Abstract：The research progress of superhydrophobic surface on metal substrates was reviewed. The main preparation methods of metal-based superhydrophobic surface were discussed, and the advantages and disadvantages of different preparation method were compared. At the same time, the functional properties of metal-based superhydrophobic surface were discussed, and the main problems in preparation and application of metal-based superhydrophobic surfaces were analyzed. It was pointed out that the future development direction of metal-based superhydrophobic surface is to simplify the preparation process, reduce costs, improve the durability and stability of superhydrophobic surface, and prepare metal superhydrophobic surface with self-healing properties.
张志斌, 尉小凤, 王海涛, 史雪婷, 冯利邦. 金属基超疏水表面的制备及性能研究进展[J]. 材料工程, 2019, 47(5): 26-33.
ZHANG Zhi-bin, YU Xiao-feng, WANG Hai-tao, SHI Xue-ting, FENG Li-bang. Research progress in preparation and properties of superhydrophobic surface on metal substrates. Journal of Materials Engineering, 2019, 47(5): 26-33.
[1] DRUMMOND C, ISRAELACHVILI J. Surface forces and wett-ability[J]. Journal of Petroleum Science and Engineering, 2002, 33(1/3):123-133.
[2] 江雷. 从自然到仿生的超疏水纳米界面材料[J].化工进展,2003, 22(12):1258-1264. JIANG L. Nanostructured materials with superhydrophobic sur-face-from nature to biomimesis[J]. Chemical Industry and Engin-eering Progress, 2003, 22(12):1258-1264.
[3] 高雪峰,江雷. 天然超疏水生物表面研究的新进展[J]. 物理, 2006, 35(7):559-564. GAO X F, JIANG L. Recent studies of natural superhydrophobic bio-surfaces[J]. Physics, 2006, 35(7):559-564.
[4] ZHANG X, SHI F, NIU J, et al. Superhydrophobic surfaces:from structural control to functional application[J]. Journal of Materials Chemistry, 2008, 18(6):621-633.
[5] LIU K S, XI Y, JIANG L. Recent developments in bio-inspired special wettability[J]. Chemical Society Reviews, 2010, 39(8):3240-3255.
[6] 连峰,王增勇,张会臣. 疏水/超疏水船用铝合金表面制备及其耐久性[J]. 材料工程, 2015, 43(1):49-53. LIAN F, WANG Z Y, ZHANG H C. Preparation of hydrophob-ic/superhydrophobic warship aluminium alloy surface and its dur-ability[J]. Journal of Materials Engineering, 2015, 43(1):49-53.
[7] 强小虎,张红霞,王彦平,等. 强黏附性超疏水氧化铝的表面结构和黏附机理[J]. 材料工程, 2013(3):55-60. QIANG X H, ZHANG H X, WANG Y P, et al. Structure and adhesive mechanism of superhydrophobic alumina surface with high adhesive force[J]. Journal of Materials Engineering, 2013(3):55-60.
[8] BARTHLOTT W, NEINHUIS C. Purity of the sacred lotus, or escape from contamination in biological surfaces[J]. Planta, 1997, 202(1):1-8.
[9] 李自力,杨燕. 金属材料交流腐蚀机理、影响因素及风险评价[J]. 化工学报, 2011, 62(7):1790-1799. LI Z L, YANG Y. Mechanism, influence factors and risk evalu-ation of metal alternating current corrosion[J]. CIESC Journal, 2011, 62(7):1790-1799.
[10] CHEN Y H. Corrosion resistance of glass coating on metal surface with thermal deposition method[J]. Journal of the Univ-ersity of Petroleum China, 2003, 27(5):81-83.
[11] JIN H Y, LI Z W, WEI S C, et al. Corrosion resistance and dynamic anti-icing of superhydrophobic surface on ASW[J]. Surface Engineering, 2018, 34(8):603-610.
[12] ZANG D M, ZHU R W, ZHANG W, et al. Corrosion-resistant superhydrophobic coatings on Mg alloy surfaces inspired by lotus seedpod[J]. Advanced Functional Materials, 2017, 27(8):1-7.
[13] GAO X Y, GUO Z G. Mechanical stability, corrosion resistance of superhydrophobic steel and repairable durability of its slippery surface[J]. Journal of Colloid and Interface Science, 2018, 512:239-248.
[14] JIANG D, ZHOU H, WAN S, et al. Fabrication of superhy-drophobic coating on magnesium alloy with improved corrosion resistance by combining micro-arc oxidation and cyclic assembly[J]. Surface and Coatings Technology, 2018, 339:155-166.
[15] ISHIZAKI T,MASUDA Y,SAKAMOTO M. Corrosion resist-ance and durability of superhydrophobic surface formed on magnesium alloy coated with nanostructured cerium oxide film and fluoroalkylsilane molecules in corrosive NaCl aqueous solu-tion[J]. Langmuir:the ACS Journal of Surfaces and Colloids, 2011, 27(8):4780-4788.
[16] WANG N, XIONG D S, DENG Y L, et al. Mechanically robust superhydrophobic steel surface with anti-icing, UV-durability, and corrosion resistance properties[J]. ACS Applied Materials & Interfaces, 2015, 7(11):6260-6272.
[17] FENG L B, CHE Y H, LIU Y H, et al. One-step immersion method for fabricating superhydrophobic aluminum alloy with excellent corrosion resistance[J]. Surface and Interface Anal-ysis, 2016, 48(12):1320-1327.
[18] WAN S, CONG Y, JIANG D, et al. Weathering barrier enh-ancement of printed circuit board by fluorinated silica based superhydrophobic coating[J]. Colloids and Surfaces A:Physico-chemical and Engineering Aspects, 2018, 538:628-638.
[19] WANG Y, LIU X W, ZHANG H F, et al. Superhydrophobic surfaces created by a one-step solution-immersion process and their drag-reduction effect on water[J]. RSC Advances, 2015, 5(24):18909-18914.
[20] 杨钦,罗荘竹,谭生,等. 超疏水自清洁涂层防结冰技术的研究进展[J]. 中国表面工程, 2016, 29(4):10-22. YANG Q, LUO Z Z, TAN S, et al. Research progress in anti-icing technology of superhydrophobic self-cleaning coating[J]. China Surface Engineering, 2016, 29(4):10-22.
[21] 刘新,赵清含. 超疏水自清洁涂料制备及应用研究[J]. 无线互联科技, 2018(6):108-112. LIU X, ZHAO Q H. Study on the preparation and application of superhydrophobic self-cleaning coating[J]. Wireless Internet Technology, 2018(6):108-112.
[22] 张艳平,董兵海,王世敏,等. 耐久性超疏水表面的构建及其研究进展[J]. 功能材料, 2017, 48(6):6057-6063. ZHANG Y P, DONG B H, WANG S M, et al. Construction of durable superhydrophobic surface and its research progress[J]. Journal of Functional Materials, 2017, 48(6):6057-6063.
[23] 徐文骥,宋金龙,孙晶,等. 金属基体超疏水表面制备及应用的研究进展[J]. 材料工程, 2011(5):93-98. XU W J, SONG J L, SUN J, et al. Progress in fabrication and application of superhydrophobic surfaces on metal substrates[J]. Journal of Materials Engineering, 2011(5):93-98.
[24] JEEVAHAN J, CHANDRASEKARAN M, JOSEPH G B, et al. Superhydrophobic surfaces:a review on fundamentals, appl-ications and challenges[J]. Journal of Coatings Technology and Research, 2018, 15(2):231-250.
[25] WEN G, GUO Z G, LIU W M. Biomimetic polymeric superh-ydrophobic surfaces and nanostructures:from fabrication to app-lications[J]. Nanoscale, 2017, 9(10):3338-3366.
[26] FENG L B, ZHANG H X, WANG Z L, et al. Superhydrop-hobic aluminum alloy surface:fabrication, structure, and corro-sion resistance[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2014, 441:319-325.
[27] KIM J H, MIRZAEI A, KIM H W, et al. Facile fabrication of superhydrophobic surfaces from austenitic stainless steel (AISI 304) by chemical etching[J]. Applied Surface Science, 2018, 439:598-604.
[28] FENG L B, YAN Z N, SHI X T, et al. Anti-icing/frosting and self-cleaning performance of superhydrophobic aluminum alloys[J]. Applied Physics A, 2018, 124(2):142-156.
[29] FENG L B, ZHU Y L, FAN W B, et al. Fabrication and corr-osion resistance of superhydrophobic magnesium alloy[J]. App-lied Physics A, 2015, 120(2):561-570.
[30] FENG L B, CHE Y H, LIU Y H, et al. Fabrication of super-hydrophobic aluminium alloy surface with excellent corrosion re-sistance by a facile and environment-friendly method[J]. Applied Surface Science, 2013, 283:367-374.
[31] LI X W, ZHANG Q X, GUO Z, et al. Low-cost and large-scale fabrication of a superhydrophobic 5052 aluminum alloy surface with enhanced corrosion resistance[J]. RSC Advances, 2015, 5(38):29639-29646.
[32] LIU W, XU Q J, HAN J, et al. A novel combination approach for the preparation of superhydrophobic surface on copper and the consequent corrosion resistance[J]. Corrosion Science,2016, 110:105-113.
[33] 李晶,赵世才,杜锋,等. 激光构筑槽棱与网格状结构超疏水耐腐蚀表面研究[J]. 材料工程, 2018, 46(5):86-91. LI J, ZHAO S C, DU F, et al. Fabrication of groove and grid structure surface with superhydrophobicity and corrosion resis-tance by laser[J]. Journal of Materials Engineering, 2018, 46(5):86-91.
[34] 任杰,廖瑞瑞,杨武,等.辉光放电电解等离子体处理制备铁基表面超疏水材料[J]. 应用化学, 2013, 30(2):208-213. REN J, LIAO R R, YANG W, et al. Fabrication of superh-ydrophobic iron-surface by using glow discharge electrolysis plas-ma[J]. Chinese Journal of Applied Chemistry, 2013, 30(2):208-213.
[35] GUSTAFSSON L, JANSSON R, HEDHAMMAR M, et al. Structuring of functional spider silk wires, coatings, and sheets by self-assembly on superhydrophobic pillar surfaces[J]. Adva-nced Materials, 2017, 30(3):1-8.
[36] PANNEERSELVAM V, MANICKAM ANBU K. Hierarchic-ally ordered self-lubricating superhydrophobic anodized alumi-num surfaces with enhanced corrosion resistance[J]. ACS Appl-ied Materials & Interfaces, 2015, 7(3):1516-1526.
[37] FENG L B, ZHAO L B, QIANG X H, et al. Fabrication of superhydrophobic copper surface with excellent corrosion resis-tance[J]. Applied Physics A, 2015, 119(1):75-83.
[38] 罗晓民,魏梦媛,曹敏. 耐腐蚀超疏水铜网的制备及其在油水分离中的应用[J]. 材料工程, 2018, 46(5):92-98. LUO X M, WEI M Y, CAO M. Preparation of superhydro-phobic Cu mesh with corrosion resistance and applications in oil-water separation[J]. Journal of Materials Engineering, 2018, 46(5):92-98.
[39] ZHOU X, YU S R, GUAN S W, et al. Fabrication and charact-erization of superhydrophobic TiO2 nanotube coating by a facile anodic oxidation approach[J]. Surface and Coatings Techn-ology, 2018, 354:83-91.
[40] HÖHNE S, BLANK C, MENSCH A, et al. Superhydrophobic alumina surfaces based on polymer-stabilized oxide layers[J]. Macromolecular Chemistry and Physics, 2009, 210(16):1263-1271.
[41] LIU C S, SU F H, LIANG J Z. Facile fabrication of a robust and corrosion resistant superhydrophobic aluminum alloy surface by a novel method[J]. RSC Advances, 2014, 4(98):556-564.
[42] 王晨玥,杨文秀,张洪敏,等. 纯钛基体长效超疏水表面的低成本制备[J]. 材料工程, 2015, 43(11):13-18. WANG C Y, YANG W X, ZHANG H M,et al. Preparation of durable superhydrophobic surface on pure titanium substrate via low-cost route[J]. Journal of Materials Engineering, 2015, 43(11):13-18.
[43] 郑顺丽,李澄,项腾飞,等. 阳极氧化法制备铝基超疏水涂层及其稳定性和耐蚀性的研究[J]. 材料工程, 2017, 45(10):71-78. ZHENG S L, LI C, XIANG T F, et al. Fabrication of alumin-um-based superhydrophobic coating by anodization and research on stability and corrosion resistance[J]. Journal of Materials Engineering, 2017, 45(10):71-78.
[44] LIU Y, LIU J D, LI S Y, et al. One-step method for fabrication of biomimetic superhydrophobic surface on aluminum alloy[J]. Colloids and Surfaces A:Physicochemical and Engineering Asp-ects, 2015, 466:125-131.
[45] PI P H, HOU K, ZHOU C L, et al. Superhydrophobic Cu2S@Cu2O film on copper surface fabricated by a facile chemical bath deposition method and its application in oil-water separation[J]. Applied Surface Science, 2017, 396:566-573.
[46] JIANG S Z, GUO Z N, GYIMAH G K, et al. Preparation of biomimetic superhydrophobic surface by a facile one-step pulse electrodeposition[J]. Procedia CIRP, 2018, 68:237-241.
[47] KANG C, LU H F, YUAN S J, et al. Superhydrophilicity/superhydrophobicity of nickel micro-arrays fabricated by electr-oless deposition on an etched porous aluminum template[J]. Chemical Engineering Journal, 2012, 203(5):1-8.
[48] 程江,赵安,孙逸飞,等. 铜基高梯度润湿表面的构建与表征[J]. 功能材料, 2015, 46(8):8138-8143. CHENG J, ZHAO A, SUN Y F, et al. Preparation and charac-terization of high wettability gradient surface on copper substrate[J]. Journal of Functional Materials,2015, 46(8):8138-8143.
[49] ZHANG B B, LI Y T, HOU B R. One-step electrodeposition fabrication of a superhydrophobic surface on an aluminum sub-strate with enhanced self-cleaning and anticorrosion properties[J]. RSC Advances, 2015, 5(121):100000-100010.
[50] SU F H, YAO K. Facile fabrication of superhydrophobic surface with excellent mechanical abrasion and corrosion resistance on copper substrate by a novel method[J]. ACS Applied Materials and Interfaces, 2014, 6(11):8762-8770.
[51] WAN Y X, CHEN M J, LIU W, et al. The research on prepar-ation of superhydrophobic surfaces of pure copper by hydrother-mal method and its corrosion resistance[J]. Electrochimica Acta, 2018, 270:310-318.
[52] CAO L, WAN Y, WANG Y H, et al. Fabrication and mech-anical durability of a superhydrophobic copper surface with mor-phological development from hydrothermal reaction:fabrication of a superhydrophobic copper surface[J]. Surface and Interface Analysis, 2016, 48(13):1418-1422.
[53] LI L J, HUANG T, LEI J L, et al. Robust biomimetic-stru-ctural superhydrophobic surface on aluminum alloy[J]. ACS Applied Materials & Interfaces, 2015, 7(3):1449-1457.
[54] PAN S, WANG N, XIONG D, et al. Fabrication of superhy-drophobic coating via spraying method and its applications in anti-icing and anti-corrosion[J]. Applied Surface Science, 2016, 389:547-553.
[55] WANG C Z, TANG F, LI Q, et al. Spray-coated superhydr-ophobic surfaces with wear-resistance, drag-reduction and anti-corrosion properties[J]. Colloids and Surfaces A:Physicoch-emical and Engineering Aspects, 2017, 514:236-242.
[56] LI W, KANG Z X. Fabrication of corrosion resistant superhy-drophobic surface with self-cleaning property on magnesium alloy and its mechanical stability[J]. Surface and Coatings Techn-ology, 2014, 253(9):205-213.
[57] FENG L B, YAN Z N, QIANG X H, et al. Facile formation of superhydrophobic aluminum alloy surface and corrosion-resistant behavior[J]. Applied Physics A, 2016, 122(3):165-179.
[58] 朱亚利,范伟博,冯利邦,等. 超疏水镁合金表面的防黏附和耐腐蚀性能[J]. 材料工程, 2016, 44(1):66-70. ZHU Y L, FAN W B,FENG L B, et al. Anti-adhesion and corrosion resistance of superhydrophobic magnesium alloy surf-ace[J]. Journal of Materials Engineering, 2016, 44(1):66-70.
[59] 晏忠钠,车彦慧,冯利邦,等. 超疏水铝合金表面的防覆冰和防黏附行为[J]. 材料工程, 2015, 43(9):25-29. YAN Z N, CHE Y H, FENG L B, et al. Anti-icing and anti-adhesion behavior of superhydrophobic aluminum alloy surface[J]. Journal of Materials Engineering, 2015, 43(9):25-29.
[60] TUO Y J, CHEN W P, ZHANG H F, et al. One-step hydro-thermal method to fabricate drag reduction superhydrophobic surface on aluminum foil[J]. Applied Surface Science, 2018, 446:230-235.
[61] WANG Z P, ZHANG S S, GAO S, et al. A simple, low-cost method to fabricate drag-reducing coatings on a macroscopic mo-del ship[J]. Chemical Research in Chinese Universities,2018,34(4):616-621.
[62] 万闪,姜丹,蔡光义,等. 铝合金超疏水转化膜的制备与性能[J]. 材料工程, 2018, 46(9):144-151. WAN S, JIANG D, CAI G Y, et al. Preparation and properties of superhydrophobic conversion film on aluminium alloy[J]. Journal of Materials Engineering, 2018, 46(9):144-151.
[63] ZHANG Z Z, GE B, MEN X H, et al. Mechanically durable, superhydrophobic coatings prepared by dual-layer method for anti-corrosion and self-cleaning[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2016, 490:182-188.
[64] WANG P, YAO T, SUN B, et al. Fabrication of mechanically robust superhydrophobic steel surface with corrosion resistance property[J]. RSC Advances, 2017, 7(63):699-703.
2019, Vol. 47 
