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材料工程  2016, Vol. 44 Issue (3): 35-39    DOI: 10.11868/j.issn.1001-4381.2016.03.006
  材料与工艺 本期目录 | 过刊浏览 | 高级检索 |
中温固化耐高温酚醛树脂的制备及性能
薛刚, 李坚辉, 王磊, 史利利, 张斌, 孙明明, 张绪刚
黑龙江省科学院石油化学研究院, 哈尔滨 150040
Preparation and Properties of Heat-resistant Phenolic Resin Cured at Medium Temperature
XUE Gang, LI Jian-hui, WANG Lei, SHI Li-li, ZHANG Bin, SUN Ming-ming, ZHANG Xu-gang
Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, China
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摘要 利用硼酸、有机硅预聚物对酚醛树脂进行改性,同时引入活性单体间苯二酚,制得了可中温固化的耐高温改性酚醛树脂。采用FTIR对改性酚醛树脂的结构进行了表征;通过DSC,TGA考察了固化行为和耐热性能;通过SEM考察了固化物的微观形态,并结合EDAX能谱仪对其元素成分进行了分析。将改性酚醛树脂与无机组合填料及多聚甲醛混合制得了耐高温酚醛胶黏剂,经过100℃固化后测试了胶黏剂的粘接强度和耐温性。结果表明,胶黏剂可在中温固化并具有良好的耐高温和粘接性能,1000℃下试样剪切强度可达1.7MPa。
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薛刚
李坚辉
王磊
史利利
张斌
孙明明
张绪刚
关键词 酚醛树脂中温固化耐高温固化行为粘接性能    
Abstract:Using boric acid and organic silicon prepolymer to modify phenolic resin, meanwhile introducing active monomer resorcinol, a kind of high temperature resistant phenolic resin which can be cured at medium temperature was prepared. The structure of the resin was characterized by fourier transform infrared spectroscopy(FTIR). The curing behaviour and thermal stability were investigated by thermal analysis (DSC and TGA). Scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDAX) were used to study the microstructures and the distribution of elements. Modified resin and inorganic filler were mixed together and paraformaldehyde was used as curing agent, then the adhesive was obtained. After cured at 100℃, its thermal and bonding properties were tested. The result shows that the adhesive can be cured at medium temperature has outstanding high temperature resistant and bonding properties. The shear strength at 1000℃ can reach 1.7MPa.
Key wordsphenolic resin    medium temperature curing    high temperature resistant    curing behavior    bonding property
收稿日期: 2014-06-03      出版日期: 2016-03-22
中图分类号:  TQ433  
通讯作者: 张斌(1964-),男,研究员,博士,研究方向:特种胶黏剂与密封材料,联系地址:哈尔滨市中山路164号黑龙江省科学院石油化学研究院(150040),E-mail:zhangbinaaa@sina.cn     E-mail: zhangbinaaa@sina.cn
引用本文:   
薛刚, 李坚辉, 王磊, 史利利, 张斌, 孙明明, 张绪刚. 中温固化耐高温酚醛树脂的制备及性能[J]. 材料工程, 2016, 44(3): 35-39.
XUE Gang, LI Jian-hui, WANG Lei, SHI Li-li, ZHANG Bin, SUN Ming-ming, ZHANG Xu-gang. Preparation and Properties of Heat-resistant Phenolic Resin Cured at Medium Temperature. Journal of Materials Engineering, 2016, 44(3): 35-39.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.03.006      或      http://jme.biam.ac.cn/CN/Y2016/V44/I3/35
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