Please wait a minute...
 
材料工程  2017, Vol. 45 Issue (3): 73-79    DOI: 10.11868/j.issn.1001-4381.2016.000002
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
爆炸喷涂WC-Co/MoS2-Ni多层复合自润滑涂层的摩擦学行为
王铁钢1, 李柏松1, 阎兵1, 范其香1, 刘艳梅1, 宫骏2, 孙超2
1. 天津职业技术师范大学 天津市高速切削与精密加工重点实验室, 天津 300222;
2. 中国科学院 金属研究所, 沈阳 110016
Tribological Behavior of Multi-layered WC-Co/MoS2-Ni Self-lubricating Coating Fabricated by Detonation Gun Spraying
WANG Tie-gang1, LI Bai-song1, YAN Bing1, FAN Qi-xiang1, LIU Yan-mei1, GONG Jun2, SUN Chao2
1. Tianjin Key Laboratory of High Speed Cutting and Precision Processing, Tianjin University of Technology and Education, Tianjin 300222, China;
2. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
全文: PDF(13930 KB)   HTML()
输出: BibTeX | EndNote (RIS)      
摘要 采用爆炸喷涂技术研制WC-Co/MoS2-Ni多层复合自润滑涂层,系统研究涂层的微观结构、元素分布、结合强度和摩擦磨损性能。结果表明:在高温爆炸喷涂过程中,少量MoS2发生氧化分解,生成SO2气体,残留在涂层内的SO2气体可使局部形成微小孔洞。在摩擦测试中,WC-Co涂层在预磨阶段摩擦因数迅速上升,进入稳定阶段后,摩擦因数缓慢增加;而多层复合涂层的摩擦因数在经历预磨阶段迅速上升后,很快进入稳定阶段,直至表层WC-Co涂层被磨穿后,摩擦因数开始逐渐下降。添加自润滑涂层MoS2-Ni后,WC-Co涂层的内聚结合强度略有下降,但减摩效果显著,摩擦因数下降了约40%,耐磨性能略有提升。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
王铁钢
李柏松
阎兵
范其香
刘艳梅
宫骏
孙超
关键词 WC-Co/MoS2-Ni涂层自润滑涂层爆炸喷涂摩擦磨损    
Abstract:The multilayered composite WC-Co/MoS2-Ni self-lubricating coatings were prepared by detonation gun spraying technology. The coating microstructure, element distribution, adhesive strength, and tribological properties were studied systematically. The results show that a little of MoS2 is oxidized and decomposed into gas of SO2 during the high-temperature spraying process. The SO2 left in the coating and can form into the micro porosities. The friction coefficient of the WC-Co coating first increases rapidly in the initial running-in phase, and then gradually increases slightly after entering into the steady-state phase; whereas the friction coefficient of multilayer composite coating steps in the steady-state phase soon and starts to decline gradually when the top WC-Co coating became perforated. By comparison, the coating cohesion declines slightly after adding the self-lubricating layer MoS2-Ni, but the friction coefficient decreases by about 40%, and the wear resistance is also improved slightly.
Key wordsWC-Co/MoS2-Ni coating    self-lubricating coating    detonation gun spraying    friction and wear
收稿日期: 2016-01-04      出版日期: 2017-03-22
中图分类号:  TH117.3  
通讯作者: 王铁钢(1978-),男,副教授,博士后,研究方向:硬质涂层,联系地址:天津市高速切削与精密加工重点实验室(300222),E-mail:sytgwang@163.com;tgwang@tute.edu.cn     E-mail: sytgwang@163.com;tgwang@tute.edu.cn
引用本文:   
王铁钢, 李柏松, 阎兵, 范其香, 刘艳梅, 宫骏, 孙超. 爆炸喷涂WC-Co/MoS2-Ni多层复合自润滑涂层的摩擦学行为[J]. 材料工程, 2017, 45(3): 73-79.
WANG Tie-gang, LI Bai-song, YAN Bing, FAN Qi-xiang, LIU Yan-mei, GONG Jun, SUN Chao. Tribological Behavior of Multi-layered WC-Co/MoS2-Ni Self-lubricating Coating Fabricated by Detonation Gun Spraying. Journal of Materials Engineering, 2017, 45(3): 73-79.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.000002      或      http://jme.biam.ac.cn/CN/Y2017/V45/I3/73
[1] GE Z, LI S, DUAN D L, et al. Wear behaviour of WC-Co HVOF coatings at different temperatures in air and argon[J]. Wear, 2015, 330-331(5):348-353.
[2] AFZAL M, NUSAIR K A, BEN M T, et al. Effect of laser melting on plasma sprayed WC-12 wt.% Co coatings[J]. Surface and Coatings Technology, 2015, 266(3):22-30.
[3] GENG Z, HOU S, SHI G, et al. Tribological behaviour at various temperatures of WC-Co coatings prepared using different thermal spraying techniques[J]. Tribology International, 2016, 104(12):36-44.
[4] NAHVI S M, JAFARI M. Microstructural and mechanical properties of advanced HVOF-sprayed WC-based cermet coatings[J]. Surface and Coatings Technology, 2016, 286(1):95-102.
[5] 王铁钢,宋丙红,华伟刚,等. 工艺参数对爆炸喷涂WC-Co涂层性能均匀性的影响[J]. 金属学报, 2011, 47(1):115-122. WANG T G, SONG B H, HUA W G, et al. Influence of process parameters on the performance uniformity of detonation gun sprayed WC-Co coatings[J]. Acta Metallurgica Sinica, 2011, 47(1):115-122.
[6] WANG T G, ZHAO S S, HUA W G, et al. Design of a separation device used in detonation gun spraying system and its effects on the performance of WC-Co coatings[J]. Surface and Coatings Technology, 2009, 203(12):1637-1644.
[7] WANG T G, ZHAO S S, HUA W G, et al. Estimation of residual stress and its effects on the mechanical properties of detonation gun sprayed WC-Co coatings[J]. Materials Science and Engineering:A, 2010, 527(3):454-461.
[8] 李倩倩, 尹桂林, 郑慈航, 等. 添加TiN对MoS2基复合薄膜结构和性能的影响[J]. 摩擦学学报, 2011, 31(1):40-44. LI Q Q, YIN G L, ZHENG C H, et al. Effect of TiN addition on the microstructure and performance of MoS2-based composite films[J]. Tribology, 2011, 31(1):40-44.
[9] 秦晓鹏,柯培玲,汪爱英. 偏压及测试环境对新型MoS2-Ti复合膜摩擦学性能的影响[J]. 摩擦学学报, 2013, 33(2):162-168. QIN X P, KE P L, WANG A Y. Effect of bias and test environments on tribological behavior of MoS2-Ti composite coatings[J]. Tribology, 2013, 33(2):162-168.
[10] 王常川,王日初,彭超群,等. 金属基固体自润滑复合材料的研究进展[J].中国有色金属学报, 2012, 22(7):1945-1955. WANG C C, WANG R C, PENG C Q, et al. Research progress of metallic solid self-lubricating composites[J]. Chinese Journal of Nonferrous Metals,2012, 22(7):1945-1955.
[11] DU H, SUN C, HUA W G, et al. Fabrication and evaluation of D-gun sprayed WC-Co coating with self-lubricating property[J]. Tribology Letters, 2006, 23(3):261-266.
[12] DU H, SUN C, HUA W G, et al. Structure, mechanical and sliding wear properties of WC-Co/MoS2-Ni coatings by detonation gun spray[J]. Materials Science and Engineering:A, 2007, 445-446(2):122-134.
[13] DU H, SUN C, GONG J, et al. Deposition and characterization of D-gun pprayed WC-Co coating with self-lubricating property[J]. Materials Science Forum, 2007, 544-545(1):215-218.
[14] WANG T G, LIU Y M, WANG Q M, et al. Influence of residual stress on the adhesive behavior of detonation gun sprayed WC-Co coatings[J]. Current Applied Physics, 2012, 12:59-62.
[15] WANG T G, JEONG D, LIU Y M, et al. Study on nanocrystalline Cr2O3 films deposited by arc ion plating:Ⅱ. Mechanical and tribological properties[J]. Surface and Coatings Technology, 2012, 206(1):2638-2644.
[16] WONG K C, LU X, COTTER J, et al. Surface and friction characterization of MoS2 and WS2 third body thin films under simulated wheel/rail rolling-sliding contact[J], Wear, 2008, 264:526-534.
[17] WANG X, XING Y M, MA S L, et al. Microstructure and mechanical properties of MoS2/titanium composite coatings with different titanium content[J]. Surface and Coatings Technology, 2007, 201:5290-5293.
[18] 潘蛟亮, 王引真, 李方坡, 等. Ni包MoS2添加剂对镍基涂层的摩擦磨损性能影响[J]. 摩擦学学报, 2008, 28(5):225-229. PAN J L, WANG Y Z, LI F P, et al. Effect of MoS2 coated with Nickel on tribological properties of Ni-based coating[J]. Tribology, 2008, 28(5):225-229.
[19] CAO T K, LEI S T, ZHANG M. The friction and wear behavior of Cu/Cu-MoS2 self-lubricating coating prepared by electrospark deposition[J]. Surface and Coatings Technology, 2015, 270(5):24-32.
[20] SHI X L, ZHAI W Z, XU Z S, et al. Synergetic lubricating effect of MoS2 and Ti3SiC2 on tribological properties of NiAl matrix self-lubricating composites over a wide temperature range[J]. Materials & Design, 2014, 55(3):93-103.
[21] WU G Y, XU C H, XIAO G C, et al. Self-lubricating ceramic cutting tool material with the addition of nickel coated CaF2 solid lubricant powders[J]. International Journal of Refractory Metals and Hard Materials, 2016, 56(4):51-58.
[22] LIU X B, MENG X J, LIU H Q, et al. Development and characterization of laser clad high temperature self-lubricating wear resistant composite coatings on Ti-6Al-4V alloy[J]. Materials & Design, 2014, 55(3):404-409.
[23] 王新平,肖金坤,张雷,等.银合金粉末粒度对Ag-MoS2复合材料摩擦磨损性能的影响[J].中国有色金属学报, 2012, 22(10):2811-2817. WANG X P, XIAO J K, ZHANG L, et al. Effect of silver alloy particle size on friction and wear properties of Ag-MoS2 composites[J]. The Chinese Journal of Nonferrous Metals, 2012, 22(10):2811-2817.
[24] 付贵忠, 孔德军, 张垒. 激光淬火后Cr12MoV渗铬层的摩擦与磨损性能[J]. 材料工程, 2016, 44(4):51-58. FU G Z, KONG D J, ZHANG L. Friction and wear properties of Cr12MoV chromized layer after laser quenching[J]. Journal of Materials Engineering, 2016, 44(4):51-58.
[25] 王敏. FeAlCrBSiNb非晶涂层形成机理和摩擦磨损行为[J]. 航空材料学报, 2016, 32(2):14-20. WANG M. Forming mechanisms and tribological properties of FeAlCrBSiNb amorphous coating deposited by high velocity arc spraying[J]. Journal of Aeronautical Materials, 2016, 32(2):14-20.
[26] RENZ A, KHADER I, KAILER A. Tribochemical wear of cutting-tool ceramics in sliding contact against a nickel-base alloy[J]. Journal of the European Ceramic Society, 2016, 36(3):705-717.
[1] 马明星, 王志新, 梁存, 周家臣, 张德良, 朱达川. CeO2掺杂对AlCoCrCuFe高熵合金的组织结构与摩擦磨损性能的影响[J]. 材料工程, 2019, 47(7): 106-111.
[2] 陈海龙, 杨学锋, 王守仁, 鹿重阳, 吴元博. 改性酚醛树脂陶瓷摩擦材料的摩擦磨损性能[J]. 材料工程, 2019, 47(6): 108-113.
[3] 王勇刚, 刘和剑, 回丽, 职山杰, 刘海青. 激光熔覆原位自生碳化物增强自润滑耐磨复合涂层的高温摩擦学性能[J]. 材料工程, 2019, 47(5): 72-78.
[4] 江泽琦, 冯彦寒, 方建华, 刘坪, 陈波水, 谷科城, 吴江. 含硫代磷酸铵盐润滑油在电磁场作用下的摩擦学性能[J]. 材料工程, 2018, 46(9): 95-100.
[5] 崔永静, 郝晶莹, 王长亮, 宇波, 汤智慧. 树脂基复合材料表面爆炸喷涂铝涂层性能研究[J]. 材料工程, 2018, 46(6): 120-124.
[6] 杨伟华, 吴玉萍, 洪晟, 李佳荟, 李柏涛. 超音速火焰喷涂WC-10Co-4Cr涂层的微观组织与摩擦磨损性能[J]. 材料工程, 2018, 46(5): 120-125.
[7] 刘小辉, 王帅星, 杜楠, 赵晴, 康佳, 刘欢欢. 电解液中Na2WO4对Ti2AlNb微弧氧化膜结构及摩擦磨损性能的影响[J]. 材料工程, 2018, 46(2): 84-92.
[8] 刘用, 马胜国, 刘英杰, 张腾, 杨慧君. AlxCrCuFeNi2多主元高熵合金的摩擦磨损性能[J]. 材料工程, 2018, 46(2): 99-104.
[9] 樊振中, 熊艳才, 陆政, 孙刚, 王胜强. Al-7Sn-1.1Ni-Cu-0.2Ti轴承合金微观组织与力学性能[J]. 材料工程, 2017, 45(6): 8-16.
[10] 金小越, 吴杰, 杨璇, 王彬, 陈琳, 曲尧, 薛文斌. 槽电压对纯铁表面液相等离子体电解硼碳氮三元共渗层摩擦磨损性能的影响[J]. 材料工程, 2017, 45(4): 58-64.
[11] 王恩青, 岳建岭, 李淼磊, 李栋, 黄峰. Si含量对VAlSiN涂层微结构、力学性能和摩擦磨损性能的影响[J]. 材料工程, 2017, 45(4): 70-76.
[12] 张雪辉, 周亮亮, 李晓闲, 张陈增, 王成, 章标, 陈颢, 梁彤祥. Y2O3对W-4.9Ni-2.1Fe合金摩擦磨损行为的影响[J]. 材料工程, 2017, 45(11): 115-121.
[13] 曹同坤, 孙何, 王晓明. 采用端面带孔电极进行电火花沉积制备自润滑涂层[J]. 材料工程, 2017, 45(10): 88-94.
[14] 刘伯威, 李亚林, 刘咏, 杨阳, 唐兵, 匡湘铭. 聚丙烯腈纤维对汽车摩擦材料性能的影响[J]. 材料工程, 2017, 45(10): 103-110.
[15] 张占辉, 王义强, 叶国云, 韩子渊, 张志杰, 骆海波. 仿生非光滑表面对对磨副的损伤机理研究[J]. 材料工程, 2016, 44(8): 98-103.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn