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材料工程  2014, Vol. 0 Issue (11): 85-89    DOI: 10.11868/j.issn.1001-4381.2014.11.015
  测试与表征 本期目录 | 过刊浏览 | 高级检索 |
交流电频率对X65钢在CO32-/HCO3-溶液中腐蚀行为的影响
朱敏, 杜翠薇, 李晓刚, 刘智勇, 赵天亮, 李建宽, 胡杰珍
北京科技大学 材料科学与工程学院, 北京 100083
Effect of Alternating Current Frequency on Corrosion Behavior of X65 Steel in CO32-/HCO3- Solution
ZHU Min, DU Cui-wei, LI Xiao-gang, LIU Zhi-yong, ZHAO Tian-liang, LI Jian-kuan, HU Jie-zhen
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
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摘要 通过极化曲线测试、浸泡实验和表面分析技术研究了不同交流电频率对X65钢在CO32-/HCO3-溶液中腐蚀行为的影响。研究表明:在30~1000Hz范围内,除200Hz外,低交流电频率时(≤300Hz),随交流电频率的减小,其钝化区宽度明显变窄,点蚀击破电位负移,维钝电流密度增大,临界钝化电流密度增大;高交流电频率时(>300Hz),频率对X65钢的钝性影响很弱。X65钢的腐蚀速率随交流电频率的增加而减小,低交流电频率作用时,X65钢的腐蚀速率随交流电频率增加快速减小,高交流电频率时,其腐蚀速率随交流电频率的增加略减小。
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朱敏
杜翠薇
李晓刚
刘智勇
赵天亮
李建宽
胡杰珍
关键词 X65钢交流电频率腐蚀行为腐蚀速率    
Abstract:Effect of alternating current(AC) frequency (30-1000Hz) on corrosion behavior of X65 steel in concentrated carbonate/bicarbonate solution was studied by potentiodynamic polarization curve measurements, immersion tests and surface characterization technique. The results show that in the range of 30-1000Hz, except 200Hz, at low AC frequency (≤300Hz), as AC frequency decreases, the passivation region become obviously narrow, the broken potential of pitting corrosion shifts negatively, the passive current density increases and the critical passivation current density increases; at high AC frequency(>300Hz), frequency has a slight effect on the passivity of X65 steel. The corrosion rates of X65 steel decrease with the AC frequency increase, at low AC frequency, the corrosion rates of X65 steel decrease rapidly as AC frequency increases, while at high AC frequency, the corrosion rates decrease slightly as AC frequency increases.
Key wordsX65 steel    AC frequency    corrosion behavior    corrosion rate
收稿日期: 2013-04-04      出版日期: 2014-11-20
中图分类号:  TG171  
基金资助:国家自然科学基金(51371036);国家自然科学基金重点项目(51131001)
通讯作者: 杜翠薇(1972-), 女, 教授, 主要从事材料的腐蚀与防护, 联系地址:北京市海淀区学院路30号北京科技大学材料科学与工程学院 (100083).     E-mail: zmii2009@163.com
引用本文:   
朱敏, 杜翠薇, 李晓刚, 刘智勇, 赵天亮, 李建宽, 胡杰珍. 交流电频率对X65钢在CO32-/HCO3-溶液中腐蚀行为的影响[J]. 材料工程, 2014, 0(11): 85-89.
ZHU Min, DU Cui-wei, LI Xiao-gang, LIU Zhi-yong, ZHAO Tian-liang, LI Jian-kuan, HU Jie-zhen. Effect of Alternating Current Frequency on Corrosion Behavior of X65 Steel in CO32-/HCO3- Solution. Journal of Materials Engineering, 2014, 0(11): 85-89.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2014.11.015      或      http://jme.biam.ac.cn/CN/Y2014/V0/I11/85
[1] WAKELIN R G, SHELDON C. Investigation and mitigation of AC corrosion on a 300 mm diameter natural gas pipeline[A]. Corrosion/2004[C]. Houston: NACE, 2004.
[2] 丁清苗. 电化学方法研究交流干扰对埋地管线的影响[D]. 北京: 中国石油大学,2010.DING Qing-miao. Electrochemical study on the impact of the AC to buried pipeline[D]. Beijing: China University of Petroleum,2010.
[3] WAKELIN R G, GUMMOW R A, SEGALL S M. AC corrosion-case histories test procedures, mitigation[A]. Corrosion/1998[C].Houston: NACE,1998.
[4] GUMMOW R A, WAKELIN R G, SEGALL S M. AC corrosion-a new challenge to pipeline integrity. Corrosion/1998.Houston: NACE,1998.
[5] ROGER F. Testing and mitigation of AC corrosion on 8 line: a field study[A]. Corrosion/2004[C].Houston: NACE,2004.
[6] 董亮, 路民旭, 杜艳霞, 等. 埋地管道交流腐蚀的研究进展[J]. 中国腐蚀与防护学报, 2011,31(3):173-178.DONG Liang, LU Min-xu, DU Yan-xia,et al. Investigation progress of alternating current corrosion on buried pipelines[J]. J Chin Soc Corros Prot, 2011,31(3):173-178.
[7] GOIDANICH S,LAZZARI L,ORMELLESE M. AC corrosion-part 2:parameters influencing corrosion rate[J]. Corros Sci,2010, 52(3): 916-922.
[8] FU A Q, CHENG Y F. Effects of alternating current on corrosion of a coated pipeline steel in a chloride-containing carbonate/bicarbonate solution [J]. Corros Sci,2010, 52(2): 612-619.
[9] FUNK D, PRINZ W, SCHONEICH H G. Investigations of AC corrosion in cathodically protected pipes [J]. 3R International, 1992, 31(6): 336-341.
[10] CHIN D T, FU T W. Corrosion by alternating current: a study of the anodic polarization of mild steel in Na2SO4 solution[J]. Corrosion, 1979, 35(11): 514- 523.
[11] DYER C K, ALWITT R S. Surface changes during AC etching of aluminum [J]. J Electrochem Soc, 1981, 128(2): 300-305.
[12] CHIN D T, SACHDEY P. Corrosion by alternating current: polarization of mild steel in neutral electrolytes [J]. J Electrochem Soc, 1983, 130(8): 1714-1718.
[13] KULMAN F E. Effects of alternating currents in causing corrosion [J]. Corrosion, 1961, 17(3): 34-35.
[14] BERTOCCI U. AC induced corrosion: the effect of an alternating voltage on electrodes under charge transfer control[J]. Corrosion, 1979, 35(5): 211-215.
[15] JONES D A. Effect of alternating current on corrosion of low alloy and carbon steels [J]. Corrosion, 1978, 34(12): 428-433.
[16] GOIDANICH S, LAZZARI L,ORMELLESE M, et al. Influence of AC on corrosion kinetics for carbon steel, zinc and copper[A]. Corrosion/2005[C]. Houston: NACE, 2005.
[17] 曹楚南. 腐蚀电化学原理[M]. 北京: 化学工业出版社, 2004. CAO Chu-nan. Principles of Electrochemistry of Corrosion[M]. Beijing: Chemistry Industry Press, 2004.
[18] NIELSEN L V,GALSGAARD F. Sensor technology for on-line monitoring of AC-induced corrosion along pipelines[A]. Corrosion/2005[C]. Houston: NACE, 2005.
[19] PANOSSIAN Z, FILHO S E, DE ALMEIDA N L, et al. Effect of alternating current by high power lines voltage and electric transmission systems in pipelines corrosion[A]. Corrosion/2009[C]. Houston: NACE, 2009.
[20] 聂向晖,李云龙,李记科,等. Q235碳钢在滨海盐土中的腐蚀形貌、产物及机理分析[J].材料工程, 2010, (8): 24-33. NIE Xiang-hui, LI Yun-long, LI Ji-ke, et al. Morphology, products and corrosion mechanism analysis of Q235 carbon steel in sea-shore salty soil [J]. Journal of Materials Engineering, 2010, (8): 24-33.
[21] FERNANDES S Z, MEHENDALE S G, VENKATACHALAM S. Influence of frequency of alternating current on the electrochemical dissolution of mild steel and nickel[J]. J Appl Electrochem, 1980,10(5):649-654.
[22] 李运超, 严川伟, 段红平. 交变电场对不锈钢钝性和钝化膜性质的影响[J]. 中国腐蚀与防护学报, 2002, 22(6): 375-379. LI Yun-chao, YAN Chuan-wei, DUAN Hong-ping. Effect of alternating voltage modulation on the passivity and the feature of passive film of stainless steels[J]. J Chin Soc Corros Prot, 2002, 22(6): 375-379.
[23] 李自力, 杨燕. 金属管道交流腐蚀研究新进展[J]. 石油学报,2012,33(1):164-171. LI Zi-li, YANG Yan. New progress in studying alternating current corrosion on metal pipelines[J]. Acta Petrol Sin,2012,33(1):164-171.
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