Please wait a minute...
 
材料工程  2019, Vol. 47 Issue (2): 34-41    DOI: 10.11868/j.issn.1001-4381.2017.001447
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
立方相碳化钛在锂空电池中的电化学行为
秦振海, 黄昊, 吴爱民, 陈明珠, 杨影影, 姚曼
大连理工大学 材料科学与工程学院 三束材料改性教育部重点实验室, 辽宁 大连 116024
Electrochemical behavior of cubic titanium carbide for lithium-air batteries
QIN Zhen-hai, HUANG Hao, WU Ai-min, CHEN Ming-zhu, YANG Ying-ying, YAO Man
Key Laboratory of Materials Modification by Laser, Ion and Electron Beams(Ministry of Education), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China
全文: PDF(5604 KB)   HTML()
输出: BibTeX | EndNote (RIS)      
摘要 采用直流电弧等离子体法在甲烷和氩气混合气氛下原位合成碳化钛(TiC)纳米颗粒。X射线衍射、透射电子显微镜等物理表征结果显示TiC纳米颗粒粒径约为40~90 nm的立方体结构。循环伏安(CV)测试表明,TiC纳米颗粒兼具高效的氧还原和氧析出双效催化活性,可有效弥补炭材料氧析出催化活性较弱的缺陷。恒流充放电测试结果表明,相对于普通炭材料(导电炭黑,Super-P),TiC纳米颗粒催化剂可将锂空电池充电过电势降低280mV;在电流密度(isp)为50mA·g-1时,首次放电比容量达1267mAh·g-1;即使在较高的电流密度150mA·g-1下,比容量仍保持在778mAh·g-1,体现了良好的倍率性能。在电流密度为100mA·g-1、限定比容量为500mAh·g-1下,稳定循环10次。通过XRD、红外、扫描电镜表征可知,在TiC纳米颗粒的双效催化作用下,Li2O2的生成与分解具有良好的可逆性,有效避免了大量反应副产物积累的问题,进而提高锂空电池的电化学性能。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
秦振海
黄昊
吴爱民
陈明珠
杨影影
姚曼
关键词 锂空电池碳化钛纳米颗粒氧还原反应氧析出反应过电势    
Abstract:Titanium carbide(TiC)nanoparticles were synthesized in situ by direct current(DC)arc-discharge method under the mixture of methane and argon gas atmosphere. The physical characterization including X-ray diffraction(XRD)and transmission electron microscope(TEM)show that TiC nanoparticles have cubic structure with grain sizes of 40-90nm. Cyclic voltammetry(CV)measurement indicates that TiC nanoparticles are efficient bi-functional catalysts toward both oxygen reduction reaction(ORR)and oxygen evolution reaction (OER)for Li-O2 batteries, which can effectively compensate for the weak catalytic activity of OER of carbon materials. The results of galvanostatic charge-discharge measurement present that the TiC nanoparticles can reduce the charge-overpotential by 280mV compared to general carbon materials(Super-P), and the TiC electrode delivers an initial discharge capacity of 1267mAh·g-1 at 50mA·g-1. Even at a high current density of 150mA·g-1, the discharge capacity still maintains 778mAh·g-1, indicating excellent rate performance of lithium-air batteries with TiC nanoparticles as catalysts. The TiC electrode displays 10 cycles at a fixed capacity of 500mAh·g-1 and at a current density of 100mA·g-1.The characterization of XRD, Fourier transform infrared(FT-IR)and scanning electron microscopy(SEM)show that the formation and decomposition of Li2O2 have great reversibility under the bi-functional catalysis of TiC nanoparticles, which can significantly alleviate the accumulation of undesired byproducts, and eventually improve the electrochemical performance of Li-air batteries.
Key wordslithium-air battery    titanium carbide nanoparticle    oxygen reduction reaction    oxygen evolution reaction    overpotential
收稿日期: 2017-11-23      出版日期: 2019-02-21
中图分类号:  O646  
通讯作者: 黄昊(1974-),男,教授,博士,现从事纳米材料制备与表征、纳米结构控制、电极高密度储能等方面的研究,联系地址:辽宁省大连市甘井子区凌工路2号大连理工大学材料学院(116024),E-mail:huanghao@dlut.edu.cn     E-mail: huanghao@dlut.edu.cn
引用本文:   
秦振海, 黄昊, 吴爱民, 陈明珠, 杨影影, 姚曼. 立方相碳化钛在锂空电池中的电化学行为[J]. 材料工程, 2019, 47(2): 34-41.
QIN Zhen-hai, HUANG Hao, WU Ai-min, CHEN Ming-zhu, YANG Ying-ying, YAO Man. Electrochemical behavior of cubic titanium carbide for lithium-air batteries. Journal of Materials Engineering, 2019, 47(2): 34-41.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2017.001447      或      http://jme.biam.ac.cn/CN/Y2019/V47/I2/34
[1] 袁琦,邹正光,万振东,等. 锂离子电池正极材料铁掺杂V6O13的制备及电化学性能[J]. 材料工程, 2018, 46(1):106-113. YUAN Q, ZOU Z G, WAN Z D, et al. Synthesis and electrochemical properties of Fe-doped V6O13 as cathode material for lithium-ion battery[J]. Journal of Materials and Engineering, 2018, 46(1):106-113.
[2] BRUCE P G, FREUNBERGER S A, HARDWICK L J, et al. Li-O2 and Li-S batteries with high energy storage[J]. Nature Materials,2012, 11(1):19-29.
[3] 吴爱明,夏国锋,沈水云,等. 非水体系锂-空气电池研究进展[J]. 物理化学学报, 2016, 32(8):1866-1879. WU A M, XIA G F, SHEN S Y, et al.Recent progress in non-aqueous lithium-air batteries[J]. Acta Physico-Chimica Sinica,2016, 32(8):1866-1879.
[4] LEE J, TAI KIM S, CAO R, et al. Metal-air batteries:Metal-air batteries with high energy density:Li-air versus Zn-air[J]. Advanced Energy Materials, 2011, 1(1):34-50.
[5] GUO Z, ZHOU D, LIU H, et al. Synthesis of ruthenium oxide coated ordered mesoporous carbon nanofiber arrays as a catalyst for lithium oxygen battery[J]. Journal of Power Sources, 2015, 276:181-188.
[6] KIM B G, KIM H J, BACK S, et al. Improved reversibility in lithium-oxygen battery:understanding elementary reactions and surface charge engineering of metal alloy catalyst[J]. Scientific Reports, 2014, 4:4225.
[7] SUN B, MUNROE P, WANG G. Ruthenium nanocrystals as cathode catalysts for lithium-oxygen batteries with a superior performance[J]. Scientific Reports, 2013, 3:2247.
[8] CHEN M, JIANG X, YANG H, et al. Performance improvement of air electrode for Li/air batteries by hydrophobicity adjustment[J]. Journal of Materials Chemistry A, 2015, 3(22):11874-11879.
[9] 李鹏,孙彦平. 非水系二次锂-氧电池正极[J]. 化学进展, 2012, 24(12):2457-2471. LI P, SUN Y P. Positive electrodes of non-aqueous rechargeable lithium-oxygen batteries[J]. Progress in Chemistry, 2012, 24(12):2457-2471.
[10] LI Q, CAO R, CHO J, et al. Nanostructured carbon-based cathode catalysts for nonaqueous lithium-oxygen batteries[J]. Physical Chemistry Chemical Physics, 2014, 16(27):13568-13582.
[11] GUO Z, ZHOU D, DONG X, et al. Ordered hierarchical mesoporous/macroporous carbon:a high-performance catalyst for rechargeable Li-O2 batteries[J]. Advanced Materials, 2013, 25(39):5668-5672.
[12] DÉBART A, BAO J, ARMSTRONG G, et al. An O2 cathode for rechargeable lithium batteries:the effect of a catalyst[J]. Journal of Power Sources, 2007, 174(2):1177-1182.
[13] THOTIYL M, FREUNBERGER S A, PENG Z, et al. A stable cathode for the aprotic Li-O2 battery[J]. Nature Materials, 2013, 12(11):1050-1056.
[14] KIM J, LEE J, TAK Y. Relationship between carbon corrosion and positive electrode potential in a proton-exchange membrane fuel cell during start/stop operation[J]. Journal of Power Sources, 2009, 192(2):674-678.
[15] PENG Z, FREUNBERGER S A, CHEN Y,et al.A reversible and higher-rate Li-O2battery[J]. Science,2012, 337(6094):563-566.
[16] PARK I,KIM T,PARK H,et al.Preparation and electrochemical properties of Pt-Ru/Mn3O4/C bifunctional catalysts for lithium-air secondary battery[J].Journal of Nanoscience & Nanotechnology,2016,16(10):10453-10458.
[17] KONINCK M D, MARSAN B. MnxCuxCoO used as bifunctional electrocatalyst in alkaline medium[J]. Electrochimica Acta, 2008, 53(23):7012-7021.
[18] LI C, HAN X, CHENG F, et al. Phase and composition controllable synthesis of cobalt manganese spinel nanoparticles towards efficient oxygen electrocatalysis[J]. Nature Communications, 2015, 6:7345.
[19] QIU F, HE P, JIANG J, et al. Ordered mesoporous TiC-C composites as cathode materials for Li-O2 batteries[J]. Chemical Communications, 2016, 52(13):2713-2716.
[20] 甘小荣,薛方红,黄昊,等. SiC/C纳米复合材料的制备与性能表征[J].材料工程, 2014(2):75-80. GAN X R, XUE F H, HUANG H,et al. Preparation and characterization of SiC/C nano-composites[J]. Journal of Materials Engineering, 2014(2):75-80.
[21] 周远良,赛义德,张黎,等. 树脂基Fe纳米粒子及碳纤维复合吸波平板的制备与性能[J]. 材料工程, 2018,46(3):41-47. ZHOU Y L, SHAH S, ZHANG L, et al. Preparation and performance of resin-based Fe nanoparticals/carbon fibers microwave absorbing composite plates[J]. Journal of Materials Engineering, 2018,46(3):41-47.
[22] XU J, XU D, WANG Z, et al. Synthesis of perovskite-based porous La0.75Sr0.25MnO3 nanotubes as a highly efficient electrocatalyst for rechargeable lithium-oxygen batteries[J]. Angewandte Chemie, 2013, 52(14):3887-3890.
[23] CHEN J, HUMMELSHØJ J S, THYGESEN K S, et al. The role of transition metal interfaces on the electronic transport in lithium-air batteries[J]. Catalysis Today, 2011, 165(1):2-9.
[24] ZHANG T, IMANISHI N, SHIMONISHI Y, et al. A novel high energy density rechargeable lithium/air battery[J]. Chemical Communications, 2010, 46(10):1661-1663.
[25] KALUBARME R S, JADHAV H S, NGO D T, et al. Simple synthesis of highly catalytic carbon-free MnCo2O4@Ni as an oxygen electrode for rechargeable Li-O2 batteries with long-term stability[J]. Scientific Reports, 2015, 5:13266.
[26] PENG S, HU Y, LI L, et al. Controlled synthesis of porous spinel cobaltite core-shell microspheres as high-performance catalysts for rechargeable Li-O2 batteries[J]. Nano Energy, 2015, 13:718-726.
[27] WANG C, ZHAO Y, LIU J, et al. Highly hierarchical porous structures constructed from NiO nanosheets act as Li ion and O2 pathways in long cycle life, rechargeable Li-O2 batteries[J]. Chemical Communications, 2016, 52(79):11772-11774.
[28] DONG S, CHEN X, ZHANG K, et al. Molybdenum nitride based hybrid cathode for rechargeable lithium-O2 batteries[J]. Chemical Communications, 2011, 47(40):11291-11293.
[29] McCLOSKEY B D, BETHUNE D S, SHELBY R M, et al. Solvents' critical role in nonaqueous lithium-oxygen battery electrochemistry[J]. Journal of Physical Chemistry Letters, 2011, 2(10):1161-1166.
[30] McCLOSKEY B D, VALERY A, LUNTZ A C, et al. Combining accurate O2 and Li2O2 assays to separate discharge and charge stability limitations in nonaqueous Li-O2 batteries[J]. Journal of Physical Chemistry Letters, 2013, 4(17):2989-2993.
[31] THOTIYL M M O, FREUNBERGER S A, PENG Z, et al. The carbon electrode in nonaqueous Li-O2 cells[J]. Journal of the American Chemical Society, 2016, 135(1):494-500.
[32] SHUI J L, OKASINSKI J S, KENESEI P, et al. Reversibility of anodic lithium in rechargeable lithium-oxygen batteries[J]. Nature Communications, 2013, 4(4):2255.
[33] ASSARY R S, LU J, DU P, et al. The effect of oxygen crossover on the anode of a Li-O2 battery using an ether-solvent:insights from experimental and computational studies[J]. Chemsuschem, 2013, 6(1):51-55.
[34] SU D, DOU S, WANG G. Gold nanocrystals with variable index facets as highly effective cathode catalysts for lithium-oxygen batteries[J]. NPG Asia Materials, 2015, 7(1):e155.
[35] CAO R, LEE J, LIU M, et al. Non-precious catalysts:recent progress in non-precious catalysts for metal-air batteries[J]. Advanced Energy Materials, 2012, 2(7):816-829.
[36] LEE C K, PARK Y J. Polyimide-wrapped carbon nanotube electrodes for long cycle Li-air batteries[J]. Chemical Communications, 2015, 51(7):1210-1213.
[37] ZHANG S S, FOSTER D, READ J. Discharge characteristic of a non-aqueous electrolyte Li/O2 battery[J]. Journal of Power Sources, 2010, 195(4):1235-1240.
[38] BALAISH M, KRAYTSBERG A, EIN-ELI Y. A critical review on lithium-air battery electrolytes[J]. Physical Chemistry Chemical Physics, 2014, 16(7):2801-2822.
[39] CHEN Y, FREUNBERGER S A, PENG Z, et al. Charging a Li-O2 battery using a redox mediator[J]. Nature Chemistry, 2013, 5(6):489-494.
[40] ZHANG T, ZHOU H. A reversible long-life lithium-air battery in ambient air[J]. Nature Communications, 2013, 4(5):1817.
[1] 齐新, 王晨, 南文争, 洪起虎, 彭思侃, 燕绍九. 人造固态电解质界面在锂金属负极保护中的应用研究[J]. 材料工程, 2020, 48(6): 50-61.
[2] 王振威, 杨晓闪, 郑亚云, 张迎九, 徐洁. CuO/CuxSy八面体核壳结构的合成及其电化学性能[J]. 材料工程, 2020, 48(6): 98-105.
[3] 吴怡芳, 崇少坤, 柳永宁, 郭生武, 白利锋, 张翠萍, 李成山. 碳纳米材料构建高性能锂离子和锂硫电池研究进展[J]. 材料工程, 2020, 48(4): 25-35.
[4] 冯艳艳, 李彦杰, 杨文, 钟开应. 原位生长法制备花瓣状氢氧化钴及其电化学性能[J]. 材料工程, 2020, 48(3): 121-126.
[5] 陈玮, 孙晓刚, 胡浩, 王杰, 李旭, 梁国东, 黄雅盼, 魏成成. AC+Li(NiCoMn)O2/Li4Ti5O12+MWCNTs混合型电容器[J]. 材料工程, 2020, 48(1): 128-135.
[6] 齐新, 陈翔, 彭思侃, 王继贤, 王楠, 燕绍九. MXenes二维纳米材料及其在锂离子电池中的应用研究进展[J]. 材料工程, 2019, 47(12): 10-20.
[7] 田玉, 丁滔滔, 朱小龙, 郑广, 詹志明. NaV6O15纳米杆的制备及其电化学性能[J]. 材料工程, 2019, 47(10): 105-112.
[8] 李久勇, 刘伟明, 张晓锋, 马一博, 陈牧, 邱然锋, 颜悦. 高离子传导纳米多孔β-Li3PS4固态电解质的湿化学法制备[J]. 材料工程, 2019, 47(9): 101-107.
[9] 李嘉俊, 刘磊, 卢玉晓, 孙之剑, 马蕾. 纳米Li2MnSiO4正极材料的高压水热法制备及其电化学特性[J]. 材料工程, 2019, 47(9): 108-115.
[10] 蔡满园, 孙晓刚, 陈玮, 邱治文, 陈珑, 刘珍红, 聂艳艳. 以预锂化多壁碳纳米管为负极的锂离子电容器性能[J]. 材料工程, 2019, 47(5): 145-152.
[11] 王倩倩, 郑俊生, 裴冯来, 戴宁宁, 郑剑平. 质子交换膜燃料电池膜电极的结构优化[J]. 材料工程, 2019, 47(4): 1-14.
[12] 常增花, 王建涛, 李文进, 武兆辉, 卢世刚. 锂离子电池硅基负极界面反应的研究进展[J]. 材料工程, 2019, 47(2): 11-25.
[13] 李可峰, 尹晓燕. 聚苯醚纳米纤维锂电隔膜的制备[J]. 材料工程, 2018, 46(10): 120-126.
[14] 陈玮, 孙晓刚, 蔡满园, 聂艳艳, 邱治文, 陈珑. 碳纳米管/纤维素复合纸为电极的超级电容器性能[J]. 材料工程, 2018, 46(10): 113-119.
[15] 云亮, 刘峥, 李海莹, 王浩, 钟寒阳. 原位合成壳聚糖复合炭材料及其在铅碳电池中的应用[J]. 材料工程, 2018, 46(8): 57-63.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn