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2222材料工程  2021, Vol. 49 Issue (1): 44-54    DOI: 10.11868/j.issn.1001-4381.2020.000254
  综述 本期目录 | 过刊浏览 | 高级检索 |
高熵非晶合金耐腐蚀性能研究进展
张舒研1,2, 高洋洋1, 张志彬2, 梁秀兵1,2,*(), 王立忠1,*()
1 浙江大学 海洋学院, 浙江 舟山 316021
2 军事科学院 国防科技创新研究院, 北京 100071
Research progress in corrosion resistance of high-entropy metallic glasses
Shu-yan ZHANG1,2, Yang-yang GAO1, Zhi-bin ZHANG2, Xiu-bing LIANG1,2,*(), Li-zhong WANG1,*()
1 Ocean College, Zhejiang University, Zhoushan 316021, Zhejiang, China
2 National Innovation Institute of Defense Technology, Academy of Military Sciences of the PLA of China, Beijing 100071, China
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摘要 

高熵非晶合金是近年来发展起来的一种新型合金材料，因其兼具高熵合金和非晶合金优异的力学性能、耐腐蚀性能、磁性能等功能特性，引发了众多学者的广泛关注。本文简述了高熵非晶合金的含义与特点，介绍了高熵非晶材料的制备方法及组织与性能；归纳了该类材料的耐蚀机理与耐腐蚀性能的最新研究成果；展望了采用机器学习助力设计高熵非晶合金的新范式，并指出探究工况环境下的腐蚀失效机制、完善高熵非晶合金微观耐蚀机理与优化相关制备工艺是该材料广泛应用的前提条件。针对高熵非晶合金的开发及其耐腐蚀性开展的应用基础研究，将为我国海洋事业的"远洋化、深海化"提供先进的技术支撑和材料保障。
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张舒研
高洋洋
张志彬
梁秀兵
王立忠
关键词 ： 高熵非晶合金,  耐腐蚀性,  制备方法,  组织与性能    
Abstract：

The high-entropy metallic glasses, as a new kind of alloyed materials, have attracted considerable attention due to its excellent mechanical, anti-corrosion and magnetic properties and so forth, which combines the advantages of high-entropy alloys and metallic glasses. Herein, a comprehensive understanding of the concepts and features of high-entropy metallic glasses was provided as well as its preparation methods, distinguished structure and performance characteristics. The recent developments in the corrosion resistance mechanism and anti-corrosion properties were summarized. A new paradigm of using machine learning to design high-entropy metallic glasses was prospected. It was also pointed out that the precondition to the extensive use of this sort of materials is to explore the corrosion failure mechanism under the working conditions, and to achieve the micro-corrosion resistance mechanism perfection and its preparation process optimization. At present, the applied basic research on the development of high-entropy metallic glasses and its corrosion resistance will provide advanced technical support and material guarantee for the "Marching into the deep ocean" of China's marine industry.
Key words： high-entropy metallic glass    anti-corrosion property    preparation method    microstructure and property
收稿日期: 2020-03-25      出版日期: 2021-01-14
中图分类号:  TG178  
基金资助:国家重点研发计划项目(2018YFC1902400);国家自然科学基金项目(51975582)
通讯作者: 梁秀兵,王立忠     E-mail: liangxb_d@163.com;wanglz@zju.edu.cn
作者简介: 王立忠(1969-), 男, 教授, 博士生导师, 研究方向为海洋岩土工程与软土力学, 联系地址:浙江省舟山市定海区浙大路1号浙江大学海洋学院行政楼411室(316021), E-mail:wanglz@zju.edu.cn
梁秀兵(1974-), 男, 研究员, 博士生导师, 主要从事新型功能材料设计与研究等相关工作, 联系地址:北京市丰台区东大街53号院国防科技创新研究院(100071), E-mail:liangxb_d@163.com
引用本文:   
张舒研, 高洋洋, 张志彬, 梁秀兵, 王立忠. 高熵非晶合金耐腐蚀性能研究进展[J]. 材料工程, 2021, 49(1): 44-54.
Shu-yan ZHANG, Yang-yang GAO, Zhi-bin ZHANG, Xiu-bing LIANG, Li-zhong WANG. Research progress in corrosion resistance of high-entropy metallic glasses. Journal of Materials Engineering, 2021, 49(1): 44-54.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2020.000254      或      http://jme.biam.ac.cn/CN/Y2021/V49/I1/44
Form Component Preparation method Characteristic Reference
dc/mm or phase Hardness Performance characteristic
Bulk Gd20Tb20Dy20Al20Co(Ni)20 Vacuum arc melting+ 1 Excellent soft magnetic [24]
Er20Dy20Co20Al20Gd20 copper mold casting 1.5 and room-temperature [25]
Er20Dy20Co20Al20Tm20 1 magnetocaloric [25]
Fe25Co25Ni25Mo5P10B10 Fluxing treatment and
J-quenching technique		 1.2 properties
 [26]
Ti20Zr20Cu20Ni20Be20 Copper mold injection
casting method		 3 High fracture strength & good GFA [27]
Ti20Zr20Hf20Cu20Ni20 1.5 Good mechanical properties [10]
Pd20Pt20Cu20Ni20P20 Fluxed water quenching 10 [2]
FeCrAlCuNiSi MA+ultrahigh pressure
consolidation		 1100-
1120HV		 Anti-corrosion & excellent mechanical properties [28]
CuMnTiMoCrFe Uniform droplets spraying micro-fabrication method 1200HV As a consumable for 3D
printing		 [29]
Fe20Ni20Cr25Mo15(P0.6C0.2B0.2)20 Induction-melting method 1 1107HV Exceptional thermal stability & corrosion resistance [30]
Ca20Mg20Zn20Sr20Yb20 >2 Bio-corrosion &
biocompatibility		 [12]
Zn20Ca20Sr20Yb20(Li0.55
Mg0.45)20		 3 Good conductivity,
polymerlike thermoplastic manufacturability & ultr-alow elastic moduli		 [1]
Ti16.7Zr16.7Hf16.7Cu16.7
Ni16.7Be16.7		 A copper mould suction
casting technique		 >15 High fracture strength [31]
Thin
film/		 (FeCoNi)25(AlTiZr)75 DC/RF/reactive
magnetron sputtering		 FCC+amorphous
and nanocrystalline		 Anti-corrosion property,
good tribological		 [32]
coatings (TiAlCrNbY)-C FCC+amorphous performance, excellent [33]
(AlCrSiTiZr)77.6N22.4 Amorphous thermal stability & [34]
TiAlCrSiV superior tensile properties [35]
GexNbTaTiZr (x=0.5, 1) [13]
AlCrTaTiZr [36]
Al0.3CoCrFeNi with Ni-P
amorphous film		 Electroless-plating method [37]
FeCrCoNiSiB Laser cladding FCC+amorphous [38]
FeCoNiBSi FCC+BCC+
amorphous		 400HV0.1 [39]
Ribbon Gd20Tb20Dy20Al20Fe20 Arc melting+spinning
Cu roller		 Amorphous Large magnetocaloric
effect		 [24]
Zr20Ti20Hf20Cu20Co20
Zr20Ti20Hf20Cu20Fe20		 Melt spinning+copper
mold casting method		 Good mechanical
properties		 [10]
(Fe, Co, Ni, Cr, Mo)-B Melt spinning [18]
Al20Ce20La20Ni20Y20 Arc melting+the
melt-spun technique		 Potential-upsurge in the apparent activation energy of tensile creep [20]
Powder FeCoNiSi0.4Al0.4 As-cast dry-milling
process		 Nano-crystal and
nano-amorphous		 Tuning magnetic
properties		 [40]
Zr2.5FeNiSi0.4B0.6 MA method
(milling 180 h)		 Full amorphous High thermal stability [41]
Metal
matrix
composites		 Al0.6CoCrFeNi
HEA particle reinforced
Al65Cu16.5Ti18.5
amorphous alloy
composite		 Ball milling+SPS (Amorphous/nano-
crystalline)+
ID layer+(BCC+
FCC)		 Outstanding yield
strength & low
plasticity		 [42]
Table 1  高熵非晶合金的制备方法与特点
Material Corrosive environment Ecorr/V icorr/(A·cm-2) Rp/(kΩ·cm-2) Reference
VAlTiCrSi Artificial sea water -0.285 4.68×10-9 [49]
CuZrAlTiNiSi Seawater solution -1.140 6.21×10-4 [50]
Fe24Co24Ni24V6Si13B9 0.1 mol/L NaCl -0.400 5.21×10-6 [51]
Fe24Co24Ni24Cr6Si13B9 0.1 mol/L NaCl -0.270 1.25×10-6
Fe24Co24Ni24Mo6Si13B9 0.1 mol/L NaCl -0.490 3.70×10-5
Fe24Co24Ni24Nb6Si13B9 0.1 mol/L NaCl -0.380 4.89×10-6
Fe20Ni20Cr25Mo15(P, C, B)20 0.5 mol/L H2SO4 1.98×10-4 2.30×10-9 [30]
3%NaCl 0.77×10-4 3.80×10-9
1 mol/L HCl 2.26×10-4 7.30×10-9
(Fe, Co, Ni, Cr)80B20 0.1 mol/L H2SO4 -0.226 1.79×10-7 [52]
0.1 mol/L HCl -0.158 6.26×10-6
3.5%NaCl -0.153 3.66×10-7
FeSiBAlNiCo0.2 3.5%NaCl -1.370 1.04×10-7 [53]
FeSiBAlNiCo0.8 3.5%NaCl -0.860 4.79×10-7
Fe3Cr2Al2CuNi4Si5 3.5%NaCl -0.190 4.00×10-6 [28]
(FeCoNi)25(AlTiZr)75 3.5%NaCl -0.260 6.20×10-8 422.00 [32]
TiAlCrSiV 3.5%NaCl -0.541 6.14×10-6 11.36 [54]
V10.4Nb10.5Mo10.5Ta11.2
W10.5Cr16.3B28.6		 3.5%NaCl 0.060 1.50×10-7 172.80 [55]
SS 310 3.5%NaCl -0.310 1.36×10-6 19.12
45 steel 3.5%NaCl -0.712 3.72×10-6 7.62 [56]
SS 304 3.5%NaCl -0.282 1.69×10-7 [57]
SS 316L 3.5%NaCl -0.164 5.38×10-8
1Cr18Ni9Ti 3.5%NaCl -0.215 7.44×10-8
Q235 steel 3.5%NaCl -0.570 7.10×10-4 [58]
T10 steel Seawater solution -1.050 6.39×10-4 [50]
Table 2  高熵非晶合金与常见的钢铁材料电化学参数
Fig.1  样品在人工海水中极化实验后的表面形貌[49]
(a)304不锈钢；(b)VAlTiCrSi高熵非晶合金薄膜
Fig.2  Fe3Cr2Al2CuNi4Si5高熵非晶合金和304不锈钢在3.5%NaCl溶液中的电化学测试[28]
(a)动电位极化曲线；(b)Nyquist曲线
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