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材料工程  2020, Vol. 48 Issue (7): 24-35    DOI: 10.11868/j.issn.1001-4381.2019.000915
  石墨烯专栏 本期目录 | 过刊浏览 | 高级检索 |
氧化石墨烯的化学还原方法与机理研究进展
郭建强1,2,3, 李炯利1,2,3, 梁佳丰1,2, 李岳1,2, 朱巧思1,2, 王旭东1,2,3
1. 中国航发北京航空材料研究院, 北京 100095;
2. 北京石墨烯技术研究院有限公司, 北京 100094;
3. 北京市石墨烯及应用工程技术研究中心, 北京 100095
Research progress in methods and mechanisms of chemical reduction graphene oxide
GUO Jian-qiang1,2,3, LI Jiong-li1,2,3, LIANG Jia-feng1,2, LI Yue1,2, ZHU Qiao-si1,2, WANG Xu-dong1,2,3
1. AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China;
2. Beijing Institute of Graphene Technology, Beijing 100094, China;
3. Beijing Engineering Research Centre of Graphene Application, Beijing 100095, China
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摘要 石墨烯物理性能优异,自被发现以来迅速引起了国内外研究者的广泛关注。石墨烯的批量生产是实现石墨烯材料应用的前提,由于氧化石墨烯具有丰富的含氧官能团,便于化学改性,生产成本低、可规模化生产,化学还原氧化石墨烯成为目前大批量制备石墨烯材料最常用的方法之一。至今已经有数十种化学还原氧化石墨烯的方法被报道,还原效果千差万别,还原机理也尚未定论。本文梳理了氧化石墨烯的主要化学还原方法,从关键反应基团的角度进行了归纳总结,论述了它们的优缺点;分析了多种氧化石墨烯的还原机理,提出氧化石墨烯化学还原的本质是羟基还原同时形成碳碳双键的过程。
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郭建强
李炯利
梁佳丰
李岳
朱巧思
王旭东
关键词 石墨烯氧化石墨烯化学还原还原机理    
Abstract:The mass production of graphene sheets is a prerequisite for exploiting the applications of graphene. A major focus of experimental research has been concentrated on the development of effective approaches to produce well-defined graphene in large scale. Due to its high yield and cost efficiency, chemical reduction of graphene oxide has been proofed to be one of the most feasible approaches to achieve this goal. Graphene consists almost entirely of sp2 hybridized carbon atoms, while graphene oxide additionally contains sp3 regions, oxygen functional groups and structural defects. The fundamental understanding of the mechanism of chemical reduction of graphene oxide is a key issue when preparing graphene materials via graphene oxide precursor. Although dozens of methods have been exploited to facilitate the chemical reduction of graphene, only few studies were focused on the reduction mechanism.The chemical reduction strategies of graphene oxide, and as well as their mechanisms were reviewed in this paper. It was suggested that the core issue of the reduction is how to clarify the removal of hydroxyl groups and the simultaneous restoration of a conjugated structure.
Key wordsgraphene    graphene oxide    chemical reduction    reduction mechanism
收稿日期: 2019-10-08      出版日期: 2020-07-17
中图分类号:  TB34  
基金资助: 
通讯作者: 王旭东(1980-),男,研究员,博士,主要研究方向为石墨烯复合材料,联系地址:北京81信箱2分箱(100095),E-mail:netfacn@163.com     E-mail: netfacn@163.com
引用本文:   
郭建强, 李炯利, 梁佳丰, 李岳, 朱巧思, 王旭东. 氧化石墨烯的化学还原方法与机理研究进展[J]. 材料工程, 2020, 48(7): 24-35.
GUO Jian-qiang, LI Jiong-li, LIANG Jia-feng, LI Yue, ZHU Qiao-si, WANG Xu-dong. Research progress in methods and mechanisms of chemical reduction graphene oxide. Journal of Materials Engineering, 2020, 48(7): 24-35.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000915      或      http://jme.biam.ac.cn/CN/Y2020/V48/I7/24
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