用放大实验制得了PEN-PET共聚酯,通过双轴拉伸制成薄膜,对薄膜的干热收缩率、声速取向因子和力学性能进行了研究,同时研究了萘二甲酰含量、拉伸工艺等的影响规律.结果表明,随着PEN含量的增加,共聚酯薄膜的干热收缩率降低,声速取向因子增大,断裂伸长率减小.
Abstract
Several PEN-PET copolyester films were prepared. The shrinking property, the sonic orientation property and mechanical property of these films were studied.The results show that the increasing of the PEN content results in decrease of the shrinking,increase of the oriental factor, and decrease of the breaking elongation.
关键词
聚对苯二甲酸乙二醇酯 /
聚2,6-萘二甲酸乙二醇酯 /
共聚酯 /
薄膜 /
性能
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Key words
poly(ethylene terephthalate) /
poly(ethylene 2,6-naphthalate) /
PEN-PET /
film /
properties
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中图分类号:
TQ323
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参考文献
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[2] RAFLER G,REINISCH G,BONATZ E.Kinetics,mass transp-ort and thoughts about the mechanism of the formation of polyethylene terephthalate by metal ion catalysis[J].Acta Chem(Budapest),1974,81:253-267.
[3] JABARIN S A,LOFGREN E A.Thermal stability of polyethyl-ene terephthalate[J].Polym Eng Sci,1984,24:1056-1063.
[4] WANG C S,SUN Y M.Studies on the formation of PEN I kinetic aspects of catalyzed reaction in transesterification of dimethylnaphthalate with ethylene glycol[J].J Polym Sci Part A:Polym Chem,1994,32:1295-1304.
[5] WANG C S,SUN Y M.Studies on the formation of PEN II Polymerization of bis(hydroxyethyl)naphthalate by various metallic catalysts[J].J Polym Sci Part A:Polym Chem,1994,32:1305-1315.
[6] BUCHNER S,WISWE D,ZACHMANN H G.Kinetics of cryst-allization and melting behaviour of poly(ethylene naphthalene-2,6-dicarboxylate)[J].Polymer,1989,30:480-488.
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脚注
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