磷酸表面处理复合SiO<sub>2</sub>涂层对Ti-6Al-4V合金抗氧化性能的影响

doi:10.3969/j.issn.1001-4381.2013.05.013

Abstract
Figure/Table
References
Related Citation (8)

Download: PDF (3209 KB) HTML()
Export: BibTeX | EndNote (RIS)

Abstract The effects of phosphoric acid chemical treatment and composite SiO₂ coating on oxidation resistance of Ti-6Al-4V alloy were investigated. Results show that, the average oxidation rate of the Ti-6Al-4V alloy treated by phosphoric acid decreases nearly by 75% in comparison with the blank samples at 600℃ after 24h oxidation in air. The oxidation rate of composite SiO₂ coating sample reduces one order of magnitude in comparison with the blank sample oxidation for 100h at the same condition. The composite SiO₂ coating has better anti-oxidation ability than phosphoric acid treatment. The compactness of the oxide scale of the composite SiO₂ coating and the phosphoric acid treatment samples increases, and a good adhesion with the substrate is shown, the volume fractions of TiO₂ in oxidation films reduce both phosphoric acid chemical treatment and composite SiO₂ coating samples. The in-diffusion of O and out-diffusion of Ti are restrained because of the formation of TiP₂O₇ phase and deposit SiO₂ coating.

Key words： phosphoric acid chemical treatment SiO₂ coating isothermal oxidation Ti-6Al-4V alloy

Received: 05 March 2012 Published: 20 May 2013

ZTFLH:

U177.2

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors

Cite this article:

URL:

http://jme.biam.ac.cn/EN/10.3969/j.issn.1001-4381.2013.05.013 OR http://jme.biam.ac.cn/EN/Y2013/V0/I5/62

[1] 陈玉勇, 杨非, 孔凡涛,等. V/Nb对Ti-45Al-9(V,Nb,Y)合金抗氧化性能的影响[J]. 稀有金属材料与工程, 2011, 40(3): 429-432. CHEN Y Y, YANG F, KONG F T, et al. Effect of V/Nb on the oxidation resistance of Ti-45Al-9(V,Nb,Y) alloy [J]. Rare Metal Materials and Engineering, 2011, 40(3): 429-432.

[2] XIONG Y M, ZHU S L, WANG F H. The oxidation behavior and mechanical performance of Ti60 alloy with enamel coating [J]. Surface and Coatings Technology, 2005, 190(2-3): 195-199.

[3] ZHANG Z X, DONG H, BELL T, et al. The effect of gold pre-deposition on the oxidation behavior of CPTi and Ti6Al4V alloy [J]. Oxidation of Metals, 2006, 66(1-2): 91-106.

[4] VICKRIDGE I C, JOHNSON P B, GILBERD P W, et al. High dose He implantation in two Ti alloys: effects on structure and thermal oxidation [J]. Nuclear Instruments and Methods in Physics Research B, 1998, 136-138(5): 1068-1073.

[5] 王振霞, 王文波, 贺志勇, 等. 钛(TA2)及钛合金(TC4)表面等离子渗Nb研究[J]. 热加工工艺, 2005, 28(9):1-2. WANG Z X, WANG W B, HE Z Y, et al. Study of plasma niobium surface alloying on titanium(TA2) and titanium alloys(TC4) [J]. Hot Working Technology, 2005, 28(9):1-2.

[6] 李佳, 夏长清, 古一, 等. 真空热处理对Ti6A14V基体／NiCrAlY涂层体系组织结构及元素扩散行为的影响[J]. 中国有色金属学报, 2004, 14(11): 1889-1894. LI J, XIA C Q, GU Y, et al. Effect of vacuum heat treatment on microstructure and elements diffusion behavior of NiCrAlY coating on Ti6Al4V [J]. The Chinese Journal of Nonferrous Metals, 2004, 14(11): 1889-1894.

[7] 潘晓龙, 李争显, 黄春良, 等. 钛合金表面熔结AlSiCrTi涂层的高温性能[J]. 热加工工艺, 2007, 36(24): 68-73. PAN X L, LI Z X, HUANG C L, et al. High-temperature properties of AlSiCrTi coating on Ti alloy surface prepared by slurry roasting process [J]. Hot Working Technology, 2007, 36(24): 68-73.

[8] 梁城, 高万振, 潘邻, 等. 钛合金表面激光熔覆Ni基梯度涂层的研究[J].材料保护, 2006, 39(11):32-34. LIANG C, GAO W Z, PAN L, et al. Microstructure and microhardness of laser cladding nickel-based gradient coating on Ti6Al4V alloy [J]. Materials Protection, 2006, 39(11):32-34.

[9] YU Cun-zhen, ZHU Sheng-long, WEI De-zhou, et al. Amorphous sol-gel SiO₂ film for protection of Ti6Al4V alloy against high temperature oxidation [J]. Surface and Coatings Technology, 2007, 201(12): 5967-5972.

[10] ZHU Ming, LI Mei-shuan, LI Ya-li, et al. Influence of sol-gel derived Al₂O₃ film on the oxidation behavior of a Ti₃Al based alloy [J].Materials Science and Engineering A, 2006, 415(1-2): 177-183.

[11] HAUGSRUD R. On the influence of sol-gel derived CeO₂ coatings on high-temperature oxidation of Co, Ni and Cu [J]. Corrosion Science, 2002, 44(7): 1569-1583.

[12] KLEININ L C. Sol-gel Technology for Thin Films, Fibers, Preforms, Electronics and Speciality Shapes [M]. New York: Noyes Publications, 1986. 17.

[13] BROU S Y, SIAB R, BONNET G, et al. On dipping of γ-TiAl in low-concentration phosphoric acid solution and consecutive oxidation resistance at 800℃ [J]. Scripta Materialia, 2007, 56(6): 517-520.

[14] ANDERSEN K A M, NORBY P, HANSON J C, et al. Preparation and characterization of a new 3-dimensional zirconium hydrogen phosphate, τ -Zr(HPO₄)₂ determination of the complete crystal structure combining synchrotron X-ray single-crystal diffraction and neutron powder diffraction [J]. Inorganic Chemistry, 1998,37(5): 876-881.

[15] DU H L, DATTA P K, LEWIS D B, et al. Air oxidation behaviour of Ti6Al4V alloy between 650 and 850℃ [J]. Corrosion Science, 1994, 36(4): 631-642.

[16] 徐仰涛, 夏天东, 闫健强, 等. 合金元素对Co-Al-W合金高温氧化行为的影响[J].中国有色金属学报, 2010, 20(11): 110-117. XU Y T, XIA T D, YAN J Q, et al. Effect of alloying elements on oxidation behavior of Co-Al-W alloys at high temperature [J]. The Chinese Journal of Nonferrous Metals, 2010, 20(11): 110-117.

[17] BROU S Y, BONNET G, GROSSEAU-POUSSARD J L. Formation and evolution of phosphorus-containing species during high-temperature oxidation of TiAl dipped in a low-concentrated phosphoric acid solution [J]. Surface and Coatings Technology, 2009, 203(9): 1138-1143.

[18] HAUGSRUD R, GUNNAES A E, SIMON C R. Effects of sol-gel-derived silica coatings on high-temperature oxidation of Ni [J]. Oxidation of Metals, 2001, 56(5-6): 453-465.