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2222材料工程  2020, Vol. 48 Issue (7): 146-153    DOI: 10.11868/j.issn.1001-4381.2019.000617
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
基于正交实验方法的蛇纹石润滑油添加剂摩擦学性能
尹艳丽, 于鹤龙(), 周新远, 宋占永, 王红美, 王文宇, 刘晓亭, 徐滨士
陆军装甲兵学院 装备再制造技术国防科技重点实验室, 北京 100072
Tribological properties of serpentine lubricant additives evaluated by orthogonal tests method
Yan-li YIN, He-long YU(), Xin-yuan ZHOU, Zhan-yong SONG, Hong-mei WANG, Wen-yu WANG, Xiao-ting LIU, Bin-shi XU
National Key Laboratory for Remanufacturing, Army Academy of Armored Forces, Beijing 100072, China
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摘要 

采用正交实验方法，利用往复式滑动磨损试验机研究油酸改性天然蛇纹石超细粉体作为500SN润滑油添加剂的减摩抗磨性能，分析载荷、往复频率、摩擦时间和蛇纹石添加量4个因素对蛇纹石添加剂性能的影响规律。结果表明：蛇纹石矿物粉体能够明显提高润滑油的摩擦学性能，各因素对其减摩性能影响的主次顺序依次为添加量、往复频率、载荷和摩擦时间，对应的最优摩擦学条件组合为100 N，5 Hz，180 min，0.5%（质量分数，下同）；对抗磨性能影响的主次顺序依次为载荷、添加量、往复频率和摩擦时间，最优条件组合为100 N，50 Hz，180 min，0.3%。蛇纹石矿物在摩擦表面形成的由多种氧化物、石墨和有机化合物等组成的复合摩擦反应膜是改善摩擦和磨损的关键。
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尹艳丽
于鹤龙
周新远
宋占永
王红美
王文宇
刘晓亭
徐滨士
关键词 ： 蛇纹石,  润滑油,  添加剂,  摩擦学性能,  正交实验    
Abstract：

Tribological properties of oleic acid modified natural serpentine ultrafine mineral powders as lubricating oil additive were investigated by a reciprocating sliding wear tester. The effects of the four factors including load, reciprocating frequency, sliding time and concentration of serpentine on the properties of serpentine additive were analyzed. Results indicate that the anti-wear and friction-reducing properties of the base oil are significantly improved by the addition of the modified serpentine powders. The order that affects the friction-reducing performance of the serpentine additive is:concentration, reciprocating frequency, load, sliding time, and the optimal tribological conditions are 100 N, 5 Hz, 180 min, 0.5%(mass fraction). While that affects the anti-wear property is:load, concentration, reciprocating frequency, sliding time, and the optimal conditions are 100 N, 50 Hz, 180 min, 0.3%. Serpentine minerals forms a tribofilm consisting of various oxides, graphite and organic compounds on the friction surface, which is the key to improving anti-wear and friction-reducing properties.
Key words： serpentine    lubricating oil    additive    tribological property    orthogonal test
收稿日期: 2019-07-01      出版日期: 2020-07-21
中图分类号:  TH117.2  
基金资助:国家重点研发计划项目(2017YFB0310703)
通讯作者: 于鹤龙     E-mail: helong.yu@163.com
作者简介: 于鹤龙(1979-), 男, 副研究员, 博士, 研究方向为自修复材料及再制造工程, 联系地址:北京市丰台区杜家坎21号院再制造技术重点实验室(100072), E-mail:helong.yu@163.com
引用本文:   
尹艳丽, 于鹤龙, 周新远, 宋占永, 王红美, 王文宇, 刘晓亭, 徐滨士. 基于正交实验方法的蛇纹石润滑油添加剂摩擦学性能[J]. 材料工程, 2020, 48(7): 146-153.
Yan-li YIN, He-long YU, Xin-yuan ZHOU, Zhan-yong SONG, Hong-mei WANG, Wen-yu WANG, Xiao-ting LIU, Bin-shi XU. Tribological properties of serpentine lubricant additives evaluated by orthogonal tests method. Journal of Materials Engineering, 2020, 48(7): 146-153.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000617      或      http://jme.biam.ac.cn/CN/Y2020/V48/I7/146
Fig.1  蛇纹石粉体的TEM形貌
No Factor Result
Load(A)/N Frequency(B)/Hz Duration(C)/min Content(D)/% fR/% wR/%
1 1(50) 1(5) 1(60) 1(0.1) 23.2 －27.0
2 1(50) 2(20) 2(120) 2(0.3) 20.4 18.8
3 1(50) 3(50) 3(180) 3(0.5) 35.5 15.8
4 2(100) 1(5) 2(120) 3(0.5) 42.4 53.9
5 2(100) 2(20) 3(180) 1(0.1) 22.3 51.5
6 2(100) 3(50) 1(60) 2(0.3) 29.7 85.3
7 3(150) 1(5) 3(180) 2(0.3) 34.6 71.4
8 3(150) 2(20) 1(60) 3(0.5) 27.8 51.3
9 3(150) 3(50) 2(120) 1(0.1) 26.8 65.7
Table 1  正交实验设计及结果
T fR wR
Load(A)/N Frequency(B)/Hz Duration(C)/min Content(D)/% Load(A)/N Frequency(B)/Hz Duration(C)/min Content(D)/%
T1 79.1 100.1 80.7 72.3 7.5 98.3 109.5 90.2
T2 94.3 70.5 89.6 84.6 190.7 121.7 138.4 175.4
T3 89.2 92.0 92.3 105.7 188.4 166.8 138.7 121.0
t1 26.4 33.4 26.9 24.1 2.5 32.8 36.5 30.1
t2 31.4 23.5 29.8 28.2 63.6 40.5 46.1 58.5
t3 29.7 30.6 30.8 35.2 62.8 55.6 46.2 40.3
R 5.0 9.9 3.9 11.1 61.1 22.8 9.7 28.4
Optimal solution A2 B1 C3 D3 A2 B3 C3 D2
Order of factors D＞B＞A＞C A＞D＞B＞C
Table 2  正交实验分析
Fig.2  500SN和含蛇纹石油样的典型摩擦因数变化曲线(a)及润滑油作用下的材料磨损体积(b)
Fig.3  在100 N, 50 Hz, 180 min条件下500SN(a)与添加蛇纹石润滑油(b)润滑下的磨损表面SEM形貌
Fig.4  磨损表面形貌及EDS能谱图
(a)500SN润滑；(b)含蛇纹石油样润滑
Area C O Mg Si Al Fe
A 7.87 2.91 - - - 89.22
B 7.94 12.50 1.55 2.54 0.81 74.66
Table 3  磨损表面EDS能谱分析结果(质量分数/%)
Fig.5  500SN(1)和含蛇纹石油样(2)润滑下磨损表面主要元素的XPS图谱
(a)Si2p;(b)Fe2p3/2; (c)O1s;(d)C1s
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