混合比及后处理对混合环氧/热塑性树脂复相体系动态力学特征的影响

唐邦铭, 安学锋, 益小苏

材料工程 ›› 2004, Vol. 0 ›› Issue (9) : 19-22,26.

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PDF(239 KB)
材料工程 ›› 2004, Vol. 0 ›› Issue (9) : 19-22,26.
研究与应用

混合比及后处理对混合环氧/热塑性树脂复相体系动态力学特征的影响

  • 唐邦铭, 安学锋, 益小苏
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Effects of Blending Ratios and Post-curing Process on Dynamic Properties of Epoxies and Thermoplastic Multi-phase System

  • TANG Bang-ming, AN Xue-feng, YI Xiao-su
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摘要

以热塑性树脂(TP)/双酚A二缩水甘油醚(DGEBA)及二苯基甲烷四缩水甘油胺(TGMDA)混合环氧树脂的复相体系为基础,采用动态力学分析手段研究了在相同热塑性树脂含量的条件下,混合比例对混合环氧/热塑性树脂的动态力学性能中tanδ曲线的特征峰位置、峰形等的影响,以及在经高温后处理后曲线特征峰的变化.结合树脂断口分析,结果显示:混合环氧在固化反应过程中对热塑性树脂的高粘度高阻碍性的响应是不同的,tanδ曲线上的主峰主要由TP的转变构成而次级峰则主要由DGEBA环氧固化物的转变构成.高温后处理使树脂体系有利于分相及固化网络的完善.在复相体系中,连续相主要由TP及TGMDA环氧固化网络构成,DGEBA环氧主要存在于分散相中.

Abstract

The tangent delta peaks of dynamic mechanical thermal analysis(DMTA)for the blends of epoxies and thermoplastic are analyzed.Effects of blending ratios and the post-curing process on peaks was studied with the help of SEM.Results show that the primary peaks of tangent delta of DMTA mainly response to the segment motions of thermoplastic in a blend and the secondary peaks mainly to that of the DGEBA cured nets.The TGMDA is helpful for the separation of phases in the blends.DGEBA otherwise is helpful for the compatibility.High temperature post-curing prompts the cuing nets construction more perfectly and the phase separation more completely.In the blends the continuous phase mainly consists of a mass of thermoplastic and some TGMDA,DGEBA mainly exists in the dispersed phase.

关键词

动态力学分析 / 环氧/热塑性树脂复相体系 / 混合比 / 后处理

Key words

dynamic mechanical thermal analysis / epoxy/thermoplastic multi-phase system / blending ratio / post-curing

引用本文

导出引用
唐邦铭, 安学锋, 益小苏. 混合比及后处理对混合环氧/热塑性树脂复相体系动态力学特征的影响[J]. 材料工程, 2004, 0(9): 19-22,26
TANG Bang-ming, AN Xue-feng, YI Xiao-su. Effects of Blending Ratios and Post-curing Process on Dynamic Properties of Epoxies and Thermoplastic Multi-phase System[J]. Journal of Materials Engineering, 2004, 0(9): 19-22,26
中图分类号: TB332   

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