研究了Ni-Cu-P化学镀液主要成分、PH值、温度以及时间等工艺参数对化学沉积Ni-Cu-P合金镀层成分及镀速的影响。通过选择适当的镀液成分及工艺参数,得到了Cu含量从0到56.18wt%的Ni-Cu-P合金镀层。利用EDS和XRD研究了镀液中硫酸铜浓度对Ni-Cu-P合金镀层组织结构的影响。在硫酸铜浓度低于3g/L时,Ni-Cu-P合金镀层中P含量高于7.05wt%,合金镀层是非晶态结构。
Abstract
The effects of the deposition parameters such as bath composition, PH, temperature and time on the element contents and deposition rate of the electroless Ni-Cu-P deposits were studied. The electroless Ni-Cu-P deposits with various copper contents from 0 to 56.18 wt% were prepared through choosing the proper deposition parameters. The effect of copper sulfate concentration in the bathon the microstructure of the electroless Ni-Cu-P deposits was studied by using EDS and XRD. Ni-Cu-P deposits with phosphorus content more than 7.05wt% were amorphous, in the situation, the copper sulfate concentration in the bath was lower than 3g/L.
关键词
化学沉积 /
Ni-Cu-P合金 /
工艺 /
结构
{{custom_keyword}} /
Key words
electroless /
Ni-Cu-P alloys /
technology /
microstructure
{{custom_keyword}} /
中图分类号:
TQ153
{{custom_clc.code}}
({{custom_clc.text}})
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] K H Hur, J H Jeong, D N Lee. Effect of Annealing on Magnetic Properties, Microstructure of Electroless Nickel-Copper-Phosphorus Alloy Deposits[J]. J Mater Sci, 1991, 26: 2037-2044.
[2] N Krasteva,V Fotty, S Armyanov. Thermal Stability of Ni-P and Ni-Cu-P Amorphous Alloys[J].J Electrochem Soc, 1994, 141 (10): 2864-2867.
[3] Hidemi Nawafune,Takashi Uegaki, et al. Preparation and Electrical Resistance Characteristics of Electroless Copper-Nickel Alloy Deposits[J]. Trans. IMF,1998, 76 (6): 231-234.
[4] Y W Wang, C G Xiao, Z G Deng. Structure and Corrosion Resistance of Electroless Ni-Cu-P[J]. Plat Surf Finish, 1992, 79: 57-59.
[5] G O Mallory, J B Hajdu. Electroless Plating Fundermentals,Applications, Chap.1[M]. Orlando, FL: AESF, 1990.
[6] G G Gawrilov. Chemical (Electroless) Nickel-Plating, Chap. 6 and 7[M]. Great Britain: Portcullis Press Ltd, 1979.
[7] D A Jones. Principles and Prevention of Corrotion, Chap. 2[M]. New York: Macmillan Publishing Company, 1992.
[8] M Cherkaoui, A Srhiri, E Chassaing. Electroless Deposition of Ni-Cu-P Alloys[J]. Plat Surf Finish, 1992, 79: 68-71.
[9] E Chassaing, K Vu Quang,R Wiart. Mechanism of Copper-Nickel Alloy Electrodeposition[J]. J Appl Electrochem, 1987, 17: 1267-1280.
[10] Stability Constants. Special Publication. No. 25[M]. London: The Chemical Soc, 1971.
[11] G O Mallory,J B Hajdu. Electroless Plating Fundermentals and Applications, Chap. 4[M]. Orlando, FL: AESF, 1990.
{{custom_fnGroup.title_cn}}
脚注
{{custom_fn.content}}
基金
国家九五科学仪器科技攻关资助项目96-A23-05-01
{{custom_fund}}