Study on Properties and Synthesis of Polymer Schiff Base with Ferrocene and Bi-thiazole
XIONG Guo-xuan1,2, ZENG Dong-hai1,2, ZHOU Yu-fen1, LU Chun-hua2
1. Key Laboratory of Nuclear Resources and Environment(East China Institute of Technology), Ministry of Education, Nanchang, 330013, China; 2. Key Laboratory of New Mat-erials of Inorganic and Its Composites(Nanjing University of Technology), Nanjing, 210009,
Abstract：The DABT was synthesized with 2,3-butanedione,liquid dibromine,and thiourea and the ferrocenyl schiff base was synthesized by DABT and ferrocenecarboxaldehyde.Then polymer of ferrocenyl schiff base was prepared by the Friedel-Crafts method,their metal complexes were made by doping Fe2+,Ni2+ and Cu2+ sulfates.Their structures were characterized by infrared spectra and 1H-NMR spectra,conductivity and magnetism properties were measured with a Four-point probe Instrument and gouy magnetic balance.The experiment results showed that the synthetical product was polymer of ferrocenyl schiff base,its conductivity was 1.61?10-6 S·cm-1 belonging to semiconductor.Magnetism properties of metal complexes by doping Fe2+,Ni2+ and Cu2+ sulfates were obviously higher than polymer of un-doping,and properties of complexes by doping Cu2+ sulfate was best.These porperties indicated they can be applied as a new organic functional electromagnetism material.
熊国宣, 曾东海, 周瑜芬, 陆春华. 含二茂铁和双噻唑的聚合席夫碱的合成与性能研究[J]. 材料工程, 2008, 0(11): 1-4.
XIONG Guo-xuan, ZENG Dong-hai, ZHOU Yu-fen, LU Chun-hua. Study on Properties and Synthesis of Polymer Schiff Base with Ferrocene and Bi-thiazole. Journal of Materials Engineering, 2008, 0(11): 1-4.
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