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2222材料工程  2020, Vol. 48 Issue (8): 73-83    DOI: 10.11868/j.issn.1001-4381.2020.000182
  综述 本期目录 | 过刊浏览 | 高级检索 |
GH4720Li合金中析出相的研究进展
曲敬龙1,2, 易出山3, 陈竞炜4, 史玉亭2, 毕中南2, 杜金辉2,*()
1 北京钢研高纳科技股份有限公司, 北京 100081
2 钢铁研究总院高温合金新材料北京市重点实验室, 北京 100081
3 中国航发南方工业有限公司, 湖南 株洲 410000
4 中国航发湖南动力机械研究所, 湖南 株洲 412000
Research progress of precipitated phase in GH4720Li superalloy
Jing-long QU1,2, Chu-shan YI3, Jing-wei CHEN4, Yu-ting SHI2, Zhong-nan BI2, Jin-hui DU2,*()
1 Beijing GAONA Materials & Technology Co., Ltd., Beijing 100081, China
2 Beijing Key Laboratory of Advanced High Temperature Materials, Central Iron & Steel Research Institute, Beijing 100081, China
3 AECC South Industry Company Limited, Zhuzhou 410000, Hunan, China
4 AECC Hunan Aviation Powerplant Research Institute, Zhuzhou 412000, Hunan, China
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摘要 

GH4720Li高温合金因其具有良好的高温强度、抗疲劳和抗腐蚀性能以及长期组织稳定性,被广泛应用于高性能航空发动机涡轮盘等转动部件。本文归纳了GH4720Li高温合金中γ'相的作用机理和演变规律,并分析了γ'相与高温性能之间的关联性和γ'相与残余应力的交互影响规律。此外,还综述了GH4720Li高温合金的改型研究进展,展望了未来分区控冷技术和双组织双性能盘制备技术在高温合金中的应用。

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曲敬龙
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毕中南
杜金辉
关键词 GH4720Li高温合金析出相热加工服役性能残余应力新型合金    
Abstract

GH4720Li superalloy has been widely employed in high-performance aero engines turbine disks and other rotating component due to the excellent high temperature strength, anti-fatigue, corrosion resistance and long-term structural stability. The mechanism of function and evolution rule of γ'phase in GH4720Li superalloy was summed up in this paper. The relationship between γ'phase and high-temperature properties and the interaction law of γ'phase and residual stress were analyzed. In addition, the research progress of the new superalloy which was designed on the basis of GH4720Li superalloy was summarized, the future application of partitioned cooling technology and dual-organization dual-performance disk preparation technology was prospected.

Key wordsGH4720Li superalloy    precipitate    hot working    service property    residual stress    new superalloy
收稿日期: 2020-03-05      出版日期: 2020-08-15
中图分类号:  TG115.23  
基金资助:国家自然科学基金面上项目(51874103)
通讯作者: 杜金辉     E-mail: superally_1@163.com
作者简介: 杜金辉(1968-), 男, 正高级工程师, 博士, 研究方向:高温合金新材料研制, 联系地址:北京市海淀区学院南路76号钢铁研究总院(100081), E-mail:superally_1@163.com
引用本文:   
曲敬龙, 易出山, 陈竞炜, 史玉亭, 毕中南, 杜金辉. GH4720Li合金中析出相的研究进展[J]. 材料工程, 2020, 48(8): 73-83.
Jing-long QU, Chu-shan YI, Jing-wei CHEN, Yu-ting SHI, Zhong-nan BI, Jin-hui DU. Research progress of precipitated phase in GH4720Li superalloy. Journal of Materials Engineering, 2020, 48(8): 73-83.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2020.000182      或      http://jme.biam.ac.cn/CN/Y2020/V48/I8/73
Fig.1  GH4720Li高温合金热力学平衡相图
Phase Cr Al Ti C Co Mo W Ni
γ 21.4 1.58 2.22 16.8 4.10 1.51 52.4
γ 2.68 4.79 11.7 9.58 0.261 0.522 70.4
MC 0.69 71.4 17.4 0.601 9.94
M23C6 70.8 5.13 2.01 20.2 0.014 1.86
σ 55.6 32.1 5.32 0.126 6.94
μ 15.6 26.2 41.1 5.37 11.7
Table 1  GH4720Li合金析出相对应的平衡成分(质量分数/%)[13]
Fig.2  GH4720Li热处理后的γ′相分布
(a)示意图;(b)SEM图
Phase Size/μm Temperature/℃ Distribution Function
Primary γ 1-10 < 1160 Grain boundary Organizational regulation
Secondary γ 90-200 800-950 Intragranular Strength
Tertiary γ 15-50 600-750 Intragranular Strength
Table 2  GH4720Li合金中γ′相的类型、分布和作用[11-12]
Superalloy Mass fraction/% Dissolution temperature of γ′/℃ γ′/%(700 ℃) Temperature/℃
Al Ti Nb
GH4169 0.5 0.9 5.125 890 15 650
GH4169D 1.45 0.75 5.6 930 20 700
GH4738 1.4 3 - 1040 25 700
GH4720Li 2.5 5 - 1160 45 750
Table 3  GH4720Li高温合金与常用涡轮盘件用高温合金主要参数对比[13]
Fig.3  再结晶过程中γ′相的透射图(1)及示意图(2)[21]
(a)细小γ′相;(b)粗化γ′相
Fig.4  GH4720Li高温合金棒材预处理前后光学显微镜(1)和扫描电子显微镜(2)照片
(a)未预处理;(b)预处理后
Fig.5  GH4720Li高温合金热变形过程中光学显微镜照片
(a)均匀化退火态;(b)再结晶态;(c)GH4720Li棒材
Fig.6  GH4169高温合金和GH4720Li高温合金冷却过程中收缩应变[33]
Fig.7  中子衍射法测得的盘锻件残余应力分布[33]
(a)中子衍射实验测试位置示意图;(b)GH4720Li高温合金;(c)GH4169高温合金
Superalloy Mass fraction/% (Ti+Nb)/Al Ti/(Al+Ti+Nb) in γ γ′ solution temperature/℃ γ′/%(700 ℃)
Al Ti Nb
GH4720Li 2.5 5 - 2 0.559 1150 45
GH4730 2.25 3.5 1.1 2 0.446 1090 35
Table 4  GH4720Li高温合金与GH4730高温合金对比[40]
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