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材料工程  2015, Vol. 43 Issue (4): 25-29    DOI: 10.11868/j.issn.1001-4381.2015.04.005
  材料与工艺 本期目录 | 过刊浏览 | 高级检索 |
NH3气氛下N掺杂ZnO的制备及光电性能
张凌云, 贾若琨, 孙旭辉, 张瑛洁, 刘春光
东北电力大学 化学工程学院, 吉林 吉林 132012
Preparation and Photovoltaic Performance of N-doped ZnO in NH3 Gas
ZHANG Ling-yun, JIA Ruo-kun, SUN Xu-hui, ZHANG Ying-jie, LIU Chun-guang
School of Chemical Engineering, Northeast Dianli University, Jilin 132012, Jilin, China
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摘要 采用自设计高温煅烧装置在NH3气氛下制备N掺杂ZnO,研究N掺杂ZnO(N-ZnO)的合成条件与ZnO带隙和光电转换效率之间的关系。通过改变NH3气压强、煅烧温度和煅烧时间得到不同N掺杂量的ZnO。采用扫描电子显微镜(SEM)、X射线粉末衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见吸收光谱(UV-vis)对N-ZnO的形貌、晶体结构、掺杂价态以及光学性质进行分析。结果表明:N-ZnO为六方纤锌矿结构,N掺杂有效窄化ZnO带隙,导致其紫外-可见吸收光谱的吸收带边红移,以其为光阳极的染料敏化太阳能电池的光电转换效率从0.34%提高至1.02%。
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张凌云
贾若琨
孙旭辉
张瑛洁
刘春光
关键词 太阳能电池氧化锌氮掺杂带隙    
Abstract:N-doped ZnO (N-ZnO) was prepared with self-designed high temperature annealing devices in NH3 gas. The relationship between preparation condition, band gap, and photovoltaic conversion efficiency of N-ZnO was investigated. ZnO with different N doping concentration was obtained by varying NH3 gas pressure, annealing temperature, and annealing time. The morphology, structure, chemical compositions and optical property of N-ZnO were characterized by scanning electron microscope(SEM),X-ray diffraction analysis(XRD),X-ray photoelectron spectroscopy(XPS) and UV-visible absorption spectroscopy(UV-vis). The results show that N-ZnO possesses a hexagonal wurtzite structure. N doping effectively leads to narrowing of band gap and a red shift of the absorption edge of ZnO. The photovoltaic conversion efficiency of dye-sensitized solar cell based on N-ZnO photoanode can be improved from 0.34% to 1.02%.
Key wordssolar cell    zinc oxide    nitrogen doping    band gap
收稿日期: 2014-02-08      出版日期: 2015-04-20
中图分类号:  O649.2  
基金资助:国家自然科学基金面上项目资助(21373043);吉林省科技厅科技发展计划项目资助(20130305017GX,20140101090JC);吉林省科技厅国际合作项目资助(20130413046GH);吉林省教育厅"十二五"科学技术研究项目资助(2014105);吉林市科技局科技攻关项目资助(201464036);东北电力大学博士科研基金项目资助(BSJXM-201321)
通讯作者: 张凌云(1978-),女,博士,副教授,主要从事锂离子电池和太阳能电池等新型能源材料的研究工作,联系地址:吉林省吉林市东北电力大学化学工程学院(132012),zhangly@mail.nedu.edu.cn     E-mail: zhangly@mail.nedu.edu.cn
引用本文:   
张凌云, 贾若琨, 孙旭辉, 张瑛洁, 刘春光. NH3气氛下N掺杂ZnO的制备及光电性能[J]. 材料工程, 2015, 43(4): 25-29.
ZHANG Ling-yun, JIA Ruo-kun, SUN Xu-hui, ZHANG Ying-jie, LIU Chun-guang. Preparation and Photovoltaic Performance of N-doped ZnO in NH3 Gas. Journal of Materials Engineering, 2015, 43(4): 25-29.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2015.04.005      或      http://jme.biam.ac.cn/CN/Y2015/V43/I4/25
[1] 王旭东,易忠,沈自才,等.ZnO白漆的质子辐照损伤与光学性能退化机理[J]. 材料工程,2013,(5):1-5.WANG Xu-dong, YI Zhong, SHEN Zi-cai, et al. Proton radiation damage in ZnO-pigmented white paints and optical degradation mechanisms[J]. Journal of Materials Engineering,2013,(5):1-5.
[2] 贺小文,孟大维,刘长珍,等. ZnO以及Fe掺杂ZnO的光学性质和室温铁磁性质研究[J]. 材料工程,2012,(12):66-70.HE Xiao-wen, MENG Da-wei, LIU Chang-zhen, et al. Optical and room-temperature ferromagnetic properties of ZnO and Fe doped ZnO[J]. Journal of Materials Engineering,2012,(12):66-70.
[3] SUN F J, XIE Y, LIU J, et al.ZnO hierarchical nanostructures and application on high-efficiency dye-sensitized solar cells[J]. Materials Science and Engineering:B,2010,166(3):196-202.
[4] WANG J, CHEN W, ZHOU Y, et al. Direct growth of highly mismatched type Ⅱ ZnO/ZnSe core/shell nanowire arrays on transparent conducting oxide substrates for solar cell applications[J]. Advanced Material,2008,20(17):3248-3253.
[5] KIN S, DOLMANAN B, SHEN L, et al. Degradation mechanism of ZnO-based dye-sensitized solar cells[J]. Solar Energy Material Solar Cells,2010,94(2):323-326.
[6] LIVRAGHI M C, PAGANINI E, GIAMELLO A, et al. Origin of photoactivity of nitrogen-doped titanium dioxide under visible light[J]. Journal of American Chemical Society,2006,128(49):15666-15671.
[7] HU J, HE H Y, PAN B C, et al. Hydrogen diffusion behaviour in N doped ZnO:first-principles study[J]. Journal of Applied Physics,2008,103(11):113706.
[8] ROGOZIN I V. Nitrogen-doped p-type ZnO thin films and ZnO/ZnSe p-n heterojunctions grown on ZnSe substrate by radical beam gettering epitaxy[J]. Thin Solid Films,2009,517(15):4318-4321.
[9] OH D C, KIM J J, MAKINO H, et al. Characteristics of schottky contacts to ZnO:N layers grown by molecular-beam epitaxy[J]. Journal of Applied Physics Letters,2005,(86):042110.
[10] DU G, MA Y, ZHANG Y, et al. Preparation of intrinsic and N-doped p-type ZnO thin films by metalorganic vapor phase epitaxy[J]. Journal of Applied Physics Letters,2005,(87):213103.
[11] DUNLOP L, KURSUMOVIC A, MACMANUS-DRISCOLL J L, et al. Reproducible growth of p-type ZnO:N using a modified atomic layer deposition process combined with dark annealing[J]. Journal of Applied Physics Letters,2008,(93):172111.
[12] NAKANO Y, MORIKAWA T, OHWAKI T, et al. Electrical characterization of p-type N-doped ZnO films prepared by thermal oxidation of sputtered Zn3N2 films[J]. Journal of Applied Physics Letters,2006,(88):172103.
[13] NIAN H, HAHN S H, KOO K K, et al. Sol-gel derived N-doped ZnO thin films[J]. Material Letters,2009,63(26):2246-2248.
[14] ZHU Y, LIN S H, ZHANG Y Z, et al. Temperature effect on the electrical,structural and optical properties of N-doped ZnO films by plasma-free metal organic chemical vapour deposition[J]. Applied Surface Science,2009,255(12):6201-6204.
[15] JIANG L Q, XU Z L, SHANG X J, et al. The surface properties and photocatalytic activities of ZnO ultrafine particles[J]. Applied Surface Science,2001,180(3-4):308-314.
[16] LOSURDO M, GIUVA D, BRUNO G, et al. The surface modification and reactivity of LiGaO2 substrates during GaN epitaxy[J]. Journal of Crystal Growth,2004,264(1-3):139-146.
[17] LI Z, XIONG Y, XIE Y. Selected-control synthesis of ZnO nanowires and nanorods via a PEG-assisted route[J]. Inorganic Chemistry,2003,(42):8105-8109.
[18] CHEN M, WANG X, YU Y H, et al. X-ray photoelectron spectroscopy and auger electron spectroscopy studies of Al-doped ZnO films[J]. Applied Surface Science,2000,158(1-2):134-140.
[19] MUTHUKUMAR S, GORLA C R, EMANETOGLU N W, et al. Control of morphology and orientation of ZnO thin films grown on SiO2/Si substrates[J]. Journal of Crystal Growth,2001,225(2-4):197-201.
[20] CONG Y, ZHANG J L, CHEN F. Synthesis and characterization of nitrogen-doped TiO2 nanophotocatalyst with high visible light activity[J]. Journal of Physical Chemistry C,2007,111(19):6976-6982.
[21] ZHOU C J, KANG J Y. Modulation of band structure in wurtzite ZnO via site-selective Ga-N codoping[J]. Journal of Physics Condens Matter,2006,(18):6281-6287.
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