Yao WANG1,2, Yang CHEN1,2,*(), Ning QIAO1,2, Xin LI3, Wen-ting ZHANG1,2
1 College of Materials Science and Engineering, North China University of Science and Technology, Tangshan 063009, Hebei, China 2 Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, Tangshan 063009, Hebei, China 3 College of Civil and Architectual Engineering, North China University of Science and Technology, Tangshan 063009, Hebei, China
SiC whiskers were prepared on the matrix of graphite by using high hydrogenous silicone oil(PSO) as raw material. The effect of surface conditions of graphite and heating temperature on the growth of SiC whisker was mainly studied in this paper. The main factor which affects the nucleation and growth of SiC whisker is the heating temperature, with the heating temperature rising, the production of SiC whisker increases. The surface condition of graphite matrix also influences the growth of SiC whisker. With the nucleation points provided by graphite matrix defects increasing, the production of SiC whisker incleases and SiC whisker starts to overlap with each other. The formation process of SiC whisker includes two steps:nucleation and growth. SiC whisker nucleates at low temperature and grows at high temperature, which follows the VLS (vapor-liquid-solid) growth mechanism.
王瑶, 陈旸, 乔宁, 李欣, 张文婷. 含氢硅油制备SiC晶须的研究[J]. 材料工程, 2017, 45(10): 59-64.
Yao WANG, Yang CHEN, Ning QIAO, Xin LI, Wen-ting ZHANG. Research on SiC Whisker Prepared by H-PSO. Journal of Materials Engineering, 2017, 45(10): 59-64.
JIN P P , ZHOU W S , DING Y T . Application of whiskers in composites and their reinforcement mechanism[J]. Journal of Salt Lake Research, 2005, 13 (2): 1- 6.
NIE L F , ZHANG Y J , WEI H K . Recent researches and developments of SiC whisker-reinforced ceramic-matrix composites[J]. Shandong Ceramics, 2006, 29 (2): 16- 19.
3
JIANG J F , WANG Y . Microstructure and mechanical properties of the rheoformed cylindrical part of 7075 aluminum matrix composite reinforced with nano-sized SiC particles[J]. Materials and Design, 2015, 79 (3): 32- 41.
4
LI X K , LIU L , ZHANG Y X , et al. Synthesis of nanometer silicon carbide whiskers from binary carbonaceous silica aerogels[J]. Carbon, 2001, 39 (2): 159- 165.
doi: 10.1016/S0008-6223(00)00020-8
5
SHIN Y , WANG C M , SAMUELS W D . Synthesis of SiC nanorods from bleached wood pulp[J]. Materials Letters, 2007, 61 (13): 2814- 2817.
doi: 10.1016/j.matlet.2006.10.035
6
DHIMAN R , JOHNSON E , MORGEN P . Growth of SiC nanowhiskers from wooden precursors, separation, and characterization[J]. Ceramics International, 2011, 37 (8): 3759- 3764.
doi: 10.1016/j.ceramint.2011.06.001
7
DHAGE S , LEE H C , HASSAN M S , et al. Formation of SiC nanowhiskers by carbothermic reduction of silica with activated carbon[J]. Materials Letters, 2009, 63 (2): 174- 176.
doi: 10.1016/j.matlet.2008.09.056
8
PANDA S K , SENGUPTA J , JACOB C . Synthesis of β-SiC/SiO2 core-sheath nanowires by CVD technique using Ni as catalyst[J]. Journal of Nanoscience and Nanotechnology, 2010, 10 (5): 3046- 3052.
doi: 10.1166/jnn.2010.2167
LI X H , GU L H , CHEN S H , et al. Research progress of producing whisker reinforced porous ceramics by in-site synthesis technique[J]. Materials Review, 2015, 29 (3): 35- 31.
doi: 10.11896/j.issn.1005-023X.2015.03.013
10
CETINKAYA S , EROGLU S . Chemical vapor deposition of C on SiO2 and subsequent carbothermal reduction for the synthesis of nanocrystalline SiC particles/whiskers[J]. Journal of Refractory Metals and Hard Materials, 2011, 29 (2): 566- 572.
WU Y J , ZHANG Y F , YANG Z X , et al. Catalyst-free method of preparing β-SiC nanowhiskers by using carbon whiskers[J]. Journal of Inorganic Materials, 2005, 20 (3): 740- 744.
WANG Y Z , GUO M X . Growth technology and mechanism of SiC whisker by use of rice hulls[J]. Journal of the Chinese Ceramic Society, 2013, 21 (1): 22- 28.
HUANG F P , LI H J , LU J H , et al. Growth process and mechanism of SiC whiskers by induction of carbon fiber[J]. Journal of the Chinese Ceramic Society, 2007, 35 (5): 643- 647.
ZHANG J Z , ZHANG Y , JIANG M X , et al. Microstructure and growth mechanism of SiC whiskers synthesized by using different raw materials[J]. Journal of Functional Materials, 2012, 43 (13): 1782- 1785.
doi: 10.3969/j.issn.1001-9731.2012.13.031
17
CHEN Y F , LIU X Z , DENG X W . Factors affecting the growth of SiC nano-whiskers[J]. Journal of Materials Science & Technology, 2010, 26 (11): 1041- 1046.
18
CHEN Y , WANG C G , ZHU B , et al. Growth of SiC whiskers from hydrogen silicone oil[J]. Journal of Crystal Growth, 2012, 357, 42- 47.
doi: 10.1016/j.jcrysgro.2012.07.043
19
GRILL A , PATEL V . Low dielectric constant films prepared by plasma-enhanced chemical vapor deposition from tetramethylsilane[J]. Journal of Applied Physics, 1999, 85 (6): 3314- 3318.
doi: 10.1063/1.369677
20
KIM M T , LEE J . Characterization of amorphous SiC:H films deposited from hexamethyldisilazane[J]. Thin Solid Films, 1997, 303 (1/2): 173- 179.
CHEN Y C , WANG Q B . Studies on the growth mechanism and the kinetics of synthesizing SiC whiskers by VLS process[J]. Chinese Journal of Chemical Physics, 1998, 11 (3): 258- 260.
CHEN Y , WANG C G , GAO R R . Research of the preparation technology for the SiC whisker[J]. Journal of Inorganic Materials, 2013, 28 (7): 758- 762.
23
LI X , ZHANG G Q . Synthesis of SiC whiskers by VLS and VS process[J]. Ceramics International, 2016, 42 (5): 5668- 5676.
doi: 10.1016/j.ceramint.2015.12.091
2017, Vol. 45 
), 乔宁1,2, 李欣3, 张文婷1,2
