新型复合纳米材料用于光催化降解染料废水的研究进展

doi:10.11868/j.issn.1001-4381.2020.001102

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Abstract

Photocatalytic technology is an effective way to solve the two major problems of environmental problems and energy crisis in today's human society. Semiconductor materials were favored in early research. However, a single semiconductor photocatalyst has disadvantages such as poor response to visible light and easy recombination of electron-hole pairs. Photocatalytic technology has low efficiency in the application of dye wastewater degradation. Therefore, researchers have conducted in-depth studies on the new composite nanomaterials as photocatalysts to degrade dye wastewater. The research progress and main results of three new composite nanomaterials of graphene, metal organic framework, and carbon quantum dots for photocatalytic degradation of pollutants in dye wastewater were introduced in this article. According to the idea of design and upgrading of composite nanomaterials, the preparation methods of some new composite nanomaterials were briefly described, and the degradation efficiency of target pollutants was analyzed. By summarizing the performance of different photocatalytic materials to degrade pollutants in water, the future development trend was prospected. The future development trend and research focus of new composite nanomaterials in the direction of photocatalysis are targeted treatment of wastewater and industrialization.

Key words： photocatalysis composite nanomaterial graphene metal organic framework carbon quan-tum dot

Received: 03 December 2020 Published: 18 July 2022

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Corresponding Authors: Changzheng WANG E-mail: changzhwang@163.com

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	Articles by authors
	Mingtai ZHANG
	Shaobin YU
	Xicheng LI
	Cuimin FENG
	Mengtong SHI
	Changzheng WANG
	Qiang WANG

Cite this article:

Mingtai ZHANG,Shaobin YU,Xicheng LI, et al. Research progress of new composite nanomaterials for photocatalytic degradation in dye wastewater[J]. Journal of Materials Engineering, 2022, 50(7): 59-68.

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http://jme.biam.ac.cn/EN/10.11868/j.issn.1001-4381.2020.001102 OR http://jme.biam.ac.cn/EN/Y2022/V50/I7/59

Schematic diagram of photocatalytic reaction mechanism

New photocatalytic materials
(a)flake graphene; (b)MOFs; (c)MOF@graphene; (d)carbon quantum dots

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SEM images of TiO₂ (a), GO(b), TiO₂/GO nanocomposites(c) and mechanism diagram of photocatalytic degradation of methylene blue by TiO₂/GO nanocomposite(d)^[22]

Photocatalytic performance of new graphene composite nanomaterials

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SEM images of MOF-5(a), MOF-74(b), ZIF-8(c), ZnO/CMOF-5(d), ZnO/CMOF-74(e) and ZnO/CZIF-8(f)^[38]

Photocatalytic performance of MOFs new composite nanomaterials

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TEM images of TiO₂ (a), NP-CQDs/TiO₂ (b) and photocatalytic performance of NP-CQDs/TiO₂, TiO₂ and NP-CQDs(c)^[52]

Photocatalytic performance of CQDs new composite nanomaterials

Photocatalytic performance of some new composite nanomaterials

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