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材料工程  2020, Vol. 48 Issue (4): 36-45    DOI: 10.11868/j.issn.1001-4381.2019.000592
  纳米材料专栏 本期目录 | 过刊浏览 | 高级检索 |
刘兴华1, 王军丽1, 王亚玲1, 张利2, 杨永珍1, 刘旭光1,3
1. 太原理工大学 新材料界面科学与工程教育部重点实验室, 太原 030024;
2. 山西白求恩医院(山西医学科学院)泌尿科, 太原 030032;
3. 太原理工大学 新型碳材料研究院, 山西 晋中 030600
Adjusting of multicolor fluorescence carbon dots and their application
LIU Xing-hua1, WANG Jun-li1, WANG Ya-ling1, ZHANG Li2, YANG Yong-zhen1, LIU Xu-guang1,3
1. Key Laboratory of Interface Science and Engineering in Advanced Materials(Ministry of Education), Taiyuan University of Technology, Taiyuan 030024, China;
2. Urology Department, Shanxi Bethune Hospital(Shanxi Academy of Medical Sciences), Taiyuan 030032, China;
3. Institute of New Carbon Materials, Taiyuan University of Technology, Jinzhong 030600, Shanxi, China
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摘要 碳点(carbon dots,CDs)由于具有优异的荧光性能、低毒性、原料广泛、生物相容性好等优点,受到了研究人员的广泛关注。然而,目前大部分CDs的发射波长位于蓝光和绿光的短波长区域,这限制了CDs的广泛应用。多色CDs的合成对长波长CDs合成具有一定的指导作用,并且可以拓宽其应用。因此,本文从CDs的粒径、内部结构和表面态角度阐述了CDs的多色发光机理,综述了实现多色CDs的调控措施(包括反应原料、反应参数、表面改性和分离提纯)及其在发光二极管和生物成像方面的应用。
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关键词 碳点多色合成应用    
Abstract:Carbon dots(CDs) have attracted extensive attention of researchers because of their excellent fluorescence performance,low toxicity,extensive raw materials and good biocompatibility.However,the emission wavelengths of most CDs are in short-wavelength region of blue and green light,limiting their widespread application.The synthesis of multicolor CDs can guide the realization of long wavelength CDs and broaden the application of CDs.Therefore, the multicolor emitting mechanism of CDs from sizes,inner structures and surface states of CDs was reviewed,the adjusting measures of achieving multicolor CDs were presented,including raw materials,reaction conditions,surface modification,and separation and purification.Furthermore,the application of multicolor CDs in light emitting diode and bioimaging was also summarized.
Key wordscarbon dot    multicolor    synthesis    application
收稿日期: 2019-06-23      出版日期: 2020-04-23
中图分类号:  O613.71  
通讯作者: 杨永珍(1969-),女,教授,博士生导师,研究方向为碳纳米功能材料与光电材料,联系地址:山西省太原市万柏林区迎泽西大街79号太原理工大学新材料界面科学与工程教育部重点实验室(030024),     E-mail:
刘兴华, 王军丽, 王亚玲, 张利, 杨永珍, 刘旭光. 多色荧光碳点调控及其应用[J]. 材料工程, 2020, 48(4): 36-45.
LIU Xing-hua, WANG Jun-li, WANG Ya-ling, ZHANG Li, YANG Yong-zhen, LIU Xu-guang. Adjusting of multicolor fluorescence carbon dots and their application. Journal of Materials Engineering, 2020, 48(4): 36-45.
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[1] WANG J,WANG Y,ZHENG J,et al.Mechanism,tuning and application of excitation-dependent fluorescence property in carbon dots[J].Progress in Chemistry,2018,30(8):1186-1201.
[2] CUI B,FENG X,ZHANG F,et al.The use of carbon quantum dots as fluorescent materials in white LEDs[J].New Carbon Materials,2017,32(5):385-401.
[3] SUN Y P,ZHOU B,LIN Y,et al.Quantum-sized carbon dots for bright and colorful photoluminescence[J].Journal of the American Chemical Society,2006,128(24):7756-7757.
[4] REN J,SUN J,SUN X,et al.Precisely controlled up/down-conversion liquid and solid state photoluminescence of carbon dots[J].Advanced Optical Materials,2018,6(14):1800115.
[5] ZHENG J,WANG Y,ZHANG F,et al.Microwave-assisted hydrothermal synthesis of solid-state carbon dots with intensive emission for white light-emitting devices[J].Journal of Materials Chemistry:C,2017,5(32):8105-8111.
[6] ZHOU J,BOOKER C,LI R,et al.An electrochemical avenue to blue luminescent nanocrystals from multiwalled carbon nanotubes (MWCNTs)[J].Journal of the American Chemical Society,2007,129(4):744-745.
[7] HU C,YU C,LI M,et al.Chemically tailoring coal to fluorescent carbon dots with tuned size and their capacity for Cu(II) detection[J].Small,2014,10(23):4926-4933.
[8] ZHANG F,FENG X,ZHANG Y,et al.Photoluminescent carbon quantum dots as a directly film-forming phosphor towards white LEDs[J].Nanoscale,2016,8(16):8618-8632.
[9] QU S,LIU X,GUO X,et al.Amplified spontaneous green emission and lasing emission from carbon nanoparticles[J].Advanced Functional Materials,2014,24(18):2689-2695.
[10] LIU R,WU D,LIU S,et al.An aqueous route to multicolor photoluminescent carbon dots using silica spheres as carriers[J].Angewandte Chemie International Edition,2009,48(25):4598-4601.
[11] BOURLINOS A B,STASSINOPOULOS A,ANGLOS D,et al.Surface functionalized carbogenic quantum dots[J].Small,2008,4(4):455-458.
[12] LI M,YU C,HU C,et al.Solvothermal conversion of coal into nitrogen-doped carbon dots with singlet oxygen generation and high quantum yield[J].Chemical Engineering Journal,2017,320:570-575.
[13] ZHAO Q L,ZHANG Z L,HUANG B H,et al.Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite[J].Chemical Communications,2008,41:5116-5118.
[14] LIU X,ZHENG J,YANG Y,et al.Preparation of N-doped carbon dots based on starch and their application in white LED[J].Optical Materials,2018,86:530-536.
[15] WANG L,BI Y,HOU J,et al.Facile,green and clean one-step synthesis of carbon dots from wool:application as a sensor for glyphosate detection based on the inner filter effect[J].Talanta,2016,160:268-275.
[16] LIU Y,ZHAO Y,ZHANG Y.One-step green synthesized fluorescent carbon nanodots from bamboo leaves for copper(Ⅱ) ion detection[J].Sensors and Actuators:B,2014,196:647-652.
[17] ZHANG F,FENG X,ZHANG Y,et al.Photoluminescent carbon quantum dots as a directly film-forming phosphor towards white LEDs[J].Nanoscale,2016,8(16):8618-8632.
[18] ZHENG J,WANG J,WANG Y,et al.Facile and rapid synthesis of yellow-emission carbon dots for white light-emitting diodes[J].Journal of Electronic Materials,2018,47(12):7497-7504.
[19] DU Q,ZHENG J,WANG J,et al.The synthesis of green fluorescent carbon dots for warm white LEDs[J].RSC Advances,2018,8(35):19585-19595.
[20] WANG Z,YUAN F,LI X,et al.53% efficient red emissive carbon quantum dots for high color rendering and stable warm white-light-emitting diodes[J].Advanced Materials,2017,29(37):1702910.
[21] WANG F,CHEN Y,LIU C,et al.White light-emitting devices based on carbon dots' electroluminescence[J].Chemical Communications,2011,47(12):3502-3504.
[22] WANG Y L,ZHAO Y Q,ZHANG Y,et al.A single-phase heteroatom doped carbon dot phosphor toward white light-emitting diodes[J].RSC Advances,2016,6(45):38761-38768.
[23] GUO L,GE J,LIU W,et al.Tunable multicolor carbon dots prepared from well-defined polythiophene derivatives and their emission mechanism[J].Nanoscale,2016,8(2):729-734.
[24] DING H,WEI J S,ZHANG P,et al.Solvent-controlled synthesis of highly luminescent carbon dots with a wide color gamut and narrowed emission peak widths[J].Small,2018,14(22):1800612.
[25] LI H,HE X,KANG Z,et al.Water-soluble fluorescent carbon quantum dots and photocatalyst design[J].Angewandte Chemie International Edition,2010,49(26):4430-4434.
[26] TIAN Z,ZHANG X,LI D,et al.Full-color inorganic carbon dot phosphors for white-light-emitting diodes[J].Advanced Optical Materials,2017,5(19):1700416.
[27] HU S,TRINCHI A,ATKIN P,et al.Tunable photoluminescence across the entire visible spectrum from carbon dots excited by white light[J].Angewandte Chemie International Edition,2015,54(10):2970-2974.
[28] MIAO X,QU D,YANG D,et al.Synthesis of carbon dots with multiple color emission by controlled graphitization and surface functionalization[J].Advanced Materials,2018,30(1):1704740.
[29] JIANG K,SUN S,ZHANG L,et al.Red,green,and blue luminescence by carbon dots:full-color emission tuning and multicolor cellular imaging[J].Angewandte Chemie International Edition,2015,54(18):5360-5363.
[30] LIU C,WANG R,WANG B,et al.Orange,yellow and blue luminescent carbon dots controlled by surface state for multicolor cellular imaging,light emission and illumination[J].Microchimica Acta,2018,185(12):539.
[31] LI S,JIANG J,YAN Y,et al.Red,green,and blue fluorescent folate-receptor-targeting carbon dots for cervical cancer cellular and tissue imaging[J].Materials Science and Engineering:C,2018,93:1054-1063.
[32] 孙晓晗.功能化荧光碳点的合成及其在重金属离子检测和细胞成像中的应用[D].兰州:兰州大学,2017. SUN X H.The synthesis of functionalized fluorescent carbon dots and their applications in the detection of heavy metal ion and cell imaging[D].Lanzhou:Lanzhou University,2017.
[33] HUO F,LIANG W,TANG Y,et al.Full-color carbon dots with multiple red-emission tuning:on/off sensors,in vitro and in vivo multicolor bioimaging[J].Journal of Materials Science,2019,54(9):6815-6825.
[34] 王延冰.多色荧光发射碳量子点的制备及其在金属离子检测中的应用[D].太原:中北大学,2018. WANG Y B.Preparing multicolor fluorescence emission carbon dots and applications in metal ion detection[D].Taiyuan:North University of China,2018.
[35] WANG Y,SU Q,YANG X.Exploration of the synthesis of three types of multicolor carbon dot originating from isomers[J].Chemical Communications,2018,54(80):11312-11315.
[36] BI Z,LI T,SU H,et al.Transparent wood film incorporating carbon dots as encapsulating material for white light-emitting diodes[J].ACS Sustainable Chemistry & Engineering,2018,6(7):9314-9323.
[37] WANG T Y,CHEN C Y,WANG C M,et al.Multicolor functional carbon dots via one-step refluxing synthesis[J].ACS Sensors,2017,2(3):354-363.
[38] ZHAN J,GENG B,WU K,et al.A solvent-engineered molecule fusion strategy for rational synthesis of carbon quantum dots with multicolor bandgap fluorescence[J].Carbon,2018,130:153-163.
[39] SHEN C L,ZANG J H,LOU Q,et al.In-situ embedding carbon dots in trisodium citrate crystal matrix for tunable solid-state fluorescence[J].Carbon,2018,136:359-368.
[40] CHANG Q,DING Y,CHENG S,et al.Quench-resistant and stable nanocarbon dot/sheet emitters with tunable solid-state fluorescence via aggregation-induced color switching[J].Nanoscale,2019,11(5):2131-2137.
[41] YUAN F,WANG Z,LI X,et al.Bright multicolor bandgap fluorescent carbon quantum dots for electroluminescent light-emitting diodes[J].Advanced Materials,2017,29(3):1604436.
[42] GAN Z,DI Y,HUANG S,et al.Modulating the fluorescent color of carbon nanodots via photon reabsorption and carbonization degree[J].Applied Physics Letters,2017,111(24):241903.
[43] LIN S,CHEN M,WANG Z,et al.Construction of full-color light-emitting N-based carbon nanodots and their efficient solid-state materials via tape-casting technology for warm WLED[J].Chemical Engineering Journal,2017,324:194-202.
[44] CHENG C,XING M,WU Q.Preparation of carbon dots with long-wavelength and photoluminescence-tunable emission to achieve multicolor imaging in cells[J].Optical Materials,2019,88:353-358.
[45] CHU C S,HSIEH M W,SU Z R.Optical sensing of H2O2 based on red-shift of emission wavelength of carbon quantum dots[J].Optical Materials Express,2016,6(3):759-766.
[46] FENG T,ZENG Q,LU S,et al.Color-tunable carbon dots possessing solid-state emission for full-color light-emitting diodes applications[J].ACS Photonics,2017,5(2):502-510.
[47] YUAN F,YUAN T,SUI L,et al.Engineering triangular carbon quantum dots with unprecedented narrow bandwidth emission for multicolored LEDs[J].Nature Communications,2018,9(1):2249.
[48] HU S,WANG Y,ZHANG W,et al.Multicolour emission states from charge transfer between carbon dots and surface molecules[J].Materials,2017,10(2):165.
[49] LIU J,GE X,SUN L,et al.Light modulation(vis-NIR region) based on lanthanide complex-functionalized carbon dots[J].RSC Advances,2016,6(53):47427-47433.
[50] GONG X,HU Q,PAAU M C,et al.Red-green-blue fluorescent hollow carbon nanoparticles isolated from chromatographic fractions for cellular imaging[J].Nanoscale,2014,6(14):8162-8170.
[51] LIU H,YE T,MAO C.Fluorescent carbon nanoparticles derived from candle soot[J].Angewandte Chemie International Edition,2007,46(34):6473-6475.
[52] DING H,YU S B,WEI J S,et al.Full-color light-emitting carbon dots with a surface-state-controlled luminescence mechanism[J].ACS Nano,2015,10(1):484-491.
[53] ZHOU Y,LIU Y,LI Y,et al.Multicolor carbon nanodots from food waste and their heavy metal ion detection application[J].RSC Advances,2018,8(42):23657-23662.
[54] HAN L,LIU S G,DONG J X,et al.Facile synthesis of multicolor photoluminescent polymer carbon dots with surface-state energy gap-controlled emission[J].Journal of Materials Chemistry:C,2017,5(41):10785-10793.
[55] DING Y,ZHENG J,WANG J,et al.Direct blending of multicolor carbon quantum dots into fluorescent films for white light emitting diodes with an adjustable correlated color temperature[J].Journal of Materials Chemistry:C,2019,7(6):1502-1509.
[56] BAO L,LIU C,ZHANG Z L,et al.Photoluminescence-tunable carbon nanodots:surface-state energy-gap tuning[J].Advanced Materials,2015,27(10):1663-1667.
[57] 张峰.碳量子点基发光薄膜的合成及其光致和电致发光性质[D].太原:太原理工大学,2017. ZHANG F.The preparation of carbon quantum dots based luminescent films with their photoluminescent and electroluminescent properties[D].Taiyuan:Taiyuan University of Technology,2017.
[58] SHAO J,ZHU S,LIU H,et al.Full-color emission polymer carbon dots with quench-resistant solid-state fluorescence[J].Advanced Science,2017,4(12):1700395.
[59] XU J,MIAO Y,ZHENG J,et al.Ultrahigh brightness carbon dot-based blue electroluminescent LEDs by host-guest energy transfer emission mechanism[J].Advanced Optical Materials,2018,6(14):1800181.
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