Please wait a minute...
 
材料工程  2016, Vol. 44 Issue (12): 107-117    DOI: 10.11868/j.issn.1001-4381.2016.12.017
  综述 本期目录 | 过刊浏览 | 高级检索 |
氧化石墨烯复合材料的研究现状及进展
吕生华, 朱琳琳, 李莹, 贺亚亚, 杨文强
陕西科技大学 资源与环境学院, 西安 710021
Current Situation and Progress of Graphene Oxide Composites
LYU Sheng-hua, ZHU Lin-lin, LI Ying, HE Ya-ya, YANG Wen-qiang
College of Resources & Environment, Shaanxi University of Science & Technology, Xi'an 710021, China
全文: PDF(22397 KB)   HTML()
输出: BibTeX | EndNote (RIS)      
摘要 氧化石墨烯(Graphene Oxide,GO)以其独特的二维纳米片层结构、超大的比表面积和亲水极性界面,使其在功能复合材料领域有着广泛的应用和发展前景。本文综述了近年来GO复合材料在增强增韧、吸附分离、光催化及生物医药等方面的研究现状及进展,介绍了GO调控高分子材料及水泥基体形成规整有序的微观结构形貌而产生显著的增强增韧效果的机理,分析了GO复合材料在吸附、催化、生物医药等方面作用原理,指出了GO增强增韧复合材料、GO吸附复合材料和GO光催化复合材料的应用前景和发展趋势。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
吕生华
朱琳琳
李莹
贺亚亚
杨文强
关键词 氧化石墨烯复合材料微观结构增强增韧光催化降解    
Abstract:Graphene oxide (GO) has wide applications and development prospects in the functional composites owing to its many unique properties, such as two-dimensional structure and large theoretical specific surface areas as well as hydrophilic and polarized interface. The present situation and progress of the graphene oxide composites used in reinforcing and toughening, adsorption separation, photocatalysis and biological medicine were introduced in this paper. The mechanism of producing reinforcing and toughening of polymer and cement based composites caused by forming regular and ordered microstructure regulated with GO nanosheets was mainly summerized. Meanwhile, application principle of the GO composites in the field of adsorption, photocatalysis and biological medicine were analyzed. Finally, the application and development trend of GO composites in reinforcing and toughness as well as adsorption and photocatalysis were pointed out.
Key wordsgraphene oxide    composite material    microstructure    reinforcing and toughening    photocatalytic degradation
收稿日期: 2015-06-03      出版日期: 2016-12-16
中图分类号:  O613.71  
  TQ172.4  
通讯作者: 吕生华(1963-),男,教授,博士生导师,主要从事氧化石墨烯的制备及复合材料的研究,联系地址:陕西省西安市未央大学园区陕西科技大学资源与环境学院1B实验楼(710021),E-mail:lvsh@sust.edu.cn     E-mail: lvsh@sust.edu.cn
引用本文:   
吕生华, 朱琳琳, 李莹, 贺亚亚, 杨文强. 氧化石墨烯复合材料的研究现状及进展[J]. 材料工程, 2016, 44(12): 107-117.
LYU Sheng-hua, ZHU Lin-lin, LI Ying, HE Ya-ya, YANG Wen-qiang. Current Situation and Progress of Graphene Oxide Composites. Journal of Materials Engineering, 2016, 44(12): 107-117.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.12.017      或      http://jme.biam.ac.cn/CN/Y2016/V44/I12/107
[1] FAN Z J,WANG K,WEI T,et al.An environmentally friendly and efficient route for the reduction of graphene oxide by aluminum powder[J].Carbon,2010,48(5):1686-1689.
[2] 杨勇辉,孙红娟,彭同江.石墨烯的氧化还原法制备及结构表征[J].无机化学学报,2011,26(11):2083-2090. YANG Y H,SUN H J,PENG T J.Synthesis and structural characterization of graphene by oxidation reduction[J].Chinese Journal of Inorganic Chemistry,2011,26(11):2083-2090.
[3] AKHAVAN O,GHADERI E.Photocatalytic reduction of graphene oxide nanosheets on TiO2 thin film for photoinactivation of bacteria in solar light irradiation[J].The Journal of Physical Chemistry C,2009,113(47):20214-20220.
[4] SHIN H J,KIM K K,BENAYAD A.Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance[J].Advanced Functional Materials,2009,19(12):1987-1992.
[5] 万武波,赵宗彬,胡涵,等.柠檬酸钠绿色还原制备石墨烯[J].新型炭材料,2011,26(1):16-20. WAN W B,ZHAO Z B,HU H,et al."Green" reduction of graphene oxide to graphene by sodium citrate[J].New Carbon Materials,2011,26(1):16-20.
[6] JIN Y H,HUANG S,ZHANG M,et al.A green and efficient method to produce graphene for electrochemical capacitors from graphene oxide using sodium carbonate as a reducing agent[J].Applied Surface Science,2013,268(3):541-546.
[7] AKHAVAN O.Photocatalytic reduction of graphene oxides hybridized by ZnO nanoparticles in ethanol[J].Carbon,2011,49(1):11-18.
[8] CHOOBTASHANI M,AKHAVAN O.Visible light-induced photocatalytic reduction of graphene oxide by tungsten oxide thin films[J].Applied Surface Science,2013,276:628-634.
[9] AKHAVAN O,KALAEE M,ALAVI Z S,et al.Increasing the antioxidant activity of green tea polyphenols in the presence of iron for the reduction of graphene oxide[J].Carbon,2012,50(8):3015-3025.
[10] KAUPPILA J,KUNNAS P,DAMLIN P.Electrochemical reduction of graphene oxide film in aqueous and organic solutions[J].Electrochemical Acta,2013,89:84-89.
[11] WANG C,ZHAN L,QIAO W M,et al.Preparation of graphene nanosheets through detonation[J].New Carbon Materials,2011,26(1):21-25.
[12] STANKOVICH S,PINER R D,NGUYEN S T,et al.Synthesis and exfoliation of isocyanate treated graphene oxide nanoplatelets[J].Carbon,2006,44(15):3342-3347.
[13] FANG F,KONG L T,HUANG J R,et al.Removal of cobalt ions from aqueous solution by an amination graphene oxide nanocomposite[J].Journal of Hazardous Materials,2014,270:1-10.
[14] ZHUANG X D,CHEN Y,LIU G,et al.Conjugated polymer-functionalized graphene oxide:synthesis and nonvolatile rewritable memory effect[J].Advanced Materials,2010,22(15):1731-1735.
[15] CHIEN H C,TSAI L D,HUANG C P,et al.Sulfonated graphene oxide/Nafion composite membranes for high-performance direct methanol fuel cells[J].International Journal of Hydrogen Energy,2013,38(31):13792-13801.
[16] YAZMIN I A-V,CESAR C L-P,MARCELA M,et al.Nitroxide-functionalized graphene oxide from graphite oxide[J].Carbon,2013,63:376-389.
[17] ISIS E M-C,JOEY D M,HANG N N,et al.Graphene oxide functionalized with ethylenediamine triacetic acid for heavy metal adsorption and anti-microbial applications[J].Carbon,2014,77(10):289-301.
[18] 郑玉婴.功能化氧化石墨烯纳米带/EVA复合材料薄膜的制备及表征[J].材料工程,2015,43(2):99-102. ZHENG Y Y.Preparation and characterization of functionalized graphene oxide nanoribbons/EVA composite films[J].Journal of Materials Engineering,2015,43(2):99-102.
[19] 杨文彬,张丽,刘菁伟,等.石墨烯复合材料的制备及应用研究进展[J].材料工程,2015,43(3):91-97. YANG W B,ZHANG L,LIU J W,et al.Progress in research on preparation and application of graphene composites[J].Journal of Materials Engineering,2015,43(3):91-97.
[20] MARIA L D L.Crystallization behavior of poly(L-lactic acid)[J].Polymer,2006,47(21):7554-7563.
[21] RENÉ A,MARIA L D L.Kinetics of crystal nucleation of poly(L-lactic acid)[J].Polymer,2013,54(26):6882-6885.
[22] ARTUR M P,SUSANA M,INES C G.et al.Biocompatibility of poly(lactic acid) with incorporated graphene-based materials[J].Colloids and Surfaces B:Biointerfaces,2013,104(3):229-238.
[23] WANG H S,QIU Z B.Crystallization kinetics and morphology of biodegradable poly(l-lactic acid)/graphene oxide nanocomposites:influences of graphene oxide loading and crystallization temperature[J].Thermochimica Acta,2012,527:40-46.
[24] WANG H S,QIU Z B.Crystallization behaviors of biodegradabale poly(L-lactic acid)/graphene oxide nanocomposites from the amorphous state[J].Thermochim Acta,2011,526(1-2):229-236.
[25] WANG B J,LI Y G,WENG G S,et al.Reduced graphene oxide enhances the crystallization and orientation of poly(ε-caprolactone)[J].Composites Science Technology,2014,96:63-70.
[26] NING N Y,ZHANG W,YAN J J,et al.Largely enhanced crystallization of semi-crystalline polymer on the surface of glass fiber by using graphene oxide as a modifier[J].Polymer,2013,54(1):303-309.
[27] 吕生华,孙婷,刘晶晶,等.氧化石墨烯纳米片层对水泥基复合材料的增韧效果及机制[J].复合材料学报,2014,31(3):644-652. LV S H,SUN T,LIU J J,et al.Toughening effect and mechanism of graphene oxide nanosheets on cement matrix composites[J].Acta Materiae Compositae Sinica,2014,31(3):644-652.
[28] 吕生华,周庆芳,孙婷,等.GO纳米片层对水泥水化晶体及胶砂力学性能的影响[J].建筑材料学报,2014,17(5):749-754. LV S H,ZHOU Q F,SUN T,et al.Effect of graphene oxide nanosheets on cement hydration crystals and mechanical properties of mortar[J].Journal of Building Materials,2014,17(5):749-754.
[29] 吕生华,孙婷,马宇娟,等.纳米氧化石墨烯对水泥复合材料中水化晶体结构的控制及增韧作用[J].混凝土,2013,(11):1-6. LV S H,SUN T,MA Y J,et al.Regulation of graphene oxide on microstructure of hydration crystals of cement composites and its impact reinforcing toughenss[J].Concrete,2013,(11):1-6.
[30] LV S H,MA Y J,QIU C C,et al.Effect of graphene oxide nanosheets of microstructure and mechanical properties of cement composites construct[J].Construction and Building Materials,2013,49(12):121-127.
[31] FAKHIM B,HASSANI A,RASHIDI A,et al.Preparation and mechanical properties of graphene oxide:cement nanocomposites[J].The Scientific World Journal,2014,(4):983-990.
[32] KIM J,COTE L J,KIM F,et al.Graphene oxide sheets at interfaces[J].Journal of the American Chemistry Society,2010,132:8180-8186.
[33] CHANG S T,LIN K-Y A,LU C.Efficient adsorptive removal of Tetramethylammonium hydroxide(TMAH) from water using graphene oxide[J].Separation and Purification Technology,2014,133(36):99-107.
[34] WANG H,YUAN X Z,WU Y,et al.Adsorption characteristics and behaviors of graphene oxide for Zn(II) removal from aqueous solution[J].Applied Surface Science,2013,279(8):432-440.
[35] 孙彤,崔欣,候雨,等.氧化石墨烯的功能化及生物相容性研究[J].应用化工,2013,42(5):806-808. SUN T,CUI X,HOU Y,et al.The functionalization and biocompatibility of graphene oxide[J].Applied Chemical Industry,2013,42(5):806-808.
[36] SUN J P,LIANG Q L,HAN Q,et al.One-step synthesis of magnetic graphene oxide nanocomposite and its application in magnetic solid phase extraction of heavy metal ions from biological samples[J].Talanta,2015,132(4):557-563.
[37] 张燚,陈彪,杨祖培,等.Fe3O4磁性纳米粒子-氧化石墨烯复合材料的可控制备及结构与性能表征[J].物理化学学报,2011,27(5):1261-1266. ZHANG Y,CHEN B,YANG Z P,et al.Controlled synthesis and characterization of the structure and property of Fe3O4 nanopartical-graphene oxide composites[J].Acta Physico-Chimica Sinica,2011,27(5):1261-1266.
[38] FAN L L,LUO C N,SUN M,et al.Highly selective adsorption of lead ions by water-dispersible magnetic chitosan/graphene oxide composites[J].Colloids and Surfaces B:Biointerfaces,2013,103(1):523-529.
[39] FAN L L,LUO C N,SUN M,et al.Synthesis of magnetic-cyclodextrin chitosan/graphene oxide as nanoadsorbent and its application in dye adsorption and removal[J].Colloids and Surfaces B:Biointerfaces,2013,103(6):601-607.
[40] YE N S,XIE Y L,SHI P Z,et al.Synthesis of magnetite/graphene oxide/chitosan composite and its application for protein adsorption[J].Materials Science and Engineering:C,2014,45:8-14.
[41] EHSAN Z,ALI M,ALI J.A novel hierarchical nanobiocomposite of graphene oxide-magnetic chitosan grafted with mercapto as a solid phase extraction sorbent for the determination of mercury ions in environmental water samples[J].Analytica Chimica Acta,2014,850:49-56.
[42] 饶维,蔡蓉,陈星,等.氧化石墨烯表面新型磁性四溴双酚A印迹复合材料的制备及吸附性能[J].高等学校化学学报,2013,34(6):1353-1359. RAO W,CAI R,CHEN X,et al.Preparation and adsorption properties of novel magnetic tetrabromobisphenol a molecularly imprinted composite material based on graphene oxide surface[J].Chemical Journal of Chinese Universities,2013,34(6):1353-1359.
[43] ZHU C Q,LU B A,SU Q,et al.A simple method for the preparation of hollow ZnO nanospheres for use as a high performance photocatalyst[J].Nanoscale,2012,4(10):3060-3064.
[44] LIU J W,YANG T,MA L Y,et al.Nickel nanoparticle decorated graphene for highly selective isolation of polyhistidine-tagged proteins[J].Nanotechnology,2013,24(50):505704.
[45] NGUYEN T L,DO T C,NGO X D,et al.Photochemical decoration of silver nanoparticles on graphene oxide nanosheets and their optical characterization[J].Journal of Alloys and Compounds,2014,615(2):843-848.
[46] QIN J L,LI R,LU C Y,et al.Ag/ZnO/graphene oxide heterostructure for the removal of rhodamine B by the synergistic adsorption-degradation effects[J].Ceramics International,2015,41(3):4231-4237.
[47] HE Y Q,ZHANG N N,WANG X D.Adsorption of graphene oxide/chitosan porous materials for metal ions[J].Chinese Chemical Letters,2011,22(7):859-862.
[48] YU B W,XU J,LIU J H,et al.Adsorption behavior of copper ions on graphene oxide-chitosan aerogel[J].Journal of Environmental Chemical Engineering,2013,1(4):1044-1050.
[49] WANG Y,LIU X,WANG H F,et al.Microporous spongy chitosan monoliths doped with graphene oxide as highly effective adsorbent for methyl orange and copper nitrate (Cu(NO3)2) ions[J].Journal of Colloid and Interface Science,2014,416:243-251.
[50] GE H C,MA Z W.Microwave preparation of triethylenetetramine modified grapheneoxide/chitosan composite for adsorption of Cr(VI)[J].Carbohydrate Polymers,2015,131:280-287.
[51] LI X Y,ZHOU H H,WU W Q,et al.Studies of heavy metal ion adsorption on chitosan/sulfydryl functionalized graphene oxide composites[J].Journal of Colloid and Interface Science,2015,448:389-397.
[52] DU Q J,SUN J K,LI Y H,et al.Highly enhanced adsorption of congo red onto graphene oxide/chitosan fibers by wet-chemical etching off silica nanoparticles[J].Chemical Engineering Journal,2014,245(6):99-106.
[53] NIKOLINA A T,GEORGE Z K,NIKOLAOS K L,et al.Graphite oxide/chitosan composite for reactive dye removal[J].Chemical Engineering Journal,2013,217:256-265.
[54] LUO S L,XU X L,ZHOU G Y,et al.Amino siloxane oligomer-linked graphene oxide as an efficient adsorbent for removal of Pb(II) from wastewater[J].Journal of Hazardous Materials,2014,274(12):145-155.
[55] XIA S J,NI M Z.Preparation of poly(vinylidene fluoride) membranes with graphene oxide addition for natural organic matter removal[J].Journal of Membrane Science,2015,473:54-62.
[56] LIN D,LIU C R,CHENG G J.Single-layer graphene oxide reinforced metal matrix composites by laser sintering:microstructure and mechanical property enhancement[J].Acta Materialia,2014,80:183-193.
[57] PASZKIEWICZ S,SZYMCZYK A,ŠPITALSKY Z,et al.Structure and properties of nanocomposites based on PTT-block-PTMO copolymer and graphene oxide prepared by in situ polymerization[J].European Polymer Journal,2014,50:69-77.
[58] LIN Q L,QU L J,LU Q F,et al.Preparation and properties of graphene oxide nanosheets/cyanate ester resin composites[J].Polymer Testing,2013,32(2):330-337.
[59] ANDREIA F D F,DIEGO S T M,STELA M M M,et al.Anti-adhesion and antibacterial activity of silver nanoparticles supported on graphene oxide sheets[J].Colloids and Surfaces B:Biointerfaces,2014,113:115-124.
[60] YU L,ZHANG Y,ZHANG B,et al.Preparation and characterization of HPEI-GO/PES ultrafiltration membrane with antifouling and antibacterial properties[J].Journal of Membrane Science,2013,447:452-462.
[61] 张建斌,田海锋,查飞,等.纳米二氧化钛光催化降解染料废水动力学研究[J].应用化工,2014,43(8):1369-1372. ZHANG J B,TIAN H F,ZHA F,et al.Study of dynamics and photocatalytic degredation of dyeing wastewater by nano-titanium dioxide[J].Applied Chemical Industry,2014,43(8):1369-1372.
[62] 张平,莫尊理,张春,等.磁响应性TiO2/石墨烯纳米复合材料的合成及光催化性能[J].材料工程,2015,43(3):72-77. ZHANG P,MO Z L,ZHANG C,et al.Preparation and photocatalytic properties of magnetic responsive TiO2/graphene nanocomposites[J].Journal of Materials Engineering,2015,43(3):72-77.
[63] SANTOS V C,WILSON K,LEE A F,et al.Physicochemical properties of WOx/ZrO2 catalysts for palmitic acid esterification[J].Applied Catalysis B:Environmental,2015,162:75-84.
[64] 张琼,贺蕴秋,陈小刚,等.氧化钛/氧化石墨烯复合结构及其光催化性能[J].科学通报,2010,55(7):620-628. ZHANG Q,HE Y Q,CHEN X G,et al.Structure and photocatalytic properties of TiO2-graphene oxide intercalated composite[J].Chinese Science Bulletin,2010,55(7):620-628.
[65] CHEN Y L,ZHANG C E,DENG C,et al.Preparation of ZnO/GO composite material with highly photocatalytic performance via an improved two-step method[J].Chinese Chemical Letters,2013,24(6):518-520.
[66] LI C P,ZHU H J,HOU T T,et al.Simultaneous polymerization and crosslinking for the synthesis of molecular-level graphene oxide-polyacryl amide-CeOx composites[J].Chemical Engineering Journal,2015,263:27-37.
[67] ZHANG M,MAO X B,WANG C X,et al.The effect of graphene oxide on conformation change,aggregation and cytotoxicity of HIV-1 regulatory protein(Vpr)[J].Biomaterials,2012,34(4):1383-1390.
[68] ALAVA T,MANN J A,THEODORE C,et al.Control of the graphene-protein interface is required to preserve adsorbed protein function[J].Analytical Chemistry,2013,85(5):2754-2759.
[69] CHEN M L,WANG H,MAO Q X,et al.Hydrous-ferric oxide nanorods grown on PEGylated graphene oxide with superior capacity for selective adsorption of albumin[J].Carbon,2015,85:335-343.
[70] ZHOU D M,XI Q,LIANG M F,et al.Graphene oxide-hairpin probe nanocomposite as a homogeneous assay platform for DNA base excision repair screening[J].Biosensors and Bioelectronics,2013,41(5):359-365.
[71] XIN J,HAO Y M,MAX R S,et al.Electrospinning thermoplastic polyurethane/graphene oxide scaffolds for small diameter vascular graft applications[J].Materials Science and Engineering C,2015,49:40-50.
[72] JUSTIN R,CHEN B Q.Characterisation and drug release performance of biodegradable chitosan-graphene oxide nanocomposites[J].Carbohydrate Polymers,2014,103(1):70-80.
[73] WANG J,LIU C H,SHUAI Y,et al.Controlled release of anticancer drug using graphene oxide as a drug-binding effector in konjac glucomannan/sodium alginate hydrogels[J].Colloids and Surfaces B:Biointerfaces,2014,113(13):223-229.
[1] 陈珂龙, 张桐, 崔溢, 王智勇. 超支化聚合物(HBPs)改性环氧树脂的研究进展[J]. 材料工程, 2019, 47(7): 11-18.
[2] 王桂芳, 刘忠侠, 张国鹏. 球磨时间对热压烧结制备TiC-CoCrFeNi复合材料微观组织及力学性能的影响[J]. 材料工程, 2019, 47(6): 94-100.
[3] 尚楷, 武志红, 张路平, 王倩, 郑海康. 模板法制备MoSi2/竹炭复合材料及吸波性能[J]. 材料工程, 2019, 47(5): 122-128.
[4] 何宗倍, 张瑞谦, 付道贵, 李鸣, 陈招科, 邱邵宇. 不同界面SiC纤维束复合材料的拉伸力学行为[J]. 材料工程, 2019, 47(4): 25-31.
[5] 李亚锋, 礼嵩明, 黑艳伟, 邢丽英, 陈祥宝. 太阳辐照对芳纶纤维及其复合材料性能的影响[J]. 材料工程, 2019, 47(4): 39-46.
[6] 李曦. 二维和零维纳米材料协同增强的高性能纳米复合材料[J]. 材料工程, 2019, 47(4): 47-55.
[7] 李芹, 盛利成, 董丽敏, 张彦飞, 金立国. ZnCo2O4及ZnCo2O4/rGO复合材料的制备与电化学性能[J]. 材料工程, 2019, 47(4): 71-76.
[8] 张航, 路媛媛, 王涛, 鲁亚冉, 刘德健. 激光熔覆WC/H13-Inconel625复合材料的冲击韧性与磨损性能[J]. 材料工程, 2019, 47(4): 127-134.
[9] 李惠, 肖文龙, 张艺镡, 马朝利. 多重结构Ti-B4C/Al2024复合材料的组织和力学性能[J]. 材料工程, 2019, 47(4): 152-159.
[10] 史思涛, 陈畅, 郭政, 李国新, 伍勇华, 苏明周, 王会萌. 原料配比对多孔MgO/Fe-Cr-Ni复合材料性能的影响[J]. 材料工程, 2019, 47(4): 167-173.
[11] 赵双赞, 燕绍九, 陈翔, 洪起虎, 李秀辉, 戴圣龙. 石墨烯纳米片增强铝基复合材料的动态力学行为[J]. 材料工程, 2019, 47(3): 23-29.
[12] 杨宇凯, 张宝, 王旭东, 张虎生, 武岳, 关永军. 石墨烯及碳化硅增强铝基复合材料的冲击力学行为[J]. 材料工程, 2019, 47(3): 15-22.
[13] 贺毅强, 徐虎林, 钱晨晨, 冯立超, 乔斌, 尚峰, 李化强. 机械合金化后注射成形制备Cu/Al2O3复合材料的显微组织与力学性能[J]. 材料工程, 2019, 47(3): 154-161.
[14] 刘巧沐, 黄顺洲, 何爱杰. 碳化硅陶瓷基复合材料在航空发动机上的应用需求及挑战[J]. 材料工程, 2019, 47(2): 1-10.
[15] 张博, 付琪智, 林森, 陈廷芳, 孙仕勇, 蒋卉. 炭化纳米Co3O4/硅藻土复合材料制备及其性能[J]. 材料工程, 2019, 47(2): 62-67.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn