莴笋叶制备多孔碳材料的优化设计及储锂性能

doi:10.11868/j.issn.1001-4381.2020.000960

Abstract
Figure/Table
References
Related Citation (4)

Download: PDF (19804 KB) HTML()
Export: BibTeX | EndNote (RIS)

Abstract

As a new energy material of environmental protection, biomass porous carbon material has been a research hotspot in recent years. In this paper, the porous carbon materials from lettuce leaves (LLs-temperature-proportional-activator) were prepared under different conditions, such as sintering temperature, the different activator, and the mass ratio of raw material and the activator, and the technological conditions were optimized through the discussion on their lithium storage performances. The results show that there are two broad and weak XRD peaks at 2θ=22°-26° and 2θ≈43° in each material, corresponding to the lattice plane (002) and (101), which indicates that the material is an amorphous carbon material with a certain degree of graphitization. In addition, the first discharge capacity of LLs-800-4R-K can reach 674.5 mAh/g. After 200 cycles, its discharge specific capacity can be maintained at 209.6 mAh /g, and the energy density is 146.8 Wh/kg. It illustrates that LLs-800-4R-K has good cycle performance and specific capacity. Thus, the optimum process conditions are as follows. The sintering temperature is at 800 ℃, KOH is used as activator, the mass ratio of raw material and the activator is 1:4.

Key words： porous carbon lettuce leaf process condition optimization design lithium storage performance

Received: 15 October 2020 Published: 18 April 2022

ZTFLH:

TM911.15

Corresponding Authors: Qiufen WANG,Juan MIAO E-mail: wqf@hpu.edu.cn;miaojuan@hpu.edu.cn

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Xin LI
	Qiufen WANG
	Juan MIAO
	Huifang TIAN
	Chengli ZHANG
	Yanlei ZHANG
	Zhilin ZHANG

Cite this article:

Xin LI,Qiufen WANG,Juan MIAO, et al. Lithium storage performance and optimal design of porous carbon materials with lettuce leaves[J]. Journal of Materials Engineering, 2022, 50(4): 53-61.

URL:

http://jme.biam.ac.cn/EN/10.11868/j.issn.1001-4381.2020.000960 OR http://jme.biam.ac.cn/EN/Y2022/V50/I4/53

Schematic diagram of porous carbon materials prepared from lettuce leaves

XRD patterns of lettuce leaves under different processing conditions

XPS patterns of LLs-800-4R-KOH and LLs-800-4R-CaCl₂
(a)survey; (b)C1s;(c)O1s;(d)Si2p;(e)N1s

SEM images of samples
(a), (b)LLs-800-4R-KOH; (c), (d)LLs-800-4R-CaCl₂

TEM images of samples
(a), (b)LLs-800-4R-KOH; (c), (d)LLs-800-4R-CaCl₂

BET test of lettuce leaves materials under different processing conditions
(a)nitrogen adsorption-desorption isotherms; (b)pore size distribution

Electrochemical properties of lettuce leaves under different processing conditions
(a)initial charge/discharge curves; (b)cycling performance; (c)rate capabilities; (d)power densities

EIS of lettuce leaves under different processing conditions
(a)different temperatures; (b)different mass ratios of raw material and KOH; (c)different activators

Relationship between ω and Z′ of the electrode at different charge states

SEM images after 200 cycles
(a)LLs-800-4R-KOH; (b)LLs-800-4R-CaCl₂

Electrochemical properties of lettuce leaves and buttonwood leaves
(a)initial charge/discharge curves; (b)cycling performance

1	CHAI Y , DU Y , LI L , et al. Dual metal oxides interconnected by carbon nanotubes for high-capacity Li- and Na-ion batteries[J]. Nanotechnology, 2020, 31 (21): 215402.
2	OH S H , PARK S M , KANG D W , et al. Fibrous network of highly integrated carbon nanotubes/MoO₃composite bundles anchored with MoO₃ nanoplates for superior lithium ion battery anodes[J]. Journal of Industrial and Engineering Chemistry, 2020, 83, 438- 448.
3	LI Y , ZHAO Y , MA C L , et al. Highly monodispersed graphene/SnO₂ hybrid nano sheets as bifunctional anode materials of Li-ion and Na-ion batteries[J]. Journal of Alloys and Compounds, 2020, 821, 153506.
4	LV S , LI C , MI J , et al. A functional activated carbon for efficient adsorption of phenol derived from pyrolysis of rice husk, KOH-activation and EDTA-4 Na-modification[J]. Applied Surface Science, 2020, 510, 145425.
5	NIE W , LIU X , XIAO Q , et al. Hierarchical porous carbon anode materials derived from rice husks with high capacity and long cycling stability for sodium-ion batteries[J]. Chem Electro Chem, 2020, 7 (3): 631- 641.
6	MARY A J C , NANDHINI C , BOSE A C . Hierarchical porous structured N-doped activated carbon derived from Helianthus Annuus seed as a cathode material for hybrid supercapacitor device[J]. Materials Letters, 2019, 256, 126617.
7	CAO L , WANG Y , HU H , et al. A N/S-codoped disordered carbon with enlarged interlayer distance derived from cirsium setosum as high-performance anode for sodium ion batteries[J]. Journal of Materials Science, 2019, 30 (24): 21323- 21331.
8	LI R , HUANG J , REN J , et al. A sandwich-like porous hard carbon/graphene hybrid derived from rapeseed shuck for high-performance lithium-ion batteries[J]. Journal of Alloys and Compounds, 2020, 818, 152849.
9	QI X , ZHANG H , LI C , et al. A simple and recyclable molten-salt route to prepare superthin biocarbon sheets based on the high water-absorbent agaric for efficient lithium storage[J]. Carbon, 2020, 157, 286- 294.
10	ZHAO G , CHENG Y , SUN P , et al. Biocarbon based template synthesis of uniform lamellar MoS₂ nanoflowers with excellent energy storage performance in lithium-ion battery and supercapacitors[J]. Electrochimica Acta, 2020, 331, 135262.
11	RASHEED T , NAVEED A , NABEEL F , et al. Bio-mass derived ultrahigh-energy storage porous graphitic carbon for advanced anode material in lithium battery[J]. Materials Chemistry and Physics, 2020, 242, 122543.
12	XIAO Q , LI G , LI M , et al. Biomass-derived nitrogen-doped hierarchical porous carbon as efficient sulfur host for lithium-sulfur batteries[J]. Journal of Energy Chemistry, 2020, 44, 61- 67.
13	FENG Y , TAO L , HE Y , et al. Chemical-enzymatic fractionation to unlock the potential of biomass-derived carbon materials for sodium ion batteries[J]. Journal of Materials Chemistry A, 2019, 7 (47): 26954- 26965.
14	DUTTA D P . Composites of Sb₂O₄ and biomass-derived mesoporous disordered carbon as versatile anodes for sodium-ion batteries[J]. Chemistry Select, 2020, 5 (6): 1846- 1857.
15	YU Z E , LYU Y , WANG Y , et al. Hard carbon micro-nano tubes derived from kapok fiber as anode materials for sodium-ion batteries and the sodium-ion storage mechanism[J]. Chem Commun, 2020, 56 (5): 778- 781.
16	ZHAO W , WEN J , ZHAO Y , et al. Hierarchically porous carbon derived from biomass reed flowers as highly stable Li-ion battery anode[J]. Nanomaterials, 2020, 10 (2): 346.
17	LI T , LIU Z , GU Y , et al. Hierarchically porous hard carbon with graphite nanocrystals for high-rate sodium ion batteries with improved initial Coulombic efficiency[J]. Journal of Alloys and Compounds, 2020, 817, 152703.
18	CHEN K , LI G , WANG Y , et al. High loading FeS₂ nanoparticles anchored on biomass-derived carbon tube as low cost and long cycle anode for sodium-ion batteries[J]. Green Energy & Environment, 2019, 5 (1): 50- 58.
19	WANG Z , ZHANG X , LIU X , et al. High specific surface area bimodal porous carbon derived from biomass reed flowers for high performance lithium-sulfur batteries[J]. J Colloid Interface Sci, 2020, 569, 22- 33.
20	DONG Y , JIANG X , MO J , et al. Hollow CuO nanoparticles in carbon microspheres prepared from cellulose-cuprammonium solution as anode materials for Li-ion batteries[J]. Chemical Engineering Journal, 2020, 381, 122614.
21	LUO J , ZHANG H , ZHANG Z , et al. In-built template synthesis of hierarchical porous carbon microcubes from biomass toward electrochemical energy storage[J]. Carbon, 2019, 155, 1- 8.
22	NANAJI K , RAO T N , VARADARAJU U V , et al. Jute sticks derived novel graphitic porous carbon nanosheets as Li-ion battery anode material with superior electrochemical properties[J]. International Journal of Energy Research, 2019, 44 (3): 2289- 2297.
23	WU X , JIANG J , WANG C , et al. Lignin-derived electrochemical energy materials and systems[J]. Biofuels Bioproducts & Biore fining-Biofpr, 2020, 14 (3): 650- 672.
24	JENSEN A C S , OLSSON E , AU H , et al. Local mobility in electrochemically inactive sodium in hard carbon anodes after the first cycle[J]. Journal of Materials Chemistry A, 2020, 8 (2): 743- 749.
25	YANG H , SUN X , ZHU H , et al. Nano-porous carbon materials derived from different biomasses for high performance supercapacitors[J]. Ceramics International, 2020, 46 (5): 5811- 5820.
26	YAN Z , YANG Q , WANG Q , et al. Nitrogen doped porous carbon as excellent dual anodes for Li- and Na-ion batteries[J]. Chinese Chemical Letters, 2020, 31 (2): 583- 588.
27	CHEN C , HUANG Y , ZHU Y , et al. Nonignorable Influence of oxygen in hard carbon for sodium ion storage[J]. ACS Sustainable Chemistry & Engineering, 2020, 8 (3): 1497- 1506.
28	ZHANG X , HUANG Q , ZHANG M , et al. Pine wood-derived hollow carbon fibers@NiO@rGO hybrids as sustainable anodes for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2020, 822, 153718.
29	GOMEZ-MARTIN A , MARTINEZ-FERNANDEZ J , RUTTERT M , et al. Porous graphene-like carbon from fast catalytic decomposition of biomass for energy storage applications[J]. ACS Omega, 2019, 4 (25): 21446- 21458.
30	ZHU Z , ZUO H , LI S , et al. Preparation of petaloid graphite nanoflakes in molten salt for high-performance lithium-ion batteries[J]. Ionics, 2020, 26 (7): 3351- 3358.
31	DING H , WANG G , QI Y , et al. Rambutan-inspired yolk-shell silica@carbon frameworks from biomass for long-life anode materials[J]. Chemistry Select, 2019, 4 (48): 14075- 14081.
32	LI Q , HUANG J , CAO L , et al. Revealing the sodium storage of surface C＝O structure in high performance Na-ion battery[J]. Journal of Electroanalytical Chemistry, 2019, 854, 113554.
33	ROMERO-CANO L A , GARCIA-ROSERO H , CARRASCO-MARIN F , et al. Surface functionalization to abate the irreversible capacity of hard carbons derived from grapefruit peels for sodium-ion batteries[J]. Electrochimica Acta, 2019, 326, 134973.
34	LIU Y , JIANG W , LIU M , et al. Ultrafine Co_1-xS attached to porous interconnected carbon skeleton for sodium-ion batteries[J]. Langmuir, 2019, 35 (50): 16487- 16495.
35	ZHAO G , YU D , ZHANG H , et al. Sulphur-doped carbon nanosheets derived from biomass as high-performance anode materials for sodium-ion batteries[J]. Nano Energy, 2020, 67, 104219.
36	LU X , XIANG K , WANG Y , et al. Selective preparation of graphene- and rope-like nano carbons from camellia wastes as high performance electrode materials for energy storage[J]. Journal of Alloys and Compounds, 2019, 811, 151616.