Abstract：Non-metallic materials such as fiber reinforced resin matrix composites with high specific strength and high specific energy absorption are the key material technologies to realize lightweight and strong protection of armor equipment. Aiming at the requirement of armored equipment protective components for high-performance ballistic materials, the technical progress, application status and development trend of polymer composite in the field of armor protection were summarized. The application of fiber reinforced resin matrix composites in composite armor, structural armor, multi-functional protective components and transparent polymer materials in transparent armor was discussed. Comparative analysis on the development and application status of high-grade organic fibers such as aramid Ⅱ, aramid Ⅲ, PBO, PIPD in China was carried out. A series of developments based on the maturity of fiber technology and different manufacturing costs, meeting the requirements of the near-term, mid-term, long-term armored equipment protection structure were proposed,and suggestions to strengthen the research on graphene ballistic materials, smart armor materials and other cutting-edge emerging protective materials and their mechanisms, and to establish and improve material evaluation methods, mechanism models and databases in the future were put forward.
[1] BENZAIT Z,RABZON L.A review of recent research on materials used in polymer-matrix composites for body armor application[J].Journal of Composite Materials,2018,52(23):3241-3263.
[2] 高华,熊超,殷军辉.纤维增强复合材料防弹装甲抗侵彻性能研究[J].飞航导弹,2018(2):91-94. GAO H,XIONG C,YIN J H.Research on penetration resistance of fiber reinforced composite bulletproof armor[J].Air Missile,2018(2):91-94.
[3] 焦亚男,何业茂,周庆,等.纤维增强树脂基复合材料防弹性能影响因素及破坏机制[J].复合材料学报,2017,34(9):1960-1972. JIAO Y N,HE Y M,ZHOU Q,et al.Factors influencing the bu-lletproof performance of fiber-reinforced resin matrix composites and failure mechanism[J].Journal of Composites,2017,34(9):1960-1972.
[4] 周亮,肖精华,黄叶萍.复合装甲材料研究新动向[J].国防技术基础,2017(1):29-33. ZHOU L,XIAO J H,HUANG Y P.New trends in composite armor materials research[J].Foundation of National Defense Technology,2017(1):29-33.
[5] 曹凌宇,罗兴柏,刘国庆,等.国外新型装甲防护技术综述[J].飞航导弹,2018(9):74-78. CAO L Y,LUO X B,LIU G Q,et al.Review of new foreign armored protection technology[J].Air Missile,2018(9):74-78.
[6] LIU X,LI M,LI X,et al.Ballistic performance of UHMWPE fabrics/EAMS hybrid panel[J].Journal of Materials Science,2018,53(10):7357-7371.
[7] SHEN Z,HU D,ZHANG Y,et al.Continuous twice-impacts ana-lysis of UHMWPE laminate fixed with bolted joints[J].International Journal of Impact Engineering,2017,109:293-301.
[8] DOGAN A,ARIKAN V.Low-velocity impact response of E-glass reinforced thermoset and thermoplastic based sandwich compo-sites[J].Composites Part B:Engineering,2017,127:63-69.
[9] 徐鲁杰,李想,马武伟.纤维增强复合材料装甲防护性能影响因素分析研究[J].材料开发与应用,2017,32(2):47-53. XU L J,LI X,MA W W.Analysis and research on influencing factors of armor protection performance of fiber reinforced compo-sites[J].Materials Development and Application,2017,32(2):47-53.
[10] BOGETTI T A,WALTER M,STANISZEWSKI J,et al.Interlaminar shear characterization of ultra-high molecular weight polyethylene (UHMWPE) composite laminates[J].Composites Part A:Applied Science and Manufacturing,2017,98:105-115.
[11] NAGHIZADEH Z,FAEZIPOUR M,POL M H,et al.Improvement in impact resistance performance of glass/epoxy composite through carbon nanotubes and silica nanoparticles[J].Procee-dings of the Institution of Mechanical Engineers, Part L:Journal of Materials:Design and Applications,2018,232(9):785-799.
[12] BALALI E,KORDANI N,SADOUGH V A.Response of glass fiber-reinforced hybrid shear thickening fluid (STF) under low-velocity impact[J].The Journal of the Textile Institute,2017,108(3):376-384.
[13] 刘建勋,祖群,朱建勋,等. 新型高强度玻璃纤维制备及其增强环氧树脂性能[J]. 航空制造技术,2010(17):75-77. LIU J X,ZU Q,ZHU J X,et al. Preparation of new high-strength glass fiber and performance of reinforced epoxy resin[J]. Aeronautical Manufacturing Technology,2010(17):75-77.
[14] 陈虹,虎龙,艾青松,等.芳纶复合材料在防弹车上的应用研究[J].中国个体防护装备,2017(2):5-8. CHEN H,HU L,AI Q S,et al.Research on the application of aramid fiber composites in bulletproof vehicles[J].China Indivi-dual Protective Equipment,2017(2):5-8.
[15] BANDARU A K,AHMAD S,BHATNAGAR N.Ballistic performance of hybrid thermoplastic composite armors reinforced with Kevlar and basalt fabrics[J].Composites Part A:Applied Science and Manufacturing,2017,97:151-165.
[16] 李亚锋,礼嵩明,黑艳伟,等.太阳辐照对芳纶纤维及其复合材料性能的影响[J].材料工程,2019,47(4):39-46. LI Y F,LI S M,HEI Y W,et al.Effects of solar irradiation on the properties of aramid fiber and its composites[J].Journal of Materials Engineering,2019,47(4):39-46.
[17] XU C,WANG Y,WU J,et al.Anti-impact response of Kevlar sandwich structure with silly putty core[J].Composites Science and Technology,2017,153:168-177.
[18] VALLEE P,ENG P. Armour system literature and industry survey for ballistic protection[M]. Quebec,Canada:CMC,1998:50-60.
[19] ROY R,LAHA A,AWASTHI N,et al.Multi layered natural rubber coated woven P-aramid and UHMWPE fabric composites for soft body armor application[J].Polymer Composites,2018,39(10):3636-3644.
[20] Da SILVA F A B-H,JÚNIOR L,PEREIRAÉ,et al.Response to ballistic impact of alumina-UHMWPE composites[J].Materials Research,2018,21(5):131-144.
[21] ZHOU Y,LI G,FAN Q,et al.Study on protection mechanism of 30CrMnMo-UHMWPE composite armor[J].Materials,2017,10(4):405-416.
[22] PRIYANKA P,DIXIT A,MALI H S.High-strength hybrid textile composites with carbon, Kevlar, and E-glass fibers for impact-resistant structures.a review[J].Mechanics of Composite Materials,2017,53(5):685-704.
[23] HU D,ZHANG Y,SHEN Z,et al.Investigation on the ballistic behavior of mosaic SiC/UHMWPE composite armor systems[J].Ceramics International,2017,43(13):10368-10376.
[24] LAI X,GUO R,XIAO H,et al.Flexible conductive copper/reduced graphene oxide coated PBO fibers modified with poly (dopamine)[J].Journal of Alloys and Compounds,2019,788:1169-1176.
[25] LAI X,GUO R,LAN J,et al.Flexible reduced graphene oxide/electroless copper plated poly (benzo)-benzimidazole fibers with electrical conductivity and corrosion resistance[J].Journal of Materials Science:Materials in Electronics,2019,30(3):1984-1992.
[26] HAO W Z,ZHANG X J,TIAN Y H.Thermal, mechanical, and microstructural study of PBO fiber during carbonization[J].Materials,2019,12(4):608.
[27] LI M,DONG J,ZHENG S,et al.Fabrication of poly (bis-benzimidazole imide) fibers with enhanced mechanical properties and high limit oxygen indexes[J].Polymer Testing,2019,76:222-231.
[28] TANG Y S,DONG W C,TANG L,et al.Fabrication and investigations on the polydopamine/KH-560 functionalized PBO fibers/cyanate ester wave-transparent composites[J].Composites Co-mmunications,2018,8:36-41.
[29] LUO L,HONG D,ZHANG L,et al.Surface modification of PBO fibers by direct fluorination and corresponding chemical reaction mechanism[J].Composites Science and Technology,2018,165:106-114.
[30] HU Z,SHAO Q,HUANG Y,et al.Light triggered interfacial damage self-healing of poly (p-phenylene benzobisoxazole) fiber composites[J].Nanotechnology,2018,29(18):526-529.
[31] LI J,WANG W,ZHAO L,et al.In situ synthesis of PBO-α-(amino phthalocyanine copper) composite fiber with excellent UV-resistance and tensile strength[J].Journal of Applied Polymer Science,2018,135(48):46870.
[32] 何烨,肖建文,姚烛威,等.碳纤维表面物理结构对复合材料界面剪切强度的影响[J].材料工程,2019,47(2):146-152. HE Y,XIAO J W,YAO Z W,et al.Effects of surface physical structure of carbon fiber on interfacial shear strength of compo-sites[J].Journal of Materials Engineering,2019,47(2):146-152.
[33] YANG Y,CHEN X.Investigation of failure modes and influence on ballistic performance of ultra-high molecular weight polyethylene (UHMWPE) uni-directional laminate for hybrid design[J].Composite Structures,2017,174:233-243.
[34] HARO E E,ODESHI A G,SZPUNAR J A.The effects of micro-and nano-fillers' additions on the dynamic impact response of hybrid composite armors made of HDPE reinforced with Kevlar short fibers[J].Polymer-Plastics Technology and Engineering,2018,57(7):609-624.
[35] SAFRI S N A,SULTAN M T H,JAWAID M,et al.Impact behaviour of hybrid composites for structural applications:a review[J].Composites Part B:Engineering,2018,133:112-121.
[36] LARSSON F,SVENSSON L. Carbon,polyethylene and PBO hybrid fibre composites for structural lightweight armour[J]. Composites:Part A,2002,33:221-231.
[37] SHIH Y F,CHOU M Y,LIAN H Y,et al.Highly transparent and impact-resistant PMMA nanocomposites reinforced by cellulose nanofibers of pineapple leaves modified by eco-friendly methods[J].Express Polymer Letters,2018,12(9):844-854.
[38] JIANG L,HE J,SUN J.Sample width and thickness effects on upward flame spread over PMMA surface[J].Journal of Hazar-dous Materials,2018,342:114-120.
[39] SNYDER R L,FORTMAN D J,De HOE G X,et al.Reprocessable acid-degradable polycarbonate vitrimers[J].Macromolecules,2018,51(2):389-397.
[40] LUO F,LIU X,SHAO C,et al.Micromechanical analysis of molecular orientation in high-temperature creep of polycarbonate[J].Materials & Design,2018,144:25-31.
[41] DURANTE M,FORMISANO A,LAMBIASE F.Incremental forming of polycarbonate sheets[J].Journal of Materials Processing Technology,2018,253:57-63.
[42] DANILAEV M P,BOGOSLOV E A,KUKLIN V A,et al.Structure and mechanical properties of a dispersedly filled transparent polycarbonate[J].Mechanics of Composite Materials,2019,55(1):53-62.
[43] WANG X,ZHANG W,QIN Z,et al.Optically transparent and flame-retarded polycarbonate nanocomposite based on diphenylphosphine oxide-containing polyhedral oligomeric silsesquioxanes[J].Composites Part A:Applied Science and Manufacturing,2019,117:92-102.
[44] CHANG K,JIA H,GU S.A transparent, highly stretchable, self-healing polyurethane based on disulfide bonds[J].European Polymer Journal,2019,112:822-831.
[45] JIAN X,HU Y,ZHOU W,et al.Self-healing polyurethane based on disulfide bond and hydrogen bond[J].Polymers for Advanced Technologies,2018,29(1):463-469.
2020, Vol. 48 
