激光3D打印非晶合金晶化体积分数的理论预测

doi:10.11868/j.issn.1001-4381.2019.000088

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摘要

采用一种有效的方法预测激光3D打印块状非晶合金的晶化程度，对于激光3D工艺参数的选择与优化至关重要。本工作从非晶合金的晶化动力学入手，通过测试不同加热速率下非晶合金的特征温度，获得非晶合金发生晶化所要克服的晶化激活能和Arrhenius指前因子，并结合有限元模拟技术，提出了一种预测激光3D打印非晶合金晶化体积分数的方法。以Zr₅₀Ti₅Cu₂₇Ni₁₀Al₈（Zr50）非晶合金为模型体系，验证了该方法的有效性。结果表明：利用该方法获得的激光3D打印单道Zr50非晶合金晶化相体积分数为1.23%，与实验得到的晶化相体积分数1.65%较接近，这有力地证明了提出的激光3D打印非晶合金晶化体积分数的理论预测方法是可行的。

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	曲丽丹
	韩斌慧
	吕云卓
	白钰枝

关键词 ：非晶合金, 激光3D打印, 晶化, 理论预测

Abstract：

It is very important to apply an effective method to predict the crystallization degree of laser 3D printed bulk metallic glasses (BMGs) for selecting and optimizing the processing parameters of laser 3D printing. In the present study, beginning with the kinetics of crystallization of amorphous alloys, the crystallization activation energy and Arrhenius factor were obtained by testing the characteristics of the temperature of the amorphous alloy under different heating rates, then a novel method of predicting the volume fraction of crystallization for the metallic glass produced by laser 3D printing was proposed combined with the finite element simulation technology. The validity of the method was verified by using Zr₅₀Ti₅Cu₂₇Ni₁₀Al₈(Zr50) amorphous alloy as the model system. The result shows that the volume fraction of the crystalline phase of the single-track Zr50 BMG obtained by this method is 1.23%, which is very close to the experimentally obtained crystallization phase volume fraction of 1.65%. This strongly proves the effectiveness of the theoretical prediction method for the crystallization volume fraction of laser 3D printing BMGs.

Key words： metallic glass laser 3D printing crystallization theoretical prediction

收稿日期: 2019-01-25 出版日期: 2020-07-21

中图分类号:

TG139⁺.8

基金资助:国家自然科学基金资助项目(51671042);国家自然科学基金资助项目(51401041);西安航空职业技术学院2018年综合科研项目(18XHZH-01)

通讯作者: 吕云卓 E-mail: luyz@djtu.edu.cn

作者简介: 吕云卓(1985-), 男, 副教授, 博士, 研究方向为金属材料激光3D打印, 联系地址:辽宁省大连市沙河口区黄河路794号大连交通大学材料科学与工程学院313(116028), E-mail:luyz@djtu.edu.cn

引用本文:

曲丽丹, 韩斌慧, 吕云卓, 白钰枝. 激光3D打印非晶合金晶化体积分数的理论预测[J]. 材料工程, 2020, 48(7): 133-138.
Li-dan QU, Bin-hui HAN, Yun-zhuo LYU, Yu-zhi BAI. Theoretical prediction of crystallization volume fraction for laser 3D printing of metallic glasses. Journal of Materials Engineering, 2020, 48(7): 133-138.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000088 或 http://jme.biam.ac.cn/CN/Y2020/V48/I7/133

Fig.1 不同升温速率下Zr50非晶合金的DSC曲线

Fig.2 Zr50非晶合金的T_x^-1与ln(T_x²/B)的关系曲线

Fig.3 不同等温温度下Zr50非晶合金的等温DSC曲线

Fig.4 不同等温温度下Zr50非晶合金晶化体积分数x′与等温时间t的关系

Fig.5 不同等温温度下Zr50非晶合金ln[－ln(1－x′)]与lnt关系

Fig.6 激光3D打印单道Zr50非晶合金截面SEM形貌(a)以及建立的有限元模型(b)

Fig.7 有限元模拟得到的不同时刻激光3D打印温度场分布(a)t=0.03 s; (b)t=0.1 s; (c)t=0.2 s; (d)t=0.5 s; (e)t=1.0 s

Fig.8 垂直激光移动方向截面平均热循环曲线

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