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材料工程  2019, Vol. 47 Issue (4): 15-24    DOI: 10.11868/j.issn.1001-4381.2018.001164
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基于微波辐照合成类石墨烯氮化碳的研究进展
王继刚1,2, 余永志1,3, 邹婧叶1, 孟江1,2, 李淑萍2, 蒋南4
1. 东南大学 材料科学与工程学院 江苏省先进金属材料重点实验室, 南京 211189;
2. 西藏民族大学 西藏水污染控制与环境修复工程实验室, 陕西 咸阳 712082;
3. 景德镇陶瓷大学 国家日用及建筑陶瓷工程技术研究中心, 江西 景德镇 333001;
4. 南京医科大学 药学院, 南京 211166
Progress in microwave irradiation synthesis of graphene-like carbon nitride
WANG Ji-gang1,2, YU Yong-zhi1,3, ZOU Jing-ye1, MENG Jiang1,2, LI Shu-ping2, JIANG Nan4
1. Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China;
2. Xizang Engineering Laboratory for Water Pollution Control and Ecological Remediation, Xizang Minzu University, Xianyang 712082, Shaanxi, China;
3. National Engineering Research Center for Domestic & Building Ceramics, Jingdezhen Ceramic Institute, Jingdezhen 333001, Jiangxi, China;
4. School of Pharmacy, Nanjing Medical University, Nanjing 211166, China
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摘要 类石墨烯氮化碳具有与石墨烯非常相似的结构特征,已在光催化、润滑等领域表现出极优越的性能,成为二维纳米功能材料领域的新热点。本文重点介绍了基于微波辐照合成类石墨烯氮化碳的研究进展,并通过与氧化刻蚀、液相超声剥离、热聚合等传统合成方法的比较,分析了微波合成在制备效率、效果上的优势;并指出采用高功率微波设备和石墨粉、短切碳纤维等对微波具有强烈响应的微波吸收剂,通过增强能量传递与吸收效率,强化微波电磁场环境下合成反应的非稳态程度,有助于提高合成效率、效果,并获取得到特殊形态、结构的新产物。
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王继刚
余永志
邹婧叶
孟江
李淑萍
蒋南
关键词 微波合成类石墨烯氮化碳研究进展微波能    
Abstract:The synthesis of graphene-like carbon nitride has been a new research hotspot in the field of two-dimensional functional materials due to its similar structural characteristics to graphene and outstanding properties covering photocatalysis and lubrication and so on. Herein, the research progress of the microwave irradiation synthesis of graphene-like carbon nitride was discussed. Based on the comparison to the traditional preparation approaches including high-temperature oxidation corrosion, liquid phase ultrasonic exfoliation and thermal polymerization, etc., the advantages of microwave irradiation synthesis were analyzed. At the same time, one can find that by means of using high-energy microwave instrument and microwave absorbents covering graphite powders and short carbon fibers that possess excellent microwave energy absorption ability, the transferring and absorption efficient of energy as well as the non-steady degree of the synthesis reactions occurred in the microwave electromagnetic field can be enhanced, is consequently beneficial to the achievement of novel products with special morphology and structure.
Key wordsmicrowave synthesis    graphene-like carbon nitride    research progress    microwave energy
收稿日期: 2018-10-04      出版日期: 2019-04-19
中图分类号:  R318  
通讯作者: 王继刚(1973-),男,教授,博士生导师,博士,主要从事纳米功能陶瓷的微波合成及功能特性研究,联系地址:南京江宁区东南大学路2号东南大学九龙湖校区材料科学与工程学院(211189),E-mail:wangjigang@seu.edu.cn     E-mail: wangjigang@seu.edu.cn;jiangnan@njmu.edu.cn
引用本文:   
王继刚, 余永志, 邹婧叶, 孟江, 李淑萍, 蒋南. 基于微波辐照合成类石墨烯氮化碳的研究进展[J]. 材料工程, 2019, 47(4): 15-24.
WANG Ji-gang, YU Yong-zhi, ZOU Jing-ye, MENG Jiang, LI Shu-ping, JIANG Nan. Progress in microwave irradiation synthesis of graphene-like carbon nitride. Journal of Materials Engineering, 2019, 47(4): 15-24.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2018.001164      或      http://jme.biam.ac.cn/CN/Y2019/V47/I4/15
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