利用二次电子成像技术分析了Galvalume镀层在NaCl,Na2SO4以及NaCl+Na2SO4介质中腐蚀产物的形貌,并用X射线衍射技术分析了各种腐蚀产物的化学组成.结果表明,在NaCl介质中的腐蚀产物主要为结构疏松的晶态物质,对镀层基本无保护作用;而在Na2SO4以及NaCl+Na2SO4介质中的腐蚀产物主要为结构致密的非晶态物质,对镀层具有较强的保护作用,说明SO42-的存在是形成致密非晶产物的根本原因.
Abstract
The structure and composition of Galvalume in different solutions such as NaCl, Na2SO4 and NaCl+Na2SO4 were studied by electron micro-probe and X-ray diffractometer respectively. The results show that the corrosion product in NaCl solution is mainly crystal compound which is not protective to coating, the corrosion product in Na2SO4 and NaCl+Na2SO4 solution is mainly amorphous which is protective to coating. So the amorphous structure is caused by the existence of SO42-.
关键词
Galvalume /
腐蚀产物 /
X射线衍射技术 /
二次电子成像技术
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Key words
Galvalume /
corrosion product /
XRD /
SEI
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中图分类号:
TG17
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参考文献
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脚注
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