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材料工程  2019, Vol. 47 Issue (5): 43-52    DOI: 10.11868/j.issn.1001-4381.2018.000977
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
NiCrAl/YSZ/NiCrAl-B.e复合涂层对α+β型高温钛合金燃烧产物的影响
欧阳佩旋1,2, 弭光宝2,3, 李培杰1, 何良菊1, 曹京霞2, 黄旭2
1. 清华大学 新材料国际研发中心, 北京 100084;
2. 中国航发北京航空材料研究院 先进钛合金航空科技重点实验室, 北京 100095;
3. 北京市石墨烯及应用工程技术研究中心, 北京 100095
Effect of NiCrAl/YSZ/NiCrAl-B. e composite coating on combustion products of high-temperature α+β titanium alloys
OUYANG Pei-xuan1,2, MI Guang-bao2,3, LI Pei-jie1, HE Liang-ju1, CAO Jing-xia2, HUANG Xu2
1. National Center of Novel Materials for International Research, Tsinghua University, Beijing 100084, China;
2. Aviation Key Laboratory of Science and Technology on Advanced Titanium Alloys, AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China;
3. Beijing Engineering Research Center of Graphene and Application, Beijing 100095, China
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摘要 通过摩擦氧浓度方法点燃涂覆NiCrAl/YSZ/NiCrAl-B.e复合涂层的TC11钛合金,采用XRD,SEM,EDS及EPMA等微观表征方法对其燃烧产物进行分析,进而探讨复合涂层对燃烧行为的影响机理。结果表明:燃烧试样的基体从中心孔沿径向往外呈分区组织演变特征,中心孔处的钛合金基体是着火源;当燃烧程度较低时,YSZ中间层对钛合金燃烧行为的影响较小;当剧烈燃烧时,YSZ中间层通过分解反应而在钛合金熔体中大量溶解,为钛合金熔体提供了O和Zr,加速了Ti与O的快速结合,同时ZrTiO4燃烧产物的阻氧能力比TiO2差,从而大大促进了钛合金的扩展燃烧。
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欧阳佩旋
弭光宝
李培杰
何良菊
曹京霞
黄旭
关键词 高温钛合金NiCrAl/YSZ/NiCrAl-B.e复合涂层微观组织燃烧行为机理    
Abstract:NiCrAl/YSZ/NiCrAl-B. e composite coating on TC11 titanium alloy was combusted by friction in oxygen-enriched atmosphere. The combustion products were studied by XRD, SEM, EDS and EPMA. The effect of the composite coating on the combustion behavior of TC11 titanium alloy was discussed. The results show that there is regional microstructural evolution along radial direction in the substrate of the combusted specimen. The substrate near the central hole is the ignition source. When the combustion degree is low, the effect of the YSZ intermediate layer on the combustion behavior of titanium alloys can be ignored. However, when the combustion degree is high, the YSZ intermediate layer dissolves greatly in the titanium alloy melt through decomposition reaction, which provides O and Zr for the titanium alloy melt and accelerates the interaction between Ti and O. Furthermore, the ZrTiO4 combustion product has a worse ability to block oxygen diffusion than TiO2. As a result, NiCrAl/YSZ/NiCrAl-B. e composite coating, especially the YSZ layer, promotes the ext-ended combustion of TC11 titanium alloy.
Key wordshigh-temperature titanium alloy    NiCrAl/YSZ/NiCrAl-B. e composite coating    microstruc-ture    combustion behavior    mechanism
收稿日期: 2018-08-16      出版日期: 2019-05-17
中图分类号:  TG146.2  
通讯作者: 弭光宝(1981-),男,博士,高级工程师,主要从事先进高温钛合金及其纳米复合材料、阻燃性能等方面研究,联系地址:北京市81信箱15分箱(100095),E-mail:miguangbao@163.com     E-mail: miguangbao@163.com
引用本文:   
欧阳佩旋, 弭光宝, 李培杰, 何良菊, 曹京霞, 黄旭. NiCrAl/YSZ/NiCrAl-B.e复合涂层对α+β型高温钛合金燃烧产物的影响[J]. 材料工程, 2019, 47(5): 43-52.
OUYANG Pei-xuan, MI Guang-bao, LI Pei-jie, HE Liang-ju, CAO Jing-xia, HUANG Xu. Effect of NiCrAl/YSZ/NiCrAl-B. e composite coating on combustion products of high-temperature α+β titanium alloys. Journal of Materials Engineering, 2019, 47(5): 43-52.
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