双向脉冲快速电沉积非晶态Ni-P/Al<sub>2</sub>O<sub>3</sub>复合镀层

doi:10.11868/j.issn.1001-4381.2017.000119

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采用双向脉冲电沉积法制备出高P非晶态Ni-P/Al₂O₃复合镀层，利用扫描电镜（SEM）和能谱分析（EDS）方法考察镀层的微观形貌和化学组成，采用X射线衍射技术（XRD）表征镀层的相结构，并通过分析金属镀层和复合镀层的电化学测试结果，评价不同种类镀层的耐腐蚀能力。结果表明：与直流电沉积法相比，双向脉冲电沉积法可将镀层中的P含量提高至12.06%（质量分数），有利于非晶态Ni-P合金镀层的形成。采用双向脉冲法制备的Ni-P/Al₂O₃复合镀层比直流电沉积法制备的Ni-P/Al₂O₃复合镀层更平整、结晶更致密。脉冲电沉积法制备的非晶态Ni-P合金镀层具有更好的耐蚀性，而且复合微粒Al₂O₃的加入，对进一步提高非晶态Ni-P合金镀层的耐蚀性有积极作用。

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关键词 ：双向脉冲, 电沉积, 复合镀层, 非晶态结构

Abstract：

The amorphous Ni-P/Al₂O₃ composite coatings with high P content were deposited using the bi-directional pulse electrodeposition. The micrographic morphology and chemical composition of the coatings were examined using the scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) analysis. Also, the phase structure of the coating was characterized using the X-ray diffraction (XRD). By analyzing the electrochemical test results of the coatings, the corrosion resistances of different types of deposits were evaluated. The results show that compared to the direct current (DC) plating, the P content in the Ni-P alloy coatings increases to 12.06%(mass fraction) by bi-directional pulse electrodeposition, which facilitates the formation of the amorphous Ni-P alloy coatings. The PC plating can produce a finer and denser Ni-P/Al₂O₃ composite coatings with more compact crystallization than that deposited by DC. The Ni-P alloy coatings deposited by the pulse electrodeposition has a better corrosion resistance, and adding composite particles of Al₂O₃ can further contribute to improving the corrosion resistance of the amorphous Ni-P alloy coatings.

Key words： bi-directional pulse electrodeposition composite coating amorphous structure

收稿日期: 2017-01-25 出版日期: 2018-03-20

中图分类号:

TQ153.2

通讯作者: 费敬银 E-mail: jyfei@nwpu.edu.cn

作者简介: 费敬银(1962-), 男, 博士, 副教授, 主要从事新型功能表面改性技术与应用研究, 联系地址:陕西省西安市西北工业大学长安校区理学院(710129), E-mail:jyfei@nwpu.edu.cn

引用本文:

彭秋艳, 费敬银, 陈居田, 赵非凡, 冯旭. 双向脉冲快速电沉积非晶态Ni-P/Al₂O₃复合镀层[J]. 材料工程, 2018, 46(3): 81-90.
Qiu-yan PENG, Jing-yin FEI, Ju-tian CHEN, Fei-fan ZHAO, Xu FENG. Fast Electrodeposition of Amorphous Ni-P/Al₂O₃ Composite Coatings Deposited by Bi-directional Pulse. Journal of Materials Engineering, 2018, 46(3): 81-90.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2017.000119 或 http://jme.biam.ac.cn/CN/Y2018/V46/I3/81

Table 1 镀液组成(g·L^-1)

Table 2 施镀工艺参数

Fig.1 脉冲波形示意图

Fig.2 镀液中H₃PO₃浓度对镀层中P含量的影响

Fig.3 不同H₃PO₃浓度下制备的Ni-P合金镀层微观形貌(a)10g/L；(b)30g/L；(c)40g/L

Fig.4 平均电流密度对镀层中P含量的影响

Fig.5 平均电流密度对镀层形貌的影响(a)I_av=10A/dm²; (b)I_av=15A/dm²

Fig.6 占空比对镀层中P含量的影响

Fig.7 占空比对镀层形貌的影响(a)λ=0.3;(b)λ=0.7

Fig.8 逆向脉冲系数对镀层中P含量的影响

Fig.9 逆向脉冲系数对镀层形貌的影响(a)x=0；(b)x=0.3

Fig.10 频率对镀层中P含量的影响

Fig.11 频率对镀层形貌的影响(a)f=1Hz; (b)f=30Hz

Fig.12 不同P含量镀层的XRD衍射图

Fig.13 镀液中H₃PO₃浓度对镀层中Al₂O₃含量的影响

Fig.14 Ni-P/Al₂O₃复合镀层的微观形貌(a)直流法; (b)脉冲法

Fig.15 不同镀层在3.5%NaCl溶液中的极化曲线

Table 3 不同镀层的自腐蚀电位和自腐蚀电流密度

Fig.16 不同电沉积条件制备的Ni-P合金镀层形貌(a)DC，w_P =6.93%；(b)PC，w_P =12.06%

1	STEVANOVIC R , STEVANOVIC J , DESPIC A . Electrochemical activation of the electroless deposition of Ni-P alloy and phase structure characterization of the deposit part Ⅱ:single bath system[J]. Journal of Applied Electrochemistry, 2001, 31 (8): 855- 862. doi: 10.1023/A:1017518817282
2	GU C D , LIAN J S , LI G Y , et al. Electroless Ni-P plating on AZ91D magnesium alloy from a sulfate solution[J]. Journal of Alloys and Compounds, 2005, 391 (1): 104- 109.
3	王红星, 谈淑咏, 柳秉毅. 纳米SiC浓度对Ni/纳米MoS₂基复合镀层结构和耐磨性能的影响[J]. 材料工程, 2015, 43 (10): 60- 65. doi: 10.11868/j.issn.1001-4381.2015.10.010
3	WANG H X , TAN S Y , LIU B Y . Effect of nano-SiC content on microstructure and wear resistance of Ni/nano-MoS₂ based composite coating[J]. Journal of Materials Engineering, 2015, 43 (10): 60- 65. doi: 10.11868/j.issn.1001-4381.2015.10.010
4	SULITANU N D . Electrochemical deposition of novel nanostructured magnetic thin films for advanced applications[J]. Materials Science and Engineering:B, 2002, 95 (3): 230- 235. doi: 10.1016/S0921-5107(02)00237-4
5	HUANG H C , CHUNG S T , PAN S J , et al. Microstructure evolution and hardening mechanisms of Ni-P electrodeposits[J]. Surface and Coatings Technology, 2010, 205 (7): 2097- 2103. doi: 10.1016/j.surfcoat.2010.08.115
6	程延海, 朱真才, 韩正铜, 等. 热处理对Ni-P镀层结构及硬度的影响[J]. 材料工程, 2010, (11): 48- 51. doi: 10.3969/j.issn.1001-4381.2010.11.012
6	CHENG Y H , ZHU Z C , HAN Z T , et al. Effect of heat treatment on the structure and hardness of the electroless Ni-P deposits[J]. Journal of Materials Engineering, 2010, (11): 48- 51. doi: 10.3969/j.issn.1001-4381.2010.11.012
7	GUO Z , KEONG K G , SHA W . Crystallisation and phase transformation behaviour of electroless nickel phosphorus platings during continuous heating[J]. Journal of Alloys and Compounds, 2003, 358 (1): 112- 119.
8	ALEXIS J , ETCHEVERRY B , BEGUIN J D , et al. Structure, morphology and mechanical properties of electrodeposited composite coatings Ni-P/SiC[J]. Materials Chemistry and Physics, 2010, 120 (2): 244- 250.
9	金世伟, 康敏, 邵越. 热处理非晶态Ni-P合金镀层的晶化过程[J]. 材料工程, 2016, 44 (9): 115- 120. doi: 10.11868/j.issn.1001-4381.2016.09.018
9	JING S W , KANG M , SHAO Y . Crystallization process of heat-treated amorphous Ni-P alloy coating[J]. Journal of Materials Engineering, 2016, 44 (9): 115- 120. doi: 10.11868/j.issn.1001-4381.2016.09.018
10	CHOU M C , GER M D , KE S T , et al. The Ni-P-SiC composite produced by electro-codeposition[J]. Materials Chemistry and Physics, 2005, 92 (1): 146- 151. doi: 10.1016/j.matchemphys.2005.01.021
11	ZOIKIS K A , PAVLATOU E A , SPYRELLIS N . The effect of heat treatment on the structure and hardness of pulse electrodeposited Ni-P-WC composite coatings[J]. Electrochimica Acta, 2009, 54 (9): 2563- 2570. doi: 10.1016/j.electacta.2008.07.027
12	LEON O A , STAIA M H , HINTERMANN H E . Wear mechanism of Ni-P-BN(h) composite autocatalytic coatings[J]. Surface and Coatings Technology, 2005, 200 (5): 1825- 1829.
13	刘铁虎. Ni-P-Cr₂O₃化学复合镀层耐磨性的研究[J]. 润滑与密封, 2002, (6): 45- 46.
13	LIU T H . Study on wear resistance of Ni-P-Cr₂O₃composite electroless plating[J]. Lubrication Engineering, 2002, (6): 45- 46.
14	徐惠, 翟钧, 苟国俊, 等. 电沉积镍-磷-纳米金刚石纳米复合镀层性能研究[J]. 兰州理工大学学报, 2005, 31 (5): 64- 66.
14	XU H , ZHAI J , GOU G J , et al. Investigation of properties of electro deposited nickel-phosphorous nanometer diamond composite coatings[J]. Journal of Lanzhou University of Technology, 2005, 31 (5): 64- 66.
15	XUE Y J , LIU H B , LAN M M , et al. Effect of different electrodeposition methods on oxidation resistance of Ni-CeO₂ nanocomposite coating[J]. Surface and Coatings Technology, 2010, 204 (21): 3539- 3545.
16	崔宁, 侯文涛, 唐炳迎, 等. 脉冲镀非晶态镍磷合金[J]. 山东工业大学学报, 1994, 24 (1): 14- 20.
16	CUI N , HOU W T , TANG B Y , et al. Pulse plating amorphous nickel phosphorus alloy[J]. Journal of Shandong University of Technology, 1994, 24 (1): 14- 20.
17	SHEU H H , HUANG P C , TSAI L C , et al. Effects of plating parameters on the Ni-P-Al₂O₃ composite coatings prepared by pulse and direct current plating[J]. Surface and Coatings Technology, 2013, 235 (22): 529- 535.
18	李倍, 费敬银, 张闫, 等. Cr³⁺镀液的双向脉冲电沉积特性[J]. 航空材料学报, 2016, 36 (2): 33- 39. doi: 10.11868/j.issn.1005-5053.2016.2.006
18	LI B , FEI J Y , ZHANG Y , et al. Reverse pulsed electrodeposition of chromium coating from Cr³⁺ bath[J]. Journal of Aeronautical Materials, 2016, 36 (2): 33- 39. doi: 10.11868/j.issn.1005-5053.2016.2.006
19	PODLAHA E J , LANDOLT D . Pulse-reverse plating of nanocomposite thin films[J]. Journal of the Electrochemical Society, 1997, 144 (7): 200- 202. doi: 10.1149/1.1837799
20	张午花, 费敬银, 骆立立, 等. 脉冲电沉积高速Ni工艺研究[J]. 中国腐蚀与防护学报, 2013, 33 (4): 317- 324.
20	ZHANG W H , FEI J Y , LUO L L , et al. High speed pulse electro plating process of nickel[J]. Journal of Chinese Society for Corrosion and Protection, 2013, 33 (4): 317- 324.
21	CHEN F , PAN Y , LEE C , et al. Internal stress control of nickel-phosphorus electrodeposits using pulse currents[J]. Journal of the Electrochemical Society, 2010, 157 (3): 154- 158. doi: 10.1149/1.3285108
22	FEI J Y , WILCOX G D . Electrodeposition of Zn-Co alloys with pulse containing reverse current[J]. Electrochimica Acta, 2005, 50 (13): 2693- 2698. doi: 10.1016/j.electacta.2004.11.014
23	LIN C S , LEE C Y , CHEN F J , et al. Electrodeposition of nickel-phosphorus alloy from sulfamate baths with improved current efficiency[J]. Journal of the Electrochemical Society, 2006, 153 (6): 387- 392. doi: 10.1149/1.2186798
24	胡振峰, 吕镖, 汪笑鹤. 相对运动速度对电刷镀镍镀层组织结构和性能的影响[J]. 材料工程, 2014, (5): 12- 16. doi: 10.11868/j.issn.1001-4381.2014.05.003
24	HU Z F , LYU B , WANG X H . Effect of relative moving speed on microstructure and properties of brush electroplating nickel[J]. Journal of Materials Engineering, 2014, (5): 12- 16. doi: 10.11868/j.issn.1001-4381.2014.05.003
25	田海燕, 朱荻, 曲宁松, 等. 电泳-电沉积镍基纳米复合镀层Ni-Al₂O₃的耐蚀性能[J]. 腐蚀与防护, 2011, 32 (6): 426- 429.
25	TIAN H Y , ZHU D , QU N S , et al. Corrosion resistance of Ni-Al₂O₃nano-composite coatings prepared by electrophoretic-electrochemical deposition[J]. Corrosion & Protection, 2011, 32 (6): 426- 429.
26	ALIREZAEI S , MONIRVAGHEFI S M , SALEHI M , et al. Wear behavior of Ni-P and Ni-P-Al₂O₃ electroless coatings[J]. Wear, 2007, 262 (7/8): 978- 985.
27	BALARAJU J N , KALAVATI , RAJIAM K S . Electroless ternary Ni-W-P alloys containing micron size Al₂O₃ particles[J]. Surface & Coatings Technology, 2010, 205 (2): 575- 581.

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