Abstract:The layered double hydroxides become research hot spot of oxygen evolution catalyzer for its easy preparation, feasible moderation of interlayer object,low cost and good stability but due to its low transmission speed of its electric charge,higher overpotential, so the modification is needed before mass application. The constructional character of the layered twinned material was firstly introduced, the catalytic mechanism of its oxygen evolution reaction was briefly described, then different kinds of optimization modification strategies to enhance its catalytic activity were introduced. The optimization modification strategies include:combination with conductive substrate, synthesis ultrathin nanometer plate, graphene compounding process, hybrid modification. The application of the stratified dihydride oxygen evolution catalyst in electrolysis of water to hydrogen and the advantages and disadvantages of different modification methods were put forward. The better-efficient oxygen evolution catalyst can be achieved through different kinds of modification. In the end, the difficulties in this kind of catalyzer were pointed out, including low recycle rate, catalyst stability, current density not meeting the requirements of industrialization and massive production.
[1] TURNER J A. Sustainable hydrogen production[J]. Science, 2004, 305(5686):972-974.
[2] ZENG K, ZHANG D. Recent progress in alkaline water electrolysis for hydrogen production and applications[J]. Progress in Energy and Combustion Science, 2010, 36(3):307-326.
[3] SUNTIVICH J, GASTEIGER H A, YABUUCHI N, et al. Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal-air batteries[J]. Nature Chemistry, 2011, 3(7):546-550.
[4] ARICO A S, SRINIVASAN S, ANTONUCCI V. DMFCs:from fundamental aspects to technology development[J]. Fuel Cells, 2015, 1(2):133-161.
[5] KIM M, KIM S, SONG D, et al. Promotion of electrochemical oxygen evolution reaction by chemical coupling of cobalt to molybdenum carbide[J]. Applied Catalysis, 2018, 227:340-348.
[6] FRYDENDAL R, PAOLI E A, KNUDSEN B P, et al. Benchmarking the stability of oxygen evolution reaction catalysts:the importance of monitoring mass losses[J]. Chemelectrochem, 2014, 1(12):2075-2081.
[7] CHEREVKO S, GEIGER S, KASIAN O, et al. Oxygen and hydrogen evolution reactions on Ru, RuO2, Ir, and IrO2 thin film electrodes in acidic and alkaline electrolytes:a comparative study on activity and stability[J].Catalysis Today,2016,262:170-180.
[8] ZHOU Q, CHEN Y, ZHAO G, et al. Active-site-enriched iron-doped nickel/cobalt hydroxide nanosheets for enhanced oxygen evolution reaction[J]. ACS Catalysis, 2018, 8(6):5382-5390.
[9] TAHIR M, PAN L, IDREES F, et al. Electrocatalytic oxygen evolution reaction for energy conversion and storage:a comprehensive review[J]. Nano Energy, 2017, 37:136-157.
[10] 李凯丹. CoO/CoSe2和单原子Au/Ni-Fe LDH异质催化剂的合成及电解水性能[D]. 天津:天津大学,2017. LI K D. Synthesis of CoO/CoSe2 and single-atom Au/Ni-Fe LDH heterogeneous catalysts for water electrolysis[D]. Tianjin:Tianjin University, 2017.
[11] 郭剑. 还原型氧化钛/水滑石复合材料的制备及其光电催化水氧化性能研究[D]. 北京:北京化工大学,2017. GUO J. Fabrication of reduced titania/layered double hydroxide hybrid materials towards photoeletrochemical water oxidation[D]. Beijing:Beijing University of Chemical Technology, 2017.
[12] 张丛. 水滑石基高效析氧电催化剂的制备及其性能研究[D]. 北京:北京化工大学,2017. ZHANG C. The design and synthesis of layered double hydroxides electrocatalysts toward enhanced oxygen evolution reaction[D]. Beijing:Beijing University of Chemical Technology, 2017.
[13] FAN G, LI F, EVANS D G, et al. Catalytic applications of layered double hydroxides:recent advances and perspectives[J]. Chemical Society Reviews, 2014, 43(20):7040-7066.
[14] YU J, WANG Q, O'HARE D, et al. Preparation of two dimensional layered double hydroxide nanosheets and their applications[J]. Chemical Society Reviews, 2017, 46(19):5950-5974.
[15] WANG L, HUANG X, JIANG S, et al. Increasing gas bubble escape rate for water splitting with nonwoven stainless steel fabrics[J]. ACS Applied Materials & Interfaces, 2017, 9(46):40281-40289.
[16] SEKHAR S C, NAGARAJU G, YU J S. Conductive silver nanowires-fenced carbon cloth fibers-supported layered double hydroxide nanosheets as a flexible and binder-free electrode for high-performance asymmetric supercapacitors[J]. Nano Energy, 2017, 36:58-67.
[17] CHEN N, LONG C, LI Y, et al. High-performance layered double hydroxide/poly(2,6-dimethyl-1,4-phenyleneoxide) membrane with porous sandwich structure for anion exchange membrane fuel cell applications[J]. Journal of Membrane Science, 2018, 552:51-60.
[18] WANG W, PAN H, SHI Y, et al. Fabrication of LDH nanosheets on beta-FeOOH rods and applications for improving the fire safety of epoxy resin[J]. Composites Part A, 2016, 80:259-69.
[19] SUEN N T, HUNG S F, QUAN Q, et al. Electrocatalysis for the oxygen evolution reaction:recent development and future perspectives[J].Chemical Society Reviews,2017,46(2):337-365.
[20] LI Z, NIU W, ZHOU L, et al. Phosphorus and aluminum co doped porous Nio nanosheets as highly efficient electrocatalysts for overall water splitting[J]. ACS Energy Letters, 2018, 3(4):892-898.
[21] TAEI M, HAVAKESHIAN E, HASHEMINASAB F. A gold nanodendrite-decorated layered double hydroxide as a bifunctional electrocatalyst for hydrogen and oxygen evolution reactions in alkaline media[J]. RSC Advances, 2017, 7(74):47049-47055.
[22] CHO S, JANG J W, PARK Y B, et al. An exceptionally facile method to produce layered double hydroxides on a conducting substrate and their application for solar water splitting without an external bias[J]. Energy & Environmental Science, 2014, 7(7):2301-2307.
[23] JIANG J, ZHANG A, LI L, et al. Nickel-cobalt layered double hydroxide nanosheets as high-performance electrocatalyst for oxygen evolution reaction[J]. Journal of Power Sources, 2015, 278:445-451.
[24] HUANG S, PENG H, TJIU W W, et al. Assembling exfoliated layered double hydroxide (LDH) nanosheet/carbon nanotube (CNT) hybrids via electrostatic force and fabricating nylon nanocomposites[J]. Journal of Physical Chemistry B, 2010, 114(50):16766-16772.
[25] YIN H, TANG Z. Ultrathin two-dimensional layered metal hydroxides:an emerging platform for advanced catalysis, energy conversion and storage[J]. Chemical Society Reviews, 2016, 45(18):4873-4891.
[26] YU L, YANG J F, GUAN B Y, et al. Hierarchical hollow nanoprisms based on ultrathin Ni-Fe layered double hydroxide nanosheets with enhanced electrocatalytic activity towards oxygen evolution[J]. Angewandte Chemie-International Edition, 2018, 57(1):172-176.
[27] XU X, ZHONG Z, YAN X, et al. Cobalt layered double hydroxide nanosheets synthesized in water-methanol solution as oxygen evolution electrocatalysts[J]. Journal of Materials Chemistry A, 2018, 6(14):5999-6006.
[28] ZHANG Y, SHAO Q, PI Y, et al. A cost-efficient bifunctional ultrathin nanosheets array for electrochemical overall water splitting[J]. Small, 2017, 13(27):1700355-1-1700355-7.
[29] SONG F, HU X. Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis[J]. Nature Communications, 2014, 5:4477-1-4477-9.
[30] LIU R, WANG Y, LIU D, et al. Water-plasma-enabled exfoliation of ultrathin layered double hydroxide nanosheets with multivacancies for water oxidation[J]. Advanced Materials, 2017, 29(30):1701546-1-1701546-7.
[31] WANG Y, ZHANG Y, LIU Z, et al. Layered double hydroxide nanosheets with multiple vacancies obtained by dry exfoliation as highly efficient oxygen evolution electrocatalysts[J]. Angewandte Chemie-International Edition,2017,56(21):5867-5871.
[32] XU H, WANG B, SHAN C, et al. Ce-doped nife-layered double hydroxide ultrathin nanosheets/nanocarbon hierarchical nanocomposite as an efficient oxygen evolution catalyst[J]. ACS Applied Materials & Interfaces, 2018, 10(7):6336-6345.
[33] LIU H, ZHOU J, WU C, et al. Integrated flexible electrode for oxygen evolution reaction:layered double hydroxide coupled with single-walled carbon nanotubes film[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(3):2911-2915.
[34] AHN S H, YU X, MANTHIRAM A. "Wiring" Fe-Nx-embedded porous carbon framework onto 1D nanotubes for efficient oxygen reduction reaction in alkaline and acidic media[J]. Advanced Materials, 2017, 29(26):1606534.
[35] 杨文彬,张丽,刘菁伟,等. 石墨烯复合材料的制备及应用研究进展[J]. 材料工程, 2015, 43(3):91-97. YANG W B, ZHANG L, LIU Q W, et al. Progress in research on preparation and application of graphene composites[J]. Journal of Materials Engineering, 2015, 43(3):91-97.
[36] 王楠,燕绍九,彭思侃,等. 3D打印石墨烯制备技术及其在储能领域的应用研究进展[J]. 材料工程, 2017, 45(12):112-125. WANG N, YAN S Q, PENG S K, et al. Research progress on 3D printed graphene materials synthesis technology and its application in energy storage field[J]. Journal of Materials Engineering, 2017, 45(12):112-125.
[37] QIN K, WANG L, WEN S, et al. Designed synthesis of NiCo-LDH and derived sulfide on heteroatom-doped edge-enriched 3D rivet graphene films for high-performance asymmetric supercapacitor and efficient OER[J]. Journal of Materials Chemistry A, 2018, 6(17):8109-8119.
[38] ISLAM M S, KIM M, JIN X, et al. Bifunctional 2D superlattice electrocatalysts of layered double hydroxide-transition metal dichalcogenide active for overall water splitting[J]. ACS Energy Letters, 2018, 3(4):952-960.
[39] ZHOU D, CAI Z, LEI X, et al. NiCoFe-layered double hydroxides/N-doped graphene oxide array colloid composite as an efficient bifunctional catalyst for oxygen electrocatalytic reactions[J]. Advanced Energy Materials, 2018, 8(9):1701905-1-1701905-7.
[40] ZHOU D, CAI Z, BI Y, et al. Effects of redox-active interlayer anions on the oxygen evolution reactivity of NiFe-layered double hydroxide nanosheets[J]. Nano Research, 2018, 11(3):1358-1368.
[41] PING J, WANG Y, LU Q, et al. Self-assembly of single-layer CoAl-layered double hydroxide nanosheets on 3D graphene network used as highly efficient electrocatalyst for oxygen evolution reaction[J]. Advanced Materials, 2016, 28(35):7640-7645.
[42] JIA Y, ZHANG L, GAO G, et al. A heterostructure coupling of exfoliated Ni-Fe hydroxide nanosheet and defective graphene as a bifunctional electrocatalyst for overall water splitting[J]. Advanced Materials, 2017, 29(17):1700017-1-1700017-8.
[43] LU F, ZHOU M, ZHOU Y, et al. First-row transition metal based catalysts for the oxygen evolution reaction under alkaline conditions:basic principles and recent advances[J]. Small, 2017, 13(45):1701931-1-1701931-18.
[44] DARBY M T, REOCREUX R, SYKES E C H, et al. Elucidating the stability and reactivity of surface intermediates on single-atom alloy catalysts[J]. ACS Catalysis, 2018, 8(6):5038-5050.
[45] ZHANG J, LIU J, XI L, et al. Single-atom Au/NiFe layered double hydroxide electrocatalyst:probing the origin of activity for oxygen evolution reaction[J]. Journal of the American Chemical Society, 2018, 140(11):3876-3879.
[46] CHEN J S, REN J, SHALOM M, et al. Stainless steel mesh-supported NiS nanosheet array as highly efficient catalyst for oxygen evolution reaction[J]. ACS Applied Materials & Interfaces, 2016, 8(8):5509-5516.
[47] ZHU W, YUE X, ZHANG W, et al. Nickel sulfide microsphere film on Ni foam as an efficient bifunctional electrocatalyst for overall water splitting[J]. Chemical Communications, 2015, 52(7):1486-1489.
[48] XIA C, JIANG Q, ZHAO C, et al. Selenide-based electrocatalysts and scaffolds for water oxidation applications[J]. Advanced Materials, 2016, 28(1):77-85.
[49] WANG Z, LI J, TIAN X, et al. Porous nickel-iron selenide nanosheets as highly efficient electrocatalysts for oxygen evolution reaction[J]. ACS Appl Mater Interfaces, 2016, 8(30):19386-19392.
[50] ZHU W, YUE Z, ZHANG W, et al. Wet-chemistry topotactic synthesis of bimetallic iron-nickel sulfide nanoarrays:an advanced and versatile catalyst for energy efficient overall water and urea electrolysis[J]. Journal of Materials Chemistry A, 2018, 6(10):4346-4353.
[51] QIU J, ZHANG X, FENG Y, et al. Modified metal-organic frameworks as photocatalysts[J]. Applied Catalysis B-Environmental, 2018, 231:317-342.
[52] WEI G, ZHOU Z, ZHAO X, et al. Ultrathin metal-organic framework nanosheets derived ultrathin Co3O4 nanomeshes with robust oxygen-evolving performance and asymmetric supercapacitors[J]. ACS Applied Materials & Interfaces, 2018, 10(28):23721-23730.
[53] CAI G, ZHANG W, JIAO L, et al. Template-directed growth of well-aligned MOF arrays and derived self-supporting electrodes for water splitting[J]. Chem, 2017, 2(6):791-802.
[54] TANG Y, FANG X, ZHANG X, et al. Space-confined earth-abundant bifunctional electrocatalyst for high-efficiency water splitting[J]. ACS Applied Materials & Interfaces, 2017, 9(42):36762-36771.
[55] KASHYAP V, KURUNGOT S. Zirconium-substituted cobalt ferrite nanoparticle supported N-doped reduced graphene oxide as an efficient bifunctional electrocatalyst for rechargeable Zn-air battery[J]. ACS Catalysis, 2018, 8(4):3715-3726.
[56] LI T, LU Y, ZHAO S, et al. Co3O4-doped Co/CoFe nanoparticles encapsulated in carbon shells as bifunctional electrocatalysts for rechargeable Zn-air batteries[J]. Journal of Materials Chemistry A, 2018, 6(8):3730-3737.