热浸镀锌铝镁钢板镀层组织及腐蚀性能研究

吕家舜, 李锋, 杨洪刚, 康永林

材料工程 ›› 2012, Vol. 0 ›› Issue (10) : 89-93.

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PDF(4694 KB)
材料工程 ›› 2012, Vol. 0 ›› Issue (10) : 89-93.
表面工程

热浸镀锌铝镁钢板镀层组织及腐蚀性能研究

  • 吕家舜1,2, 李锋2, 杨洪刚2, 康永林1
作者信息 +

Research on Coating Microstructure and Corrosion Behavior of Galvanized Zn-Al-Mg Coated Steel Sheet

  • LU Jia-shun1,2, LI Feng2, YANG Hong-gang2, KANG Yong-lin1
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文章历史 +

摘要

锌铝镁镀层钢板比普通的镀锌钢板具有更加优异的耐腐蚀性能,本研究利用热镀锌模拟器在实验室制备了热浸镀锌铝镁合金镀层钢板,利用扫描电子显微镜SEM观察了镀层表面及截面的微观组织,利用能谱EDS进行了微区成分分析;利用电子探针EPMA对镀层的表面及截面进行了元素分布分析,利用盐雾试验方法对锌铝镁镀层钢板的耐腐蚀性能进行了研究,利用X射线衍射分析了镀层及镀层盐雾试验腐蚀产物的物相组成。结果表明,热浸镀锌铝镁镀层钢板比普通镀锌板具有更加细致的组织,镀层主要由MgZn2与含Al富锌相构成的共晶相和MgZn2组成,另外还存在一些粒状富铝相和块状富锌相,Zn-Al-Mg镀层比普通镀锌板具有更强的耐腐蚀性能,最后分析了锌铝镁镀层钢板的耐盐雾腐蚀机理。

Abstract

Galvanized Zn-Al-Mg coated steel sheet offer higher corrosion resistance than conventionally galvanized steel because aluminum magnesium has a positive effect on the corrosion resistance of steel coating. In this research, Galvanized Zn-Al-Mg coated steel sheet was prepared in laboratory by hot dip simulator. By SEM and EDS, the surface and cross section microstructure Zn-Al-Mg coating was analyzed. The distribution of elements in coating includes Zn, Al, Mg and Fe was observed by EPMA. The anti-corrosion capability of Zn-Al-Mg coating was studied by salt spray test. Coating itself and the erode production was inspect by X-ray diffraction. It was proved that the Zn-Al-Mg coating has finer microstructure, and has even more excellent corrosion resistance. The protection mechanism of Zn-Al-Mg coating steel sheet in salt spray test was analyzed.

关键词

热浸镀 / 锌铝镁镀层 / 盐雾试验 / 耐腐蚀性能

Key words

galvanized / Zn-Al-Mg coating / salt spray test / corrosion behavior

引用本文

导出引用
吕家舜, 李锋, 杨洪刚, 康永林. 热浸镀锌铝镁钢板镀层组织及腐蚀性能研究[J]. 材料工程, 2012, 0(10): 89-93
LU Jia-shun, LI Feng, YANG Hong-gang, KANG Yong-lin. Research on Coating Microstructure and Corrosion Behavior of Galvanized Zn-Al-Mg Coated Steel Sheet[J]. Journal of Materials Engineering, 2012, 0(10): 89-93
中图分类号: TG174.433   

参考文献

[1] SPEER J G, ASSUNCAO F C R, MATLOCK D K, et al. The "quenching and partitioning" process: background and recent progress[J]. Materials Research, 2005, 8(4): 417-423.

[2] LI Y.Formation of nano-crystalline corrosion products on Zn-Al alloy coating exposed to seawater[J]. Corrosion Science, 2001,43(9):1793-1800.

[3] ROCCO A M, NOGUEIRA T M C, SIMO R A, et al. Evaluation of chromate passivation and chromate conversion coating on 55% Al-Zn coated steel[J]. Surface and Coatings Technology, 2004,179(2-3): 135-144.

[4] KONG F R, SANTHANAKRISHNAN S, LIN D CH, et al. Modeling of temperature field and grain growth of a dual phase steel DP980 in direct diode laser heat treatment[J]. Journal of Materials Processing Technology, 2009,209(18-19):5996-6003.

[5] SCHUERZ S, FLEISCHANDERL M, LUCKENEDER G H, et al. Corrosion behaviour of Zn-Al-Mg coated steel sheet in sodium chloride-containing environment[J]. Corrosion Science,2009, 51(10): 2355-2363.

[6] ELVINS J, SPITTLE J A, SULLIVAN J H, et al. The effect of magnesium additions on the microstructure and cut edge corrosion resistance of zinc aluminum alloy galvanised steel[J]. Corrosion Science, 2008, 50(6):1650-1658.

[7] HIDESHI F, RIE K, HIROSHI I. Hot-dip Zn-5% Al alloy-coated steel sheets[J]. JFE Technical Report, 2009,14(12):41-45.

[8] BRUYCKER E D, ZERMOUT Z, COOMAN B C D. Zn-Al-Mg coatings: thermodynamic analysis and microstructure related properties[J]. Materials Science Forum, 2007,539-543: 1276-1281.

[9] BRUYCKER E D, COOMAN B C D, MEYER M D. Experimental study and microstructure simulation of Zn-Al-Mg coatings[J]. Revue de Metallurgie, 2005, 102(7-8):543-550.

[10] KOMATS U A, IZUTAN I H. Corrosion resistance and protection mechanism of hot-dip Zn-Al-Mg alloy coated steel sheet under accelerated corrosion environment[J]. Journal of the Iron and Steel Institute of Japan, 2000,86(8):36-43.
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