Please wait a minute...
 
2222材料工程  2015, Vol. 43 Issue (3): 91-97    DOI: 10.11868/j.issn.1001-4381.2015.03.016
  综述 本期目录 | 过刊浏览 | 高级检索 |
石墨烯复合材料的制备及应用研究进展
杨文彬1,2,*(), 张丽1,2, 刘菁伟1,2, 刘欢锐1,2, 唐兵华3
1 西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地, 四川 绵阳 621010
2 西南科技大学 教育部生物质材料工程研究中心, 四川 绵阳 621010
3 中国工程物理研究院 电子工程研究所, 四川 绵阳 621900
Progress in Research on Preparation and Application of Graphene Composites
Wen-bin YANG1,2,*(), Li ZHANG1,2, Jing-wei LIU1,2, Huan-rui LIU1,2, Bing-hua TANG3
1 State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
2 Engineering Research Center of Biomass Materials (Ministry of Education), Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
3 Institute of Electronic Engineering, China Academy of Engineering Physics, Mianyang 621900, Sichuan, China
全文: PDF(637 KB)   HTML ( 190 )  
输出: BibTeX | EndNote (RIS)      
摘要 

石墨烯是碳原子以sp2杂化连接而成的单原子层结构,这一独特的二维结构使得石墨烯具有优异的光电性能、热稳定性以及化学性能。石墨烯复合材料的制备、性能和应用成为近年的研究热点。本文综述了石墨烯复合材料的制备方法,包括石墨烯/高分子复合材料、石墨烯/金属(金属氧化物)复合材料、石墨烯三元复合材料,以及石墨烯复合材料在锂电池、电容器、光伏材料、传感器等方面的应用研究进展,指出了石墨烯复合材料研究的重要方向。

服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
杨文彬
张丽
刘菁伟
刘欢锐
唐兵华
关键词 石墨烯复合材料制备应用    
Abstract

Graphene is a single atomic layer structure, which is the thinnest 2-D planar sheet composed of sp2-bonded carbon atoms. The special structure of graphene has excellent properties, such as photoelectric property, heat stability and mechanical properties. There has been increasing attention to preparation, property and application of graphene composites in recent years. In the paper, preparation methods of graphene composites is reviewed, such as graphene/polymer composites, graphene/metal (metal oxide) composites, and ternary composites of graphene. The advances in application of graphene composites are also reviewed, such as in lithium battery, supercapacitors, photovoltaic devices, sensor applications. Furthermore, the important research direction of graphene composites is pointed out.

Key wordsgraphene    composite    preparation    application
收稿日期: 2013-08-27      出版日期: 2015-03-20
基金资助:国家自然科学基金委员会-中国工程物理研究院联合基金资助项目(11176025);四川省教育厅重大培育项目(14CZ0011);西南科技大学研究生创新基金(14ycx021).
通讯作者: 杨文彬     E-mail: yangwbscu@sina.com
作者简介: 杨文彬(1971-),男,教授,博士,从事石墨烯复合材料的制备与性能研究,联系地址:四川省绵阳市西南科技大学材料学院(621010), yangwbscu@sina.com
引用本文:   
杨文彬, 张丽, 刘菁伟, 刘欢锐, 唐兵华. 石墨烯复合材料的制备及应用研究进展[J]. 材料工程, 2015, 43(3): 91-97.
Wen-bin YANG, Li ZHANG, Jing-wei LIU, Huan-rui LIU, Bing-hua TANG. Progress in Research on Preparation and Application of Graphene Composites. Journal of Materials Engineering, 2015, 43(3): 91-97.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2015.03.016      或      http://jme.biam.ac.cn/CN/Y2015/V43/I3/91
1 NOVOSELOV K S, GEIM A K, MOROZOV S V, et al Electric field effect in atomically thin carbon films[J]. Science, 2004, 306 (5296): 666- 669.
2 NOVOSELOV K S, GEIM A K, MOROZOV S V, et al Two-dimensional gas of massless Dirac fermions in graphene[J]. Nature, 2005, 438 (7065): 197- 200.
3 GEIM A K, NOVOSELOV K S The rise of graphene[J]. Nature Materials, 2007, 6 (3): 183- 191.
4 BALANDIN A A, GHOSH S, BAO W, et al Superior thermal conductivity of single-layer graphene[J]. Nano Letters, 2008, 8 (3): 902- 907.
5 CHAE H K, SIBERIO-PEREZ D Y, KIM J, et al A route to high surface area, porosity and inclusion of large molecules in crystals[J]. Nature, 2004, 427 (6974): 523- 527.
6 LEE C G, WEI X D, KYSAR J W, et al Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science, 2008, 321 (5887): 385- 388.
7 KIM H, MIURA Y, MACOSKO C W Graphene/polyurethane nanocomposites for improved gas barrier and electrical conductivity[J]. Chem Mater, 2010, 22 (11): 3441- 3450.
8 WAKABAYASHI K, PIERRE C, DIKIN D A, et al Polymer-graphite nanocomposites: effective dispersion and major property enhancement via solid-state shear pulverization[J]. Macromolecules, 2008, 41 (6): 1905- 1908.
9 YANG Y, WANG J, ZHANG J, et al Exfoliated graphite oxide decorated by PDMAEMA chains and polymer particles[J]. Langmuir, 2009, 25 (19): 11808- 11814.
10 KIM H, MACOSKO C W Processing-property relationships of polycarbonate/graphene composites[J]. Polymer, 2009, 50 (15): 3797- 3809.
11 LIANG J, HUANG Y, ZHANG L, et al Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites[J]. Adv Fun Mater, 2009, 19 (14): 2297- 2302.
12 ZHAO X, ZHANG Q, CHEN D, et al Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites[J]. Macromolecules, 2010, 43 (5): 2357- 2363.
13 WU Q, XU Y, YAO Z, et al Supercapacitors based on flexible graphene/polyaniline nanofiber composite films[J]. ACS Nano, 2010, 4 (4): 1963- 1970.
14 WANG H, HAO Q, YANG X, et al Effect of graphene oxide on the properties of its composite with polyaniline[J]. ACS Appl Mate Inter, 2010, 2 (3): 821- 828.
15 GLOVER A J, CAI M, OVERDEEP K R, et al In situ reduction of graphene oxide in polymers[J]. Macromolecules, 2011, 44 (24): 9821- 9829.
16 TANG Y, WU N, LUO S, et al One-step electrodeposition to layer-by-layer graphene-conducting-polymer hybrid films[J]. Macromol Rapid Comm, 2012, 33 (20): 1780- 1786.
17 STANKOVICH S, DIKIN D A, DOMMETT G H B, et al Graphene-based composite materials[J]. Nature, 2006, 442 (7100): 282- 286.
18 BAE S, KIM H, LEE Y, et al Roll-to-roll production of 30-inch graphene films for transparent electrodes[J]. Nat Nanotechol, 2010, 5 (8): 574- 578.
19 CHEN Z, REN W, GAO L, et al Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J]. Nat Mater, 2011, 10 (6): 424- 428.
20 燕绍九, 杨程, 洪起虎, 等 石墨烯增强铝基纳米复合材料的研究[J]. 材料工程, 2014, (4): 1- 6.
20 YAN Shao-jiu, YANG Cheng, HONG Qi-hu, et al Research of graphene-reinforced aluminum matrix nanocomposites[J]. Journal of Materials Engineering, 2014, (4): 1- 6.
21 BAI S, SHEN X, ZHONG X, et al One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite hybrids for organic dye removal[J]. Carbon, 2012, 50 (6): 2337- 2346.
22 TIAN J, LIU S, ZHANG Y, et al Environmentally friendly, one-pot synthesis of Ag nanoparticle-decorated reduced graphene oxide composites and their application to photocurrent generation[J]. Inorg Chem, 2012, 51 (8): 4742- 4746.
23 LIANG J, WEI W, ZHONG D, et al One-step in situ synthesis of SnO2/graphene nanocomposites and its application as an anode material for Li-ion batteries[J]. ACS Appl Mater Inter, 2011, 4 (1): 454- 459.
24 DONG X, XU H, WANG X, et al 3D graphene-cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection[J]. ACS Nano, 2012, 6 (4): 3206- 3213.
25 WU J, SHEN X, JIANG L, et al Solvothermal synthesis and characterization of sandwich-like graphene/ZnO nanocomposites[J]. Appl Surf Sci, 2010, 256 (9): 2826- 2830.
26 SHEN J F, YAN B, SHI M, et al One step hydrothermal synthesis of TiO2-reduced graphene oxide sheets[J]. J Mater Chem, 2011, 21 (10): 3415- 3421.
27 WANG H W, HU Z A, CHANG Y Q, et al Facile solvothermal synthesis of a graphene nanosheet-bismuth oxide composite and its electrochemical characteristics[J]. Electrochim Acta, 2010, 55 (28): 8974- 8980.
28 ZHU J X, ZHU T, ZHOU X Z, et al Facile synthesis of metal oxide/reduced graphene oxide hybrids with high lithium storage capacity and stable cyclability[J]. Nanoscale, 2011, 3 (3): 1084- 1089.
29 DAI Y, CAI S, YANG W, et al Fabrication of self-binding noble metal/flexible graphene composite paper[J]. Carbon, 2012, 50 (12): 4648- 4654.
30 ADHIKARI B, BISWAS A, BANERJEE A Graphene oxide-based supramolecular hydrogels for making nanohybrid systems with Au nanoparticles[J]. Langmuir, 2011, 28 (2): 1460- 1469.
31 TIEN H, HUANG Y, YANG S, et al The production of graphene nanosheets decorated with silver nanoparticles for use in transparent, conductive films[J]. Carbon, 2011, 49 (5): 1550- 1560.
32 ZHOU X, HUANG X, QI X, et al In situ synthesis of metal nanoparticles on single-layer graphene oxide and reduced graphene oxide surfaces[J]. J Phys Chem C, 2009, 113 (25): 10842- 10846.
33 ZHANG Z, XU F, YANG W, et al A facile one-pot method to high-quality Ag-graphene composite nanosheets for efficient surface-enhanced Raman scattering[J]. Chem Commun, 2011, 47 (22): 6440- 6442.
34 ZHANG M, QU B, LEI D, et al A green and fast strategy for the scalable synthesis of Fe2O3/graphene with significantly enhanced Li-ion storage properties[J]. J Mater Chem, 2012, 22 (9): 3868- 3874.
35 VADAHANAMBI S, JUNG J, OH I Microwave syntheses of graphene and graphene decorated with metal nanoparticles[J]. Carbon, 2011, 49 (13): 4449- 4457.
36 LIN Y, BAGGETT D W, KIM J, et al Instantaneous formation of metal and metal oxide nanoparticles on carbon nanotubes and graphene via solvent-free microwave heating[J]. ACS Appl Mater Interf, 2011, 3 (5): 1652- 1664.
37 HASSAN H M A, ABDELSAYED V, KHDER A E R S, et al Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic media[J]. J Mater Chem, 2009, 19 (23): 3832- 3837.
38 GUARDIA L, VILLAR-RODIL S, PAREDES J I, et al UV light exposure of aqueous graphene oxide suspensions to promote their direct reduction, formation of graphene-metal nanoparticle hybrids and dye degradation[J]. Carbon, 2012, 50 (3): 1014- 1024.
39 AKHAVAN O Photocatalytic reduction of graphene oxides hybridized by ZnO nanoparticles in ethanol[J]. Carbon, 2011, 49 (1): 11- 18.
40 WILLIAMS G, SEGER B, KAMAT P V TiO2-graphene nanocomposites[J]. UV-assisted photocatalytic reduction of graphene oxide[J]. ACS Nano, 2008, 2 (7): 1487- 1491.
41 KARIM M R, SHINODA H, NAKAI M, et al Electrical conductivity and ferromagnetism in a reduced graphene-metal oxide hybrid[J]. Adv Fun Mater, 2013, 23 (3): 323- 332.
42 LIU X, MAO J, LIU P, et al Fabrication of metal-graphene hybrid materials by electroless deposition[J]. Carbon, 2011, 49 (2): 477- 483.
43 CAO X, SHI Y, SHI W, et al Preparation of novel 3D graphene networks for supercapacitor applications[J]. Small, 2011, 7 (22): 3163- 3168.
44 MANDAL S, SAHA S K Ni/graphene/Ni nanostructures for spintronic applications[J]. Nanoscale, 2012, 4 (3): 986- 990.
45 TUNG T T, FELLER J, KIM T, et al Electromagnetic properties of Fe3O4-functionalized graphene and its composites with a conducting polymer[J]. J Polym Sci Pol Chem, 2012, 50 (5): 927- 935.
46 KASSAEE M Z, MOTAMEDI E, MAJDI M Magnetic Fe3O4-graphene oxide/polystyrene: fabrication and characterization of a promising nanocomposite[J]. Chem Eng J, 2011, 172 (1): 540- 549.
47 WANG X, SONG L, YANG H, et al Cobalt oxide/graphene composite for highly efficient CO oxidation and its application in reducing the fire hazards of aliphatic polyesters[J]. J Mater Chem, 2012, 22 (8): 3426- 3431.
48 BIRROZZIA A, RACCICHINIB R, NOBILIA F, et al High-stability graphene nano sheets/SnO2 composite anode for lithium ion batteries[J]. Electrochimica Acta, 2014, 137 (10): 228- 234.
49 WANG H L, CUI L F, YANG Y A, et al Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries[J]. J Am Chem Soc, 2010, 132 (40): 13978- 13980.
50 CHEN J S, WANG Z Y, DONG X C, et al Graphene-wrapped TiO2 hollow structures with enhanced lithium storage capabilities[J]. Nanoscale, 2011, 3 (5): 2158- 2161.
51 丁翔, 黄正宏, 沈万慈, 等 氧化铜/石墨烯的制备及其电化学性能[J]. 新型炭材料, 2013, 28 (3): 172- 177.
51 DING Xiang, HUANG Zheng-hong, SHEN Wan-ci, et al Preparation and electrochemical performance of a CuO/graphene composite[J]. New Carbon Materials, 2013, 28 (3): 172- 177.
52 CHEN S, ZHU J, WU X, et al Graphene oxide-MnO2 nanocomposites for supercapacitors[J]. ACS Nano, 2010, 4 (5): 2822- 2830.
53 曲江英, 李雨佳, 李传鹏, 等 还原氧化石墨烯/Mn3O4纳米复合材料的合成及其在超级电容器中的应用[J]. 新型炭材料, 2014, 29 (3): 186- 192.
53 QU Jiang-ying, LI Yu-jia, LI Chuan-peng, et al Synthesis of reduced graphene oxide/Mn3O4 nanocomposites for supercapacitors[J]. New Carbon Materials, 2014, 29 (3): 186- 192.
54 CHEN S, ZHANG L L, ZHAO X S, et al Graphene/polyaniline nanofiber composites as supercapacitor electrodes[J]. Chem Mater, 2010, 22 (4): 1392- 1401.
55 LIU J, WANG Z, XIE X, et al A rationally-designed synergetic polypyrrole/graphene bilayer actuator[J]. J Mater Chem, 2012, 22 (9): 4015- 4020.
56 ZHAO Y, LIU J, HU Y, et al Highly compression-tolerant supercapacitor based on polypyrrole-mediated graphene foam electrodes[J]. Adv Mater, 2013, 25 (4): 591- 595.
57 WANG X, ZHI L J, MULLEN K, et al Transparent, conductive graphene electrodes for dye-sensitized solar cells[J]. Nano Letter, 2008, 8 (1): 323- 327.
58 BECERRIL H A, MAO J, LIU Z F, et al Evaluation of solution-processed reduced graphene oxide films as transparent con-ductors[J]. ACS Nano, 2008, 2 (3): 463- 470.
59 LI X L, ZHANG G Y, BAI X D, et al Highly conducting graphene sheets and langmuir-blodgett films[J]. Nat Nanotechnol, 2008, 3 (9): 538- 542.
60 ALWARAPPAN S, ERDEM A, LI C Z, et al Probing the electrochemical properties of graphene nanosheets for biosensing applications[J]. J Phys Chem C, 2009, 113 (20): 8853- 8857.
61 WANG Y, YANG R, SHI Z, et al Super-elastic graphene ripples for flexible strain sensors[J]. ACS Nano, 2011, 5 (5): 3645- 3650.
62 HONG W, BAI H, XU Y, et al Preparation of gold nanoparticle/graphene composites with controlled weight contents and their application in biosensors[J]. J Phys Chem C, 2010, 114 (4): 1822- 1826.
63 ROBINSON J T, PERKINS F K, SNOW E S, et al Reduced graphene oxide molecular sensors[J]. Nano Letter, 2008, 8 (10): 3137- 3140.
64 SCHEDIN F, GEIM A K, MOROZOV S V, et al Detection of individual gas molecules adsorbed on graphene[J]. Nat Mater, 2007, 6 (9): 652- 655.
65 DAN Y, LU Y, KYBERT N J, et al Intrinsic response of graphene vapor sensors[J]. Nano Letters, 2009, 9 (4): 1472- 1475.
66 KIM Y, NA H, MIN D Influence of surface functionalization on the growth of gold nanostructures on graphene thin films[J]. Langmuir, 2010, 26 (16): 13065- 13070.
67 LIU H R, YANG W B, HE F F, et al Graphene-based composite with microwave absorption property prepared by in situ reduction[J]. Polym Compos, 2014, 35 (3): 461- 467.
[1] 熊京鹏, 刘勇. 镁基复合材料界面调控研究进展[J]. 材料工程, 2023, 51(1): 1-15.
[2] 李淑波, 侯江涛, 孟繁婧, 刘轲, 王朝辉, 杜文博. CNTs/Mg-9Al复合材料微观组织、力学及导热性能[J]. 材料工程, 2023, 51(1): 26-35.
[3] 吴立清, 冯柳, 毛晓璇, 穆洪亮, 刘志超, 牛金叶, 高蔷. 量子点/碳复合材料在碱金属离子电池的应用进展[J]. 材料工程, 2023, 51(1): 36-51.
[4] 华江龙, 江琦. 耐久可拉伸超疏水材料的构建及应用研究进展[J]. 材料工程, 2023, 51(1): 76-84.
[5] 王宪, 贺雍律, 唐俊, 刘钧, 黄贤俊, 翟多才, 张鉴炜. Al颗粒夹层CFRP复合材料力学及电磁屏蔽性能[J]. 材料工程, 2023, 51(1): 140-147.
[6] 曾宏伟, 李红, 姚彧敏, 杨敏, 陶银萍, 任慕苏, 孙晋良. 热解碳含量对碳/碳-聚酰亚胺复合材料性能的影响[J]. 材料工程, 2023, 51(1): 148-154.
[7] 刘子欣, 刘欢, 于浩然, 王琰, 王建英. 腰果壳油基超交联聚合物的制备及吸附VOCs性能[J]. 材料工程, 2023, 51(1): 155-161.
[8] 鞠录岩, 张建兵, 马玉钦, 张钊源, 魏文澜. ZrW2O8-Cf/E51低/负热膨胀复合材料制备及超声时间对其热膨胀和力学性能的影响[J]. 材料工程, 2023, 51(1): 171-178.
[9] 张林琳, 顾学林, 向笑笑, 刘会娥, 陈爽. 石墨烯-羧甲基纤维素复合气凝胶的制备及吸油性能评价[J]. 材料工程, 2022, 50(9): 43-51.
[10] 许家豪, 汪选国, 姚振华. 粉末冶金制备工艺对TiC增强高铬铸铁基复合材料性能的影响[J]. 材料工程, 2022, 50(9): 105-112.
[11] 孔国强, 安振河, 魏化震, 李莹, 邵蒙, 于秋兵, 纪校君, 李居影, 王康. 碳纤维丝束结构对碳纤维/酚醛复合材料烧蚀性能的影响[J]. 材料工程, 2022, 50(9): 113-119.
[12] 米玉洁, 宋明明, 张存瑞, 张贵恩, 王月祥, 常志敏. 羰基铁室温硫化硅橡胶复合材料的吸波性能[J]. 材料工程, 2022, 50(9): 120-126.
[13] 邢宇, 张代军, 王成博, 倪洪江, 李军, 陈祥宝. PEEK复合材料用碳纤维上浆剂研究进展[J]. 材料工程, 2022, 50(8): 70-81.
[14] 李守佳, 罗春燕, 陈卫星, 方铭港, 孙健鑫. 氧化石墨烯接枝聚乙二醇对左旋聚乳酸结晶行为和热稳定性的影响[J]. 材料工程, 2022, 50(8): 99-106.
[15] 周银, 乔畅, 邹家栋, 郭洪锍, 王树奇. 多层石墨烯对钛合金摩擦学性能的影响[J]. 材料工程, 2022, 50(8): 107-114.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn