热分解法制备Ni0.5Zn0.5Fe2O4纳米颗粒

doi:10.11868/j.issn.1001-4381.2015.001062

摘要
参考文献
相关文章
Metrics

全文: PDF(3141 KB) HTML()
输出: BibTeX | EndNote (RIS)

摘要采用热分解法制备Ni_0.5Zn_0.5Fe₂O₄纳米颗粒，研究表面活性剂用量、回流温度和回流时间对产物尺寸、形貌以及分散性的影响。通过X射线衍射仪（XRD）、透射电子显微镜（TEM）和振动样品磁强计（VSM）对样品的结构、形貌与磁性能进行了表征。结果表明：增加表面活性剂的用量，产物的粒径减小，分散性明显提高，而提高回流温度和延长回流时间则会使产物粒径增加，但粒径分布也会变宽。在三辛基氧化膦（TOPO）用量为0.6mmol，260℃回流1h条件下制备产物的饱和磁化强度为49.38A·m²/kg，矫顽力为7143.20A/m，剩余磁化强度为5.76A·m²/kg，表现为亚铁磁性。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	赵海涛
	马瑞廷
	刘瑞萍

关键词 ：热分解法, Ni-Zn铁氧体, 分散性, 磁性能

Abstract：Ni_0.5Zn_0.5Fe₂O₄ nanoparticles were synthesized by thermal decomposition method. The influence of reaction conditions such as the amount of the surfactant, refluxing temperature and time on the size, morphology and dispersibility was investigated. The structure, morphology and magnetic properties of the samples were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM) and vibrating sample magnetometry(VSM). The results indicate that increasing the amount of the surfactant is beneficial to obtain samples with smaller particle size and better dispersibility, and the improving refluxing temperature and extending refluxing time is beneficial to obtain samples with larger particle size, but with wider size distribution. The saturation magnetization of the sample is determined to be 49.38A·m²/kg, coercivity is 7143.20A/m and remanent magnetization is 5.76A·m²/kg with ferrimagnetic behavior at room temperature when the reaction condition is determined as follows, the amount of TOPO is 0.6mmol, the refluxing temperature is 260℃ and the refluxing time is 1h.

Key words： thermal decomposition method Ni-Zn ferrite dispersibility magnetic property

收稿日期: 2015-08-28 出版日期: 2017-09-16

中图分类号:	TB332
	TM25

通讯作者: 赵海涛(1976-),女,博士,教授,现从事功能材料研究,联系地址:辽宁省沈阳市浑南新区南屏中路6号沈阳理工大学材料科学与工程学院(110159),E-mail:zht95711@163.com E-mail: zht95711@163.com

引用本文:

赵海涛, 马瑞廷, 刘瑞萍. 热分解法制备Ni_0.5Zn_0.5Fe₂O₄纳米颗粒[J]. 材料工程, 2017, 45(9): 81-85.
ZHAO Hai-tao, MA Rui-ting, LIU Rui-ping. Synthesis of Ni_0.5Zn_0.5Fe₂O₄ Nanoparticles by Thermal Decomposition Method. Journal of Materials Engineering, 2017, 45(9): 81-85.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2015.001062 或 http://jme.biam.ac.cn/CN/Y2017/V45/I9/81

[1] WANG L S, NIE S J, WANG J B, et al. Effect of experiment parameters on the structure and magnetic properties of NiZn-ferrite films[J]. Materials Chemistry and Physics, 2015, 160:321-328.
[2] WANG L, DONG H, LI J, et al. Effects of annealing temperature on structural and magnetic properties of Ni_0.8Zn_0.2Fe₂O₄ thin films[J]. Ceramics International, 2014, 40(7):10323-10327.
[3] GUTIERREZ-LPEZA J, LEVENFELDA B, VAREZA A, et al. Study of the densification, mechanical and magnetic properties of Ni-Zn ferrites sintered in a solar furnace[J]. Ceramics International, 2015, 41(5):6534-6541.
[4] 赵海涛, 张强, 刘瑞萍, 等. 单分散纳米锌铁氧体的制备及其磁性能[J]. 材料工程, 2016, 44(1):103-107. ZHAO H T, ZHANG Q, LIU R P, et al. Synthesis and magnetic properties of monodisperse ZnFe₂O₄ nanoparticles[J]. Journal of Materials Engineering, 2016, 44(1):103-107.
[5] IBRAHIM I R, HASHIM M, NAZLAN R, et al. Grouping trends of magnetic permeability components in their parallel evolution with microstructure in Ni_0.3Zn_0.7Fe₂O₄[J]. Journal of Magnetism and Magnetic Materials, 2014, 355:265-275.
[6] RASHAD M M, RAYAN D A, TURKY A O, et al. Effect of Co²⁺ and Y³⁺ ions insertion on the microstructure development and magnetic properties of Ni_0.5Zn_0.5Fe₂O₄ powders synthesized using Co-precipitation method[J]. Journal of Magnetism and Magnetic Materials, 2015, 374:359-366.
[7] 曹慧群, 魏波, 刘剑洪, 等. 水热法制备纳米镍锌铁氧体粉体及其磁性能[J]. 硅酸盐学报, 2007, 35(6):713-716. CAO H Q, WEI B, LIU J H, et al. Hydrothermal synthesis and magnetic properties of nanosized nickel zinc ferrite powder[J]. Journal of the Chinese Ceramic Society, 2007, 35(6):713-716.
[8] 张永刚, 徐波, 王树林, 等. 镍锌铁氧体纳米材料制备及其光催化性能研究[J]. 功能材料, 2013, 44(14):2010-2013. ZHANG Y G, XU B, WANG S L, et al. Preparation and photocatalytic properties of Ni-Zn ferrite nanopower[J]. Journal of Functional Materials, 2013, 44(14):2010-2013.
[9] 张宁, 吴华强, 冒丽, 等. 微波多元醇法制备单分散Ni_1-xZn_xFe₂O₄/MWCNTs与磁性能[J]. 功能材料, 2012, 43(18):2554-2557. ZHANG N, WU H Q, MAO L, et al. Microwave-assisted polyol synthesis and magnetic properties of monodisperse Ni_1-xZn_xFe₂O₄/MWCNTs nanocomposites[J]. Journal of Functional Materials, 2012, 43(18):2554-2557.
[10] ZHU Y, JIANG F Y, CHEN K X, et al. Size-controlled synthesis of monodisperse superparamagnetic iron oxide nanoparticles[J]. Journal of Alloys and Compounds, 2011, 509(34):8549-8553.
[11] SONG M J, ZHANG Y, HU S L, et al. Influence of morphology and surface exchange reaction on magnetic properties of monodisperse magnetite nanoparticles[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2012, 408:114-121.
[12] ZHANG L, HE R, GU H C. Oleic acid coating on the monodisperse magnetite nanoparticles[J]. Applied Surface Science, 2006, 253(5):2611-2617.
[13] LI D, JIANG D L, CHEN M, et al. An easy fabrication of monodisperse oleic acid-coated Fe₃O₄ nanoparticles[J]. Materials Letters, 2010, 64(22):2462-2464.
[14] 李浩, 张喜斌. 络合剂/表面活性剂对溶剂热法制备钴纳米花的影响[J]. 无机盐工业, 2010, 42(6):30-32. LI H, ZHANG X B. Effect of complexing agents/surfactants on flowery Co microcrystals prepared by solvothermal method[J]. Inorganic Chemicals Industry, 2010, 42(6):30-32.
[15] 陈瑾. 高温多元醇法制备超顺磁CoFe₂O₄纳米颗粒磁共振造影剂[J]. 无机材料学报, 2009, 24(5):967-972. CHEN J. High temperature polyol synthesis of superparamagnetic CoFe₂O₄ nanoparticles for magnetic resonance imaging contrast agents[J]. Journal of Inorganic Materials, 2009, 24(5):967-972.
[16] ABBAS M, PARVATHEESWARA RAO B, KIM C G. Shape and size-controlled synthesis of Ni-Zn ferrite nanoparticles by two different routes[J]. Materials Chemistry and Physics, 2014, 147(3):443-451.
[17] HAJALILOUA A, HASHIM M, EBRAHIMI-KAHRIZSANGI R, et al. Synthesis and structural characterization of nano-sized nickel ferrite obtained by mechanochemical process[J]. Ceramics International, 2014, 40(4):5881-5887.
[18] GHASEMIN A, MOUSAVINIA M. Structural and magnetic evaluation of substituted NiZnFe₂O₄ particles synthesized by conventional sol-gel method[J]. Ceramics International, 2014, 40(2):2825-2834.
[19] LAZAREVI?Z ?, MILUTINOVI?A N, JOVALEKI??D, et al. Spectroscopy investigation of nanostructured nickel-zinc ferrite obtained by mechanochemical synthesis[J]. Materials Research Bulletin, 2015, 63:239-247.
[20] WU H Q, ZHANG N, MAO L, et al. Controlled synthesis and magnetic properties of monodisperse Ni_1-xZn_xFe₂O₄/MWCNT nanocomposites via microwave-assisted polyol process[J]. Journal of Alloys and Compounds, 2013, 554:132-137.

[1]	徐斌, 陈程华, 张彩霞, 鲁聪达, 倪忠进. 热分解法制备Cu空心微球及其光热转换性能[J]. 材料工程, 2019, 47(7): 57-63.
[2]	王莹, 李勇, 朱靖, 赵亚茹, 李焕. 氧化石墨烯表面稀土改性机理[J]. 材料工程, 2018, 46(5): 29-35.
[3]	赵晖, 马瑞廷, 赵海涛. 合成条件对纳米锌铁氧体形貌与性能的影响[J]. 材料工程, 2018, 46(4): 38-42.
[4]	王晨, 王魁, 肖小波, 丁浩, 汪炳叔, 毛朝武, 张维林, 金钢南. 钨酸钠对取向硅钢绝缘涂层性能的影响[J]. 材料工程, 2018, 46(4): 51-57.
[5]	李悦, 朱立群, 李卫平, 刘慧丛, 南海洋. 钕铁硼器件表面电沉积铜层及性能[J]. 材料工程, 2017, 45(6): 55-60.
[6]	梁瑞洋, 杨平, 毛卫民. 冷轧压下率及初始高斯晶粒取向度对超薄取向硅钢织构演变与磁性能的影响[J]. 材料工程, 2017, 45(6): 87-96.
[7]	谢春晓, 钟守炎, 杨元政, 罗剑英, 廖梓龙. 热处理对(Fe_0.52Co_0.30Ni_0.18)₇₃Cr₁₇Zr₁₀非晶合金的组织结构及磁性能的影响[J]. 材料工程, 2016, 44(8): 46-50.
[8]	钟喜春, 胡庚, 郭兴家, 刘仲武. 流动温压成型黏结钕铁硼/锶铁氧体复合磁体的研究[J]. 材料工程, 2016, 44(4): 9-13.
[9]	芦刚, 毛蒲, 严青松, 吴昊, 纪超众. 超声振荡和羟丙基甲基纤维素对短切纤维在精铸硅溶胶浆料中分散性能的影响[J]. 材料工程, 2016, 44(1): 71-76.
[10]	何天兵, 胡仁伟, 何晓磊, 李沛勇. 碳纳米管增强金属基复合材料的研究进展[J]. 材料工程, 2015, 43(10): 91-101.
[11]	王新星, 张宝林, 王行展, 冯凌云. 雾化热分解-氧化五羰基铁制备磁性氧化铁纳米粒子[J]. 材料工程, 2014, 0(8): 51-54.
[12]	刘渊, 刘祥萱, 王煊军. 铁氧体基核壳结构复合吸波材料研究进展[J]. 材料工程, 2014, 0(7): 98-106.
[13]	刘繁茂, 张慧燕, 张涛. Fe-Nd-B-Zr块体非晶合金的形成能力和磁性能[J]. 材料工程, 2014, 0(10): 6-10.
[14]	王金香, 高岩, 杨洋, 钱潜, 刘银. Zn²⁺含量对纳米Ni-Zn铁氧体结构和磁性能的影响[J]. 材料工程, 2012, 0(10): 22-24,34.
[15]	张晓红, 乔英杰. 纤维增强隐身复合材料的研究进展[J]. 材料工程, 2011, 0(8): 87-92.

Viewed

Full text

Abstract

Cited

Shared

Discussed