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材料工程  2018, Vol. 46 Issue (11): 110-117    DOI: 10.11868/j.issn.1001-4381.2017.000893
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
电刷镀Ni-石墨烯复合镀层的组织结构及性能
丁小龙1,2, 胡振峰2, 金国1, 吕镖2, 汪笑鹤3
1. 哈尔滨工程大学 材料科学与化学工程学院, 哈尔滨 150001;
2. 陆军装甲兵学院 机械产品再制造国家工程研究中心, 北京 100072;
3. 中国华阴兵器试验中心, 陕西 华阴 714200
Microstructure and Properties of Electro-brush Plating Ni-graphene Composite Coating
DING Xiao-long1,2, HU Zhen-feng2, JIN Guo1, LYU Biao2, WANG Xiao-he3
1. School of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China;
2. National Engineering Research Center for Mechanical Product Remanufacturing, Academy of Armored Army Force, Beijing 100072, China;
3. Hua Yin Weapon Test Centre in China, Huayin 714200, Shaanxi, China
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摘要 利用电刷镀技术在45钢表面制备出Ni-石墨烯(Ni-GE)复合镀层。采用透射电镜(TEM)、原子力显微镜(AFM)、扫描电镜(SEM)、能谱仪(EDS)、Raman光谱仪、X射线衍射仪(XRD)对GE片层、复合镀层内部的GE、镀层的晶粒大小以及微观形貌进行表征,采用显微硬度计对镀层的硬度进行研究。结果表明:Ni-GE复合镀层中的石墨烯以3种形式(Ⅰ型、Ⅱ型、Ⅲ型)存在;相比于纯Ni镀层,Ni-GE复合镀层的晶粒尺寸均减小;当GE的添加量为0.5g/L时,Ni-GE复合镀层的质量最优;由于GE自身的高硬度及其细晶强化作用,Ni-石墨烯复合镀层的硬度相对于纯Ni镀层提高了15.2%。
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丁小龙
胡振峰
金国
吕镖
汪笑鹤
关键词 电刷镀石墨烯Ni-GE复合镀层硬度    
Abstract:Ni-graphene composite coating was prepared on 45 steel substrates by electro-brush plating. The graphene layers,graphene in the composite coatings,the grain size and morphology of the coatings were characterized by transmission electron microscope(TEM),atomic force microscope(AFM),scanning electron microscope(SEM),energy dispersive spectrometer(EDS),Raman spectrometer,X-ray diffraction(XRD). The hardness of coatings was investigated by microhardness tester. The results show that graphene in Ni-graphene composite coating exists in the form of three(type Ⅰ,type Ⅱ,type Ⅲ),compared with the pure Ni coating,the grain size of Ni-graphene composite coatings reduces; when the content of graphene is 0.5g/L,the quality of Ni-graphene composite coating is best; because of the high hardness of graphene and its fine-grain strengthening effect,the hardness of Ni-graphene composite coating is 15.2% higher than that of pure Ni coating.
Key wordselectro-brush plating    graphene    Ni-graphene composite coating    hardness
收稿日期: 2017-07-10      出版日期: 2018-11-19
中图分类号:  TQ153  
基金资助: 
通讯作者: 胡振峰(1976-),男,博士,助理研究员,主要从事电沉积理论及技术应用和装备再制造方面的研究工作,联系地址:北京市丰台区长辛店杜家坎21号院(1000072),E-mail:hu_zhenfeng@sina.com     E-mail: hu_zhenfeng@sina.com
引用本文:   
丁小龙, 胡振峰, 金国, 吕镖, 汪笑鹤. 电刷镀Ni-石墨烯复合镀层的组织结构及性能[J]. 材料工程, 2018, 46(11): 110-117.
DING Xiao-long, HU Zhen-feng, JIN Guo, LYU Biao, WANG Xiao-he. Microstructure and Properties of Electro-brush Plating Ni-graphene Composite Coating. Journal of Materials Engineering, 2018, 46(11): 110-117.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2017.000893      或      http://jme.biam.ac.cn/CN/Y2018/V46/I11/110
[1] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2] 贾瑛,许国根,王煊军.轻质碳材料的应用[M].北京:国防工业出版社,2013. JIA Y,XU G G,WANG X J.Application of lightweight carbon materials[M].Beijing:National Defense Industry Press,2013.
[3] 张丹丹,郭长虹,勾兴军,等.石墨烯增强金属基纳米复合材料的研究进展[J].燕山大学学报,2014,38(6):484-489. ZHANG D D,GUO C H,GOU X J,et al.Review of metal matrix nanocomposites reinforced by graphene[J].Journal of Yanshan University,2014,38(6):484-489.
[4] 凌自成,闫翠霞,史庆南,等.石墨烯增强金属基复合材料的制备方法研究进展[J].材料导报,2015,29(4):143-149. LING Z C,YAN C X,SHI Q N,et al.Recent progress in preparation methods for metal matrix composite materials reinforced with graphene nanosheets[J].Materials Review,2015,29(4):143-149.
[5] BAKSHI S R,LAHIRI D,AGARWAL A.Carbon nanotube reinforced metal matrix composites-a review[J].Int Mater Rev,2010,55(1):41-64.
[6] PAVITHRA C L P,SARADA B V,RAJULAPATI K V,et al.A new electrochemical approach for the synthesis of copper-graphene nanocomposite foils with high hardness[J].Sci Rep,2014,4:4049.
[7] 宾胜武.刷镀技术[M].北京:化学工业出版社,2003. BIN S W.Brush plating technology[M].Beijing:Chemical Industry Press,2003.
[8] 王柏春,朱永伟,许向阳,等.含纳米金刚石的复合镀研究[J].材料导报,2003,17(10):51-54. WANG B C,ZHU Y W,XU X Y,et al.Study on metal-ultrafine diamond composite co-deposition[J].Materials Review,2003,17(10):51-54.
[9] BALAKAI V I,MURZENKO K V,BYRYLOV I F,et al.Properties of nickel-cobalt-diamond composite coating deposited from a chloride electrolyte[J].Russian Journal of Applied Chemistry,2010,83(9):1581-1588.
[10] 曹伟,宋雪梅,王波,等.碳纳米管的研究进展[J].材料导报,2007,21(8):77-82. CAO W,SONG X M,WANG B,et al.Research progress in carbon nanotube[J].Materials Review,2007,21(8):77-82.
[11] CHEN X H,CHEN C S,XIAO H N,et al.Dry friction and wear characteristics of nickel/carbon nanotube electroless composite deposits[J].Tribology International,2006,39(1):22-28.
[12] ALISHAHI M,MONIRVAGHEFI S M,SAATCHI A,et al.The effect of carbon nanotubes on the corrosion and tribological behavior of electroless Ni-P-CNT composite coating[J].Applied Surface Science,2012,258(7):2439-2446.
[13] TAN J,YU T,XU B,et al.Microstructure and wear resistance of nickel-carbon nanotube composite coating from brush plating technique[J].Tribology Letters,2006,21(2):107-111.
[14] 杜宝中,高晓泽,唐建红,等.复合电镀(Ni-P)-石墨工艺及镀层性能的研究[J].电镀与精饰,2009,31(2):1-4. DU B Z,GAO X Z,TANG J H,et al.Electrodeposition technology and performance of(Ni-P)-graphite composite coatings[J].Plating & Finishing,2009,31(2):1-4.
[15] 艾薇,高志,潘红良,等.电刷镀Ni-石墨耐磨复合镀层研究[J].电镀与涂饰,2006,25(2):11-14. AI W,GAO Z,PAN H L,et al.Study on the anti-friction Ni-graphite composite deposit prepared by brush plating[J]. Electroplating & Finishing,2006,25(2):11-14.
[16] 杨勇辉,孙红娟,彭同江.石墨烯的氧化还原法制备及结构表征[J].无机化学学报,2010,26(11):2083-2090. YANG Y H,SUN H J,PENG T J.Synthesis and structural characterization of graphene by oxidation reduction[J].Chinese Journal of Inorganic Chemistry,2010,26(11):2083-2090.
[17] 吴娟霞,徐华,张锦.拉曼光谱在石墨烯结构表征中的应用[J].化学学报,2014,72(3):301-318. WU J X,XU H,ZHANG J.Raman spectroscopy of graphene[J].Acta Chimica Sinica,2014,72(3):301-318.
[18] LIAN J S,LI G Y,NIU L Y,et al.Electroless Ni-P deposition plus zinc phosphate coating on AZ91D magnesium alloy[J].Surface and Coatings Technology,2006,200(20):5956-5962.
[19] 陈天玉.镀镍合金[M].北京:化学工业出版社,2007. CHEN T Y.Nickel plated alloy[M].Beijing:Chemical Industry Press,2007.
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