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材料工程  2020, Vol. 48 Issue (10): 148-156    DOI: 10.11868/j.issn.1001-4381.2018.001211
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
硅酸钙及硅酸钠浓度对钛合金表面生物活性涂层的影响
何代华1, 朱威1,2, 刘翔2, 刘平1
1. 上海理工大学 材料科学与工程学院, 上海 200093;
2. 上海微创医疗器械(集团)有限公司, 上海 201210
Effects of calcium silicate and sodium silicate concentrations on bioactive coating on titanium alloy
HE Dai-hua1, ZHU Wei1,2, LIU Xiang2, LIU Ping1
1. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China;
2. Shanghai MicroPort Medical(Group) Co., Ltd., Shanghai 201210, China
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摘要 使用微弧氧化技术,在恒压工作模式下,脉冲电压400 V,脉冲频率600 Hz,占空比15%,氧化时间10 min,电解液由CaSiO3,Na2SiO3·9H2O,EDTA-2Na和K2HPO4·3H2O组成,以不同浓度(0.0835~0.15 mol/L)的CaSiO3及不同浓度(0~0.06 mol/L)的Na2SiO3·9H2O,在3D打印基体钛片表面制备生物活性涂层。利用扫描电子显微镜、能谱仪、电化学工作站、涡流膜厚仪、Image-Pro Plus 6.0、轮廓仪、划痕仪等对涂层进行结构、性能及微观形貌表征,研究CaSiO3和Na2SiO3·9H2O浓度对涂层的影响。结果表明:随着CaSiO3浓度的增加,涂层厚度、粗糙度、微孔孔径及孔隙率、涂层钙磷元素比逐渐增大,耐腐蚀性能及膜基结合力变差;随着Na2SiO3·9H2O浓度的增加,涂层孔隙率及孔径先增大后减小,涂层厚度、粗糙度、涂层钙磷元素比逐渐增大,膜基结合效果和耐腐蚀性先变差后变好。当CaSiO3和Na2SiO3·9H2O的浓度分别为0.15 mol/L和0.015 mol/L时,涂层的性能最佳。
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何代华
朱威
刘翔
刘平
关键词 3D打印钛合金微弧氧化硅酸钙硅酸钠生物活性涂层    
Abstract:The bioactive coatings were prepared on the surface of Ti6Al4V by micro-arc oxidation in the electrolyte system consist of CaSiO3, Na2SiO3·9H2O, EDTA-2Na, K2HPO4·3H2O and the electrical parameters were fixed at 400 V, 600 Hz, 15%, 10 min with constant voltage mode. The value of concentration of CaSiO3 and Na2SiO3·9H2O were changed, and the range of change was 0.0835-0.15 mol/L and 0-0.06 mol/L respectively. Structural properties and microstructure of bioactive coating fabricated by micro-arc oxidation were detected by scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), electrochemical workstation, eddy current thickness profiler, scratch tester and Image-Pro Plus 6.0. The effects of CaSiO3 and Na2SiO3·9H2O concentrations on the bioactive coating were studied. The results show that thickness, roughness, micropore diameter and porosity, calcium phosphate ratio gradually increase and corrosion resistance, bond strength gradually deteriorate with the increase of CaSiO3 concentration. Micropore diameter and porosity first grow larger and then become smaller, thickness,roughness,calcium phosphate ratio and bond strength gradually increase and corrosion resistance becomes better first and then deteriorates with the increase of Na2SiO3·9H2O concentration. The performance of the coating is the best when the concentrations of calcium silicate and sodium silicate are 0.15 mol/L and 0.015 mol/L, respectively.
Key words3D printed titanium alloy    micro-arc oxidation    calcium silicate    sodium silicate    bioactive coating
收稿日期: 2018-10-16      出版日期: 2020-10-17
中图分类号:  TG174.451  
通讯作者: 何代华(1975-),女,副教授,博士后,研究方向:异种材料界面工程,联系地址:上海理工大学材料科学与工程学院(200093),E-mail:hedh21@163.com     E-mail: hedh21@163.com
引用本文:   
何代华, 朱威, 刘翔, 刘平. 硅酸钙及硅酸钠浓度对钛合金表面生物活性涂层的影响[J]. 材料工程, 2020, 48(10): 148-156.
HE Dai-hua, ZHU Wei, LIU Xiang, LIU Ping. Effects of calcium silicate and sodium silicate concentrations on bioactive coating on titanium alloy. Journal of Materials Engineering, 2020, 48(10): 148-156.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2018.001211      或      http://jme.biam.ac.cn/CN/Y2020/V48/I10/148
[1] WANG Y,YU H,CHEN C,et al.Review of the biocompatibility of micro-arc oxidation coated titanium alloys[J].Materials & Design,2015,85:640-652.
[2] GEETHA M,SINGH A K,ASOKA M R,et al.Ti based biomaterials, the ultimate choice for orthopaedic implants-a review[J].Progress in Materials Science,2009,54(3):397-425.
[3] NⅡNOMI M.Biologically and mechanically biocompatible titanium alloys[J].Materials Transactions,2008,49(10):2170-2178.
[4] KARBOWNICZEK J,MUHAFFEL F,CEMPURA G,et al.Influence of electrolyte composition on microstructure, adhesion and bioactivity of micro-arc oxidation coatings produced on biomedical Ti6Al7Nb alloy[J].Surface & Coatings Technology,2017,321:97-107.
[5] KIESWETTER K,SCHWARTZ Z,HΜMMERT T W,et al.Surface roughness modulates the local production of growth factors and cytokines by osteoblast-like MG-63 cells[J].Journal of Biomedical Materials Research,1996,32(1):55-63.
[6] SIMCHI A,TAMJID E,PISHBIN F,et al.Recent progress in inorganic and composite coatings with bactericidal capability for orthopaedic applications[J].Nanomedicine Nanotechnology Biology & Medicine,2011,7(1):22-39.
[7] McGILLIVRAY K,EASLEY J,SEIM H B,et al.Bony ingrowth potential of 3D printed porous titanium alloy:a direct comparison of interbody cage materials in an in vivo ovine lumbar fusion mo-del[J].Spine Journal,2018,18(7):1250-1260.
[8] RAN Q,YANG W,HU Y,et al.Osteogenesis of 3D printed po-rous Ti6Al4V implants with different pore sizes[J].Journal of the Mechanical Behavior of Biomedical Materials,2018,84:1-11.
[9] OSHIDA Y,REYES M J.Titanium-porcelain system.part Ⅳ:some mechanistic considerations on porcelain bond strengths[J].Bio-medical Materials and Engineering,2001,11(2):137-142.
[10] REYES M J,OSHIDA Y,ANDRES C J,et al.Titanium-porcelain system.part Ⅲ:effects of surface modification on bond strengths[J]. Bio-medical Materials and Engineering,2001,11(2):117-136.
[11] CURTIS J G,DOSSETT J,PRIHODA T J,et al.Effect of bonding agent application method on titanium-ceramic bond strength[J].Journal of Prosthodontics,2015,24(5):394-400.
[12] CHAKMAKCHI M,ELIADES G,ZINELIS S,et al.Bonding agents of low fusing cpTi porcelains:elemental and morphological characterization[J].Journal of Prosthodontic Research,2009,53(4):166-171.
[13] XU L,WU C,LEI X,et al.Effect of oxidation time on cytocompatibility of ultrafine-grained pure Ti in micro-arc oxidation treatment[J].Surface & Coatings Technology,2018,342:12-22.
[14] ZHOU R,WEI D,FENG W,et al.Bioactive coating with hierarchical double porous structure on titanium surface formed by two-step micro-arc oxidation treatment[J].Surface & Coatings Technology,2014,252(9):148-156.
[15] ZHOU R,WEI D,YANG H,et al.MC3T3-E1 cell response of amorphous phase/TiO2 nanocrystal composite coating prepared by microarc oxidation on titanium[J].Materials Science and Engineering:C,2014,39:186-195.
[16] CIMENOGLU H,GUNYUZ M,KOSE G T,et al.Micro-arc oxidation of Ti6Al4V and Ti6Al7Nb alloys for biomedical applications[J].Materials Characterization,2011,62(3):304-311.
[17] HAN Y,SUN J,HUANG X.Formation mechanism of HA-based coatings by micro-arc oxidation[J].Electrochemistry Communications,2008,10(4):510-513.
[18] SUN J,HAN Y,HUANG X.Hydroxyapatite coatings prepared by micro-arc oxidation in Ca- and P-containing electrolyte[J].Surface & Coatings Technology,2007,201(9):5655-5658.
[19] KIM M S,RYU J,SUNG Y M.One-step approach for nano-crystalline hydroxyapatite coating on titanium via micro-arc oxidation[J].Electrochemistry Communications,2007,9(8):1886-1891.
[20] CAMPANELLI L C,DUARTE L T,BOLFARINI C.Fatigue behavior of modified surface of Ti-6Al-7Nb and CP-Ti by micro-arc oxidation[J].Materials & Design,2014,64(9):393-399.
[21] 李兴照.医用钛合金表面微弧氧化膜层制备工艺及性能的研究[D].长春:长春工业大学,2016. LI X Z.Study on preparation process and properties of micro-arc oxidation film on medical titanium alloy[D].Changchun:Changchun University of Technology,2016.
[22] 赵晖,朱其柱,金光,等.硅酸钠对TC4钛合金微弧氧化电极参数及陶瓷膜的影响[J].材料保护,2011,44(2):14-16. ZHAO H,ZHU Q Z,JIN G,et al.Effect of sodium silicate on micro-arc oxidation electrode parameters and ceramic membrane of TC4 titanium alloy[J].Materials Protection,2011,44(2):14-16.
[23] 史兴岭,王庆良.络合剂对Ti6A14V合金微弧氧化膜性能的影响[C]//2008全国青年摩擦学与表面保护学术会议.武汉:中国机械工程学会,2008:74-77. SHI X L, WANG Q L.Effect of complexing agent on properties of micro-arc oxidation film of Ti6A14V alloy[C]//2008 National Youth Tribology and Surface Protection Conference.Wuhan:Chinese Mechanical Engineering Society,2008:74-77.
[24] 寇斌达.微弧氧化制备钛表面磷钙生物活性涂层[D].北京:北京工业大学,2003. KOU B D.Preparation of phosphorus-calcium bioactive coating on titanium surface by micro-arc oxidation[D].Beijing:Beijing University of Technology,2003.
[25] 江楠,王智,王林龙,等.硫酸盐对聚羧酸减水剂分散性及吸附量的影响[J].硅酸盐学报,2013(11):1521-1526. JIANG N,WANG Z,WANG L L,et al.Effect of sulfate on dispersibility and adsorption of polycarboxylate water reducer[J].Journal of the Chinese Ceramic Society,2013(11):1521-1526.
[26] 王亚明,邹永纯,王树棋,等.金属微弧氧化功能陶瓷涂层设计制备与使役性能研究进展[J].中国表面工程,2018,31(4):20-45. WANG Y M,ZOU Y C,WANG S Q,et al.Design,fabrication and performance of multifunctional ceramic coatings formed by microarc oxidation on metals[J].China Surface Engineering,2018,31(4):20-45.
[27] TANG Y,ZHAO X,JIANG K,et al.The influences of duty cycle on the bonding strength of AZ31B magnesium alloy by microarc oxidation treatment[J].Surface & Coatings Technology,2010,205(6):1789-1792.
[28] HAN J,CHENG Y,TU W,et al.The black and white coatings on Ti-6Al-4V alloy or pure titanium by plasma electrolytic oxidation in concentrated silicate electrolyte[J].Applied Surface Science,2018,428:684-697.
[29] WANG C,WANG F,HAN Y,et al.The structure, bond strength and apatite-inducing ability of micro-arc oxidized tantalum and their response to annealing[J].Applied Surface Science,2016,361:190-198.
[30] 李思锐.硅酸钠添加量对微弧氧化膜层特性影响研究[J].信息记录材料,2017,18(5):30-31. LI S R.Effect of the addition of sodium silicate on the characte-ristics of micro-arc oxidation film[J].Journal of Information Recording Materials,2017,18(5):30-31.
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