量子点敏化太阳能电池光阳极的研究进展

doi:10.11868/j.issn.1001-4381.2016.001002

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摘要

介绍量子点敏化太阳能电池的发展现状及趋势，针对光阳极改性来提高量子点敏化太阳能电池转化效率的方法，从半导体薄膜、量子点共敏化、量子点掺杂3个方面综合分析光阳极的研究进展和相关技术。根据制约电池效率的主要因素，提出量子点敏化太阳能电池的未来发展趋势，包括继续优化光阳极半导体薄膜的组成及结构、探索新型的宽光谱响应量子点以及发展高效的界面修饰技术等。

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	李智敏
	李钊颖
	张茂林
	王媛
	黄云霞

关键词 ：太阳能电池, 量子点敏化, 光阳极, 掺杂, 共敏化

Abstract：

This paper presents the development status and tendency of quantum dot sensitized solar cells. Photoanode research progress and its related technologies are analyzed in detail from the three ways of semiconductor thin films, quantum dot co-sensitization and quantum dot doping, deriving from the approach that the conversion efficiency can be improved by photoanode modification for quantum dot sensitized solar cells. According to the key factors which restrict the cell efficiency, the promising future development of quantum dot sensitized solar cells is proposed, for example, optimizing further the compositions and structures of semiconductor thin films for the photoanodes, exploring new quantum dots with broadband absorption and developing high efficient techniques of interface modification.

Key words： solar cell quantum dot sensitization photoanode doping co-sensitization

收稿日期: 2016-08-22 出版日期: 2017-08-10

中图分类号:

TM914.4

基金资助:陕西省自然科学基础研究计划(2015JQ6252);高等学校博士学科点专项科研基金(20130203120016);宁波市自然科学基金(2015A610037);宁波市自然科学基金(2015A610109);宁波市自然科学基金(2016A610029)

通讯作者: 李智敏 E-mail: lizhmin@163.com

作者简介: 李智敏(1976-), 男, 副教授, 博士, 主要从事新能源材料与器件的研究, 联系地址:陕西省西安市太白南路2号西安电子科技大学(710071), E-mail:lizhmin@163.com

引用本文:

李智敏, 李钊颖, 张茂林, 王媛, 黄云霞. 量子点敏化太阳能电池光阳极的研究进展[J]. 材料工程, 2017, 45(8): 132-138.
Zhi-min LI, Zhao-ying LI, Mao-lin ZHANG, Yuan WANG, Yun-xia HUANG. Research Progress of Photoanodes for Quantum Dot Sensitized Solar Cells. Journal of Materials Engineering, 2017, 45(8): 132-138.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.001002 或 http://jme.biam.ac.cn/CN/Y2017/V45/I8/132

Fig.1 量子点敏化太阳能电池结构示意图

Fig.2 量子点敏化太阳能电池的工作原理图

Fig.3 不同厚度TiO₂量子点阻挡层对QDSSCs电子寿命(a)和电子传输时间(b)的影响^[13]

Fig.4 不同金属氧化物表面修饰层对QDSSCs性能的影响^[20]

Fig.5 各种量子点敏化TiO₂薄膜和TiO₂薄膜的紫外-可见吸收光谱图^[25]

Fig.6 TiO₂/CdS/CdSe共敏化前(a)和共敏化后(b)的导带边缘与能级^[25]

Fig.7 Type-Ⅱ型量子点敏化太阳能电池的示意图^[30]

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