,et al.Corrosion-resistant ZSM-5 zeolite coatings formed on Mg-Li alloy by hot-pressing[J].Corrosion Science,2011,53:1732-1737.
[46] 王政,王林,张国香,等.ZSM-5/磷酸铝复合分子筛在甲醇制烯烃反应中的应用[J].石油学报(石油加工),2011,27(4):543-548. WANG Z,WANG L,ZHANG G X,et al.Application of ZSM-5/aluminophosphates composite zeolite for methanol to oiefins[J].Acta Petrolei Sinica(Petroleum Processing Section),2011,27(4):543-548.
[47] CUI L Y,QIN P H,HUANG X L,et al.Electrodeposition of TiO2 layer-by-layer assembled composite coating and silane treatment on Mg alloy for corrosion resistance[J].Surface and Coatings Technology,2017,324:560-568.
[48] ZENG R C,HU Y,ZHANG F,et al.Corrosion resistance of cerium-doped zinc calcium phosphate chemical conversion coatings on AZ31 magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2016,26(2):472-483.
[49] PHUONG N V,GUPTA M,MOON S.Enhanced corrosion performance of magnesium phosphate conversion coating on AZ31 magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2017,27:1087-1095.
[50] LI X,WENG Z,YUAN W,et al.Corrosion resistance of dicalcium phosphate dihydrate/poly(lactic-co-glycolic acid) hybrid coating on AZ31 magnesium alloy [J].Corrosion Science,2016,102:209-221.
[51] BAKHSHESHI-RAD H R,HAMZAH E,ISMAIL A F,et al. Bioactivity, in-vitro corrosion behavior, and antibacterial activity of silver-zeolites doped hydroxyapatite coating on magnesium alloy[J].Trans Nonferrous Met Soc China,2018,28:1553-1562.
[52] JIANG M Y,WU L K,HU J M,et al.Silane-incorporated epoxy coatings on aluminum alloy (AA2024): part 1 improved corrosion performance[J].Corrosion Science,2015,92:118-126.
[53] MAHDAVIAN M,NADERI R,PEIGHAMBARI M,et al.Evaluation of cathodic disbondment of epoxy coating containing azole compounds[J].J Ind Eng Chem,2015,21:1167-1173.
[54] MATIN E,ATTAR M,RAMEZANZADEH B.Investigation of corrosion protection properties of an epoxy nanocomposite loaded with polysiloxane surface modified nanosilica particles on the steel substrate[J].Prog Org Coat,2015,78:395-403.
[55] PALIMI M,ROSTAMI M,MAHDAVIAN M,et al.A study on the corrosion inhibition properties of silane-modified Fe2O3 nanoparticle on mild steel and its effect on the anticorrosion properties of the polyurethane coating[J].J Coat Technol Res,2015,12:277-292.
[56] 周楠,陈浩,丁纪恒,等.石墨烯的分散及其在防腐涂层中的应用[J].中国涂料,2017,32(2):6-10. ZHOU N,CHEN H,DING J H,et al.Efficient dispersion of graphene and its application in anticorrosion coatings[J].China Coatings,2017,32(2):6-10.
[57] CHANG K C,JI W F,LI C W,et al.The effect of varying carboxylic-group content in reduced graphene oxides on the anticorrosive properties of PMMA/reduced graphene oxide composites[J].Express Polym Lett,2014,8(12):908-920.
[58] LIU J,HUA L,LI S,et al.Graphene dip coatings:an effective anticorrosion barrier on aluminum[J].Appl Surf Sci,2015,327:241-245.
[59] ZHANG S,TANG S,LEI J,et al.Functionalization of graphene nanoribbons with porphyrin for electrocatalysis and amperometric biosensing [J].Journal of Electroanalytical Chemistry,2011,656(1):285-288.
[60] 郑辉东.3D氧化石墨烯纳米带-碳纳米管/TPU复合材料薄膜的制备与性能[J].材料工程,2016,44(6):1-8. ZHENG H D.Fabrication and properties of 3D graphene oxide nanoribbons-carbon nanotubes/TPU composite films [J].Journal of Materials Engineering,2016,44(6):1-8.
[61] HAERI S Z,RAMEZANZADEH B,ASGHARI M.A novel fabrication of a high performance SiO2-graphene oxide (GO) nanohybrids:characterization of thermal properties of epoxy nanocomposites filled with SiO2-GO nanohybrids[J]. Journal of Colloid and Interface Science,2017,493:111-122.
[62] LI Z K,LANG W Z,MIAO W,et al.Preparation and properties of PVDF/SiO2@GO nanohybrid membranes via thermally induced phase separation method[J].Journal of Membrane Science,2016,511:151-161.
[63] RAMEZANZADEH B,HAERI Z,RAMEZANZADEH M.A facile route of making silica nanoparticles-covered graphene oxide nanohybrids(SiO2-GO);fabrication of SiO2-GO/epoxy composite coating with superior barrier and corrosion protection performance[J].Chemical Engineering Journal,2016,303:511-528.
[64] SCHRIVER M,REGAN W,GANNETT W J,et al.Graphene as a long-term metal oxidation barrier:worse than nothing[J].ACS Nano,2013,7(7):5763-5765.
[65] KRISHNAMOORTHY K,JEYASUBRAMANIAN K,PREMANATHAN M,et al.Graphene oxide nanopaint[J].Carbon,2014,72:328-337.
[66] MANGADLAO J D,De LEON A C C,FELIPE M J L,et al.Grafted carbazole-assisted electrodeposition of graphene oxide[J].ACS Appl Mater Inter,2015,7(19):10266-10274.
[67] LI Y,YANG Z,QIU H,et al.Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings[J].J Mater Chem A,2014,2(34):14139-14141.
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