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材料工程  2020, Vol. 48 Issue (1): 136-143    DOI: 10.11868/j.issn.1001-4381.2018.001206
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
羟基磷灰石纳米棒的水热制备及其晶体生长机理研究
焦华, 赵康, 石蕊, 马利宁, 卞铁荣, 汤玉斐
西安理工大学, 西安 710048
Hydrothermal synthesis and crystal growth mechanism of hydroxyapatite nanorods
JIAO Hua, ZHAO Kang, SHI Rui, MA Li-ning, BIAN Tie-rong, TANG Yu-fei
Xi'an University of Technology, Xi'an 710048, China
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摘要 以无水CaCl2和(NH42HPO4为原料,尿素为均相沉淀剂,十六烷基三甲基溴化铵(CTAB)为模板剂,利用水热法制备了羟基磷灰石(HA)纳米棒。采用X射线衍射仪(XRD)、扫描电镜(SEM)和透射电镜(TEM)对产物的物相组成、微观形貌进行了表征。结果表明:通过改变反应温度和时间,可实现HA纳米形貌的可控微调。在120℃水热反应12 h可以制备出单晶密排六方结构HA纳米棒,其长约为0.5~1.0 μm,直径约为15~30 nm。并从晶体结构的角度详细研究了CTAB在合成纳米棒结构中所起的作用,并通过实验进行了验证。
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焦华
赵康
石蕊
马利宁
卞铁荣
汤玉斐
关键词 羟基磷灰石纳米棒水热法生长机理    
Abstract:Hydroxyapatite (HA) nanorods were synthesized by hydrothermal process using anhydrous CaCl2 and (NH4)2HPO4 as raw materials, urea was used as a homogeneous precipitation agent; hexadecyltrimethy ammonium bromide (CTAB) was used as a template agent. Phase composition and microstructure of the products were characterized via X-ray diffractometer (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM). The results show that the morphologies of HA nanorods can be controllably fine-tuning by changing the reaction temperature and time. Hexagonal single crystal HA nanorods single structure can be obtained at 120℃ for hydrothermal 12 h, its length is about 0.5-1.0 μm, diameter is about 15-30 nm. Finally, the role of CTAB was studied by the formation process of nanorods crystalline structure in details, and verified by experiment.
Key wordshydroxyapatite    nanorod    hydrothermal method    growth mechanism
收稿日期: 2018-10-15      出版日期: 2020-01-09
中图分类号:  O611  
基金资助: 
通讯作者: 赵康(1963-),男,教授,博士,博士生导师,主要从事生物材料的研究与制备等方面的研究工作,联系地址:陕西省西安市金花南路5号西安理工大学(710048),E-mail:kzhao@xaut.edu.cn     E-mail: kzhao@xaut.edu.cn
引用本文:   
焦华, 赵康, 石蕊, 马利宁, 卞铁荣, 汤玉斐. 羟基磷灰石纳米棒的水热制备及其晶体生长机理研究[J]. 材料工程, 2020, 48(1): 136-143.
JIAO Hua, ZHAO Kang, SHI Rui, MA Li-ning, BIAN Tie-rong, TANG Yu-fei. Hydrothermal synthesis and crystal growth mechanism of hydroxyapatite nanorods. Journal of Materials Engineering, 2020, 48(1): 136-143.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2018.001206      或      http://jme.biam.ac.cn/CN/Y2020/V48/I1/136
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