前过渡族元素<i>X</i>对TiAl<i>X</i>N涂层结构与性能的作用

doi:10.11868/j.issn.1001-4381.2021.000971

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Abstract

The TiAlN-based coatings have good mechanical and anti-oxidation properties. Therefore, they have been widely used in the surface protection of typical mechanical parts, such as aero-engine compressor blades, cutting tools and precision molds. However, with the continuous improvement of the performance requirements of mechanical parts, the service conditions of the coating are becoming more and more harsh, and the reliability and service life of the protective coating are facing more severe challenges. Addition of the pre-transitional elements into TiAlN coatings is an effective method to improve their properties in various aspects for a prolonged service life. In this work, based on the ternary TiAlN coating, the effects of the addition of pre-transitional elements X (X=V, Cr, Y, Zr, Nb, Mo, Hf, Ta and W) on the structures and properties of TiAlN coatings were systematically discussed with the aid of phase diagrams. Furthermore, the composition-structure-property relationship of TiAlXN coatings was tentatively established. In view of the problems faced by adding pre-transitional elements to TiAlN coating, such as lack of phase diagram calculation assistance, failure behavior of quaternary coating in extreme environment and high cost of coating preparation equipment, the prospects of developing quaternary phase diagram of TiAlXN system combined with phase field simulation, developing TiAlN based high entropy coating and vigorously developing coating preparation technology combined with the advantages of vapor deposition technology were put forward in this paper.

Key words： TiAlN coating pre-transitional element composition-structure-property relationship multi-component phase diagram

Received: 06 October 2021 Published: 18 July 2022

ZTFLH:

TG174.44

Corresponding Authors: Yong MAO E-mail: maoyong@ynu.edu.cn

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	Articles by authors
	Lu WANG
	Leilei CHEN
	Kai XU
	Ming LOU
	Yujie DU
	Yong MAO
	Keke CHANG

Cite this article:

Lu WANG,Leilei CHEN,Kai XU, et al. Effect of pre-transitional element X on structure and performance of TiAlXN coatings[J]. Journal of Materials Engineering, 2022, 50(7): 69-79.

URL:

http://jme.biam.ac.cn/EN/10.11868/j.issn.1001-4381.2021.000971 OR http://jme.biam.ac.cn/EN/Y2022/V50/I7/69

15]
(a)Gibbs free energy of fcc and hcp solid solution phase in TiAlN system; (b)metastable phase formation diagram calculated based on experimental data at 550 ℃
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Thermodynamic information of phase diagram calculated based on CALPHAD method^[15]
(a)Gibbs free energy of fcc and hcp solid solution phase in TiAlN system; (b)metastable phase formation diagram calculated based on experimental data at 550 ℃

56]
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H/E ratio, friction coefficient and wear rate of TiAlMoN coating change with Mo contents^[56]

Effect of pre-transitional elements on mechanical properties of TiAlN coatings

64]
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XRD patterns acquired after annealing for TiAlN, TiAlTa_0.05N and TiAlTa_0.10N coatings^[64]

Effect of pre-transitional elements on thermal stability of TiAlN coatings

75]
(a)TiAlCr_0.26N; (b)TiAlCr_0.42N; (c)TiAlCr_0.51N
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Cross section morphologies and EDX-ray scanning of TiAlCrN coatings after oxidation at 1000 ℃ for 2 h^[75]
(a)TiAlCr_0.26N; (b)TiAlCr_0.42N; (c)TiAlCr_0.51N

Effect of pre-transitional elements on oxidation resistance of TiAlN coatings

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