Abstract：Due to its large specific surface area, excellent penetration resistance and a large number of functional groups distributed on the surface, graphene oxide(GO) has become a research hotspot in the fields of anticorrosion, permeation separation and coating mechanical properties. The research progress of GO application on metal surface in recent years was reviewed. On the basis of domestic and foreign literature, the research progress of GO applied on metal surface for anticorrosion, permeation separation, mechanical properties of coating and other aspects was described, and the mechanism was summarized and analyzed. The anticorrosion mechanism is mainly the physical barrier effect of GO and its chemical inertness to the electroactive medium. The mechanism of osmotic separation is mainly the multi-layer pore structure and functional groups of GO. The main mechanism of mechanical properties of the coating is the good compatibility between GO and coating and the formation of chemical bond between surface functional groups and metal matrix. It was pointed out that there is still a lack of GO composite preparation technology that meets the requirements of environmental protection, low cost and large-scale industrialization, the technological parameters involved, the design of composite phase system and other aspects still need further study. It was also proposed to be applied to metal anticorrosion, oil-water separation and mechanical properties of coating, so as to solve the key problems such as corrosion resistance of metal surface, oil-water permeability and separation performance, bonding force between coating and metal substrate.
杜娟, 曹翔宇, 宋海鹏, 魏子明, 李香云, 杨涵清, 杨梓铭, 李伯阳, 李海龙. 氧化石墨烯在金属表面的应用及其机理研究进展[J]. 材料工程, 2021, 49(2): 32-41.
DU Juan, CAO Xiang-yu, SONG Hai-peng, WEI Zi-ming, LI Xiang-yun, YANG Han-qing, YANG Zi-ming, LI Bo-yang, LI Hai-long. Research progress in application of graphene oxide on metal surface and its mechanism. Journal of Materials Engineering, 2021, 49(2): 32-41.
 NOVOSELOV K S, GEIM A K, MOROZOV S V, et al. Two-dimensional gas of massless Dirac fermions in graphene[J].Nature, 2005, 438(7065):197-200.  NOVOSELOV K S, GEIM A K, MOROZOV S V, et al. Electric field effect in atomically thin carbon films[J].Science, 2004, 306(5696):666-669.  CHEN D, FENG H, LI J. Graphene oxide:preparation, functionalization, and electrochemical applications[J]. Chemical Reviews, 2012, 112(11):6027-6053.  CALI A, YA IZATLI Y,SAHIN A,et al. Highly durable phosphonated graphene oxide doped polyvinylidene fluoride (PVDF) composite membranes[J]. International Journal of Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2020.01.092.  KOWALIK-KLIMCZAK A,WOSKOWICZ E, KACPRZY ČŃ SKA-GOŁACKA J. The surface modification of polyamide membranes using graphene oxide[J].Colloids and Surfaces A,2020,587:124281.  MENG X X, FAN Y Y, ZHU J C, et al. Improving hydrogen permeation and interface property of ceramic-supported graphene oxide membrane via embedding of silicalite-1 zeolite into Al2O3 hollow fiber[J]. Separation and Purification Technology, 2019,227:115712.  HEGAB H M, ZOU L. Graphene oxide-assisted membranes:fabrication and potential applications in desalination and water purification[J].Journal of Membrane Science,2015,484:95-106.  NARAYANAM P K, SUNDARARAJAN K. Organic solvent supported fabrication of transparent free standing graphene oxide membranes[J]. Ceramics International,2020,46(4):5394-5401.  LIANG J F, WU X W, LING Y H, et al. Trilaminar structure hydrophobic graphene oxide decorated organosilane composite coatings for corrosion protection[J]. Surface & Coatings Technology, 2018,339:65-77.  KAVIMANI V, PRAKASH K S, GUNASHRI R, et al. Corrosion protection behaviour of r-GO/TiO2 hybrid composite coating on magnesium substrate in 3.5wt.% NaCl[J]. Progress in Organic Coatings, 2018, 125:358-364.  LALEH R R, SAVALONI H, ABDI F, et al. Corrosion inhibition enhancement of Al alloy by graphene oxide coating in NaCl solution[J]. Progress in Organic Coatings, 2019, 127:300-307.  GAO Y, SU K, WANG X, et al. A metal-nano GO frameworks/PPS membrane with super water flux and high dyes interception[J]. Journal of Membrane Science, 2019,574:55-64.  YE Y, ZHANG D, LI J, et al. One-step synthesis of superhydrophobic polyhedral oligomeric silsesquioxane-graphene oxide and its application in anti-corrosion and anti-wear fields[J]. Corrosion Science, 2019,147:9-21.  XIAO F J,QIAN C,GUO M Y, et al. Anticorrosive durability of zinc-based waterborne coatings enhanced by highly dispersed and conductive polyaniline/graphene oxide composite[J]. Progress in Organic Coatings, 2018, 125:79-88.  POURHASHEM S, RASHIDI A, VAEZI M R, et al. Excellent corrosion protection performance of epoxy composite coatings filled with amino-silane functionalized graphene oxide[J]. Surface & Coatings Technology, 2017, 317:1-9.  NING Y, TAO Y. Polydopamine modified polyaniline-graphene oxide composite for enhancement of corrosion resistance[J]. Journal of Hazardous Materials, 2019,377:142-151.  CHAUHANA D S, QURAISHIA M A, ANSARI K R, et al. Graphene and graphene oxide as new class of materials for corrosion control and protection:present status and future scenario[J]. Progress in Organic Coatings, 2020, 147:105741.  RYU S, KWON Y J, KIM Y, et al. Corrosion protection coating of three-dimensional metal structure by electrophoretic deposition of graphene oxide[J]. Materials Chemistry and Physics, 2020, 250:123039.  KAMIL M P, KIM M J, KO Y G. Direct electro-co-deposition of Ni-reduced graphene oxide composite coating for anti-corrosion application[J]. Materials Letters, 2020,273:127911.  MANDAL P, KIRAN U N, PATI S, et al. Investigation of the effects of electrophoretic deposition parameters on 304SS steel coated with graphene oxide for PEMFC application[J]. Materials Today:Proceedings, 2020,26:654-659.  HO C Y, HUANG S M,LEE S T,et al. Evaluation of synthesized graphene oxide as corrosion protection film coating on steel substrate by electrophoretic deposition[J]. Applied Surface Science, 2019,477:226-231.  PARK J H, PARK J M. Electrophoretic deposition of graphene oxide on mild carbon steel for anti-corrosion application[J]. Surface & Coatings Technology, 2014,254:167-174.  RAMEZANZADEH B, NIROUMANDRAD S, AHMADI A, et al. Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide[J]. Corrosion Science, 2016, 103:283-304.  LIU Q, MA R, DU A, et al. Investigation of the anticorrosion properties of graphene oxide doped thin organic anticorrosion films for hot-dip galvanized steel[J]. Applied Surface Science, 2019, 480:646-654.  LIU J, YU Q, YU M, et al. Silane modification of titanium dioxide-decorated graphene oxide nanocomposite for enhancing anticorrosion performance of epoxy coatings on AA-2024[J]. Journal of Alloys and Compounds, 2018, 744:728-739.  HAYATGHEIB Y, RAMEZANZADEH B, KARDAR P, et al. A comparative study on fabrication of a highly effective corrosion protective system based on graphene oxide-polyaniline nanofibers/epoxy composite[J]. Corrosion Science, 2018, 133:358-373.  NIKPOUR B, RAMEZANZADEH B, BAHLAKEH G, et al. Synthesis of graphene oxide nanosheets functionalized by green corrosion inhibitive compounds to fabricate a protective system[J]. Corrosion Science, 2017, 127:240-259.  RAMEZANZADEH B, BAHLAKEH G, RAMEZANZADEH M. Polyaniline-cerium oxide (PAni-CeO2) coated graphene oxide for enhancement of epoxy coating corrosion protection performance on mild steel[J].Corrosion Science,2018,137:111-126.  DING R, LI W, WANG X, et al. A brief review of corrosion protective films and coatings based on graphene and graphene oxide[J]. Journal of Alloys and Compounds, 2018, 764:1039-1055.  NAYAK S R, MOHANA K N S. Corrosion protection performance of functionalized graphene oxide nanocomposite coating on mild steel[J]. Surfaces and Interfaces,2018,11:63-73.  LI J, ALI S J. In-situ electrodeposition of conductive polypyrrole-graphene oxide composite coating for corrosion protection of 304SS bipolar plates[J]. Journal of Alloys and Compounds,2019,770:35-47.  LI J, CUI J. Silanized graphene oxide reinforced organofunctional silane composite coatings for corrosion protection[J]. Progress in Organic Coatings, 2016, 99:443-451.  GUPTA A, SRIVASTAVA C. Optimum amount of graphene oxide for enhanced corrosion resistance by tin-graphene oxide composite coatings[J]. Thin Solid Films, 2018, 661:98-107.  ANSARI K R, CHAUHAN D S, QURAISHI M A, et al. Bis(2-aminoethyl)amine-modified graphene oxide nanoemulsion for carbon steel protection in 15% HCl:effect of temperature and synergism with iodide ions[J]. Journal of Colloid and Interface Science, 2020, 564:124-133.  AZAR M M K, GUGTAPEH H S, REZAEI M.Evaluation of corrosion protection performance of electroplated zinc and zinc-graphene oxide nanocomposite coatings in air saturated 3.5 wt.% NaCl solution[J]. Colloids and Surfaces A, 2020, 601:125051.  ZHOU S,WU Y,ZHAO W,et al. Designing reduced graphene oxide/zinc rich epoxy composite coatings for improving the anticorrosion performance of carbon steel substrate[J]. Materials & Design, 2019,169:107694.  GUPTA A, SRIVASTAVA C. Enhanced corrosion resistance by SnCu-graphene oxide composite coatings[J]. Thin Solid Films, 2019, 669:85-95.  LI H, YIN Y Y, ZHU L, et al. A hierarchical structured steel mesh decorated with metal organic framework/graphene oxide for high-efficient oil/water separation[J]. Journal of Hazardous Materials, 2019, 373:725-732.  ABHIJIT G, JYOTI K T, KALYAN R, et al. Water and salt dynamics in multilayer graphene oxide (GO) membrane:role of lateral sheet dimensions[J]. Journal of Membrane Science, 2018, 563:785-793.  BABAK J, KOSAR S. Uniform and stable electrophoretic deposition of graphene oxide on steel mesh:low temperature thermal treatment for switching from superhydrophilicity to superhydrophobicity[J]. Colloids and Surfaces A, 2019, 577:323-332.  HAN J L, ZHANG D, JIANG W, et al. Tuning the functional groups of a graphene oxide membrane by·OH contributes to the nearly complete prevention of membrane fouling[J]. Journal of Membrane Science, 2019,576:190-197.  KIM J, LEE S E,SEO S,et al. Near-complete blocking of multivalent anions in graphene oxide membranes with tunable interlayer spacing from 3.7 to 8.0 angstrom[J]. Journal of Membrane Science, 2019,592:117394.  YIN Y Y, HUI L. A durable mesh decorated with polydopamine/graphene oxide for highly efficient oil/water mixture separation[J]. Applied Surface Science, 2019, 479:351-359.  MASUMEH F, HOJAT Z. Investigation of water-oil separation via graphene oxide membranes:a molecular dynamics study[J]. Colloids and Surfaces A,2018,555:201-208.  BORGES D D, WOELLNER C F, AUTRETO P A S, et al. Insights on the mechanism of water-alcohol separation in multilayer graphene oxide membranes:entropic versus enthalpic factors[J]. Carbon:An International Journal Sponsored by the American Carbon Society,2018,127:280-286.  POURHASHEM S, VAEZI M R, RASHIDI A. Investigating the effect of SiO2-graphene oxide hybrid as inorganic nanofiller on corrosion protection properties of epoxy coatings[J]. Surface & Coatings Technology, 2017, 311:282-294.  ÖZKAN D, ERARSLAN Y, KINCAL C, et al. Wear and corrosion resistance enhancement of chromium surfaces through graphene oxide coating[J]. Surface & Coatings Technology, 2020, 391:125595.  LUÉVANO-CABRALES O L, ALVAREZ-VERA M, HDZ-GARCÍA H M, et al. Effect of graphene oxide on wear resistance of polyester resin electrostatically deposited on steel sheets[J]. Wear, 2019, 426/427:296-301.  PARHIZKAR N, SHAHRABI T, RAMEZANZADEH B. A new approach for enhancement of the corrosion protection properties and interfacial adhesion bonds between the epoxy coating and steel substrate through surface treatment by covalently modified amino functionalized graphene oxide film[J]. Corrosion Science, 2017,123:55-75.  PARHIZKAR N, RAMEZANZADEH B, SHAHRABI T. Corrosion protection and adhesion properties of the epoxy coating applied on the steel substrate pre-treated by a sol-gel based silane coating filled with amino and isocyanate silane functionalized graphene oxide nanosheets[J]. Applied Surface Science, 2018, 439:45-59.  PARHIZKAR N, SHAHRABI T, RAMEZANZADEH B. Steel surface pre-treated by an advance and eco-friendly cerium oxide nanofilm modified by graphene oxide nanosheets; electrochemical and adhesion measurements[J]. Journal of Alloys and Compounds, 2018, 747:109-123.  POURHASHEM S, VAEZI M R, RASHIDI A, et al. Exploring corrosion protection properties of solvent based epoxy-graphene oxide nanocomposite coatings on mild steel[J]. Corrosion Science, 2017, 115:78-92.  RAMEZANZADEH B, AHMADI A, MANDAVIAN M. Enhancement of the corrosion protection performance and cathodic delamination resistance of epoxy coating through treatment of steel substrate by a novel nanometric sol-gel based silane composite film filled with functionalized graphene oxide nanosheets[J]. Corrosion Science, 2016, 109:182-205.  HOLMBERG K, KIVIKYTO-REPONEN P, HARKISAARI P, et al. Global energy consumption due to friction and wear in the mining industry[J].Tribology International,2017,115:116-139.  RUIZ V, YATE L, LANGER J, et al. PEGylated carbon black as lubricant nanoadditive with enhanced dispersion stability and tribological performance[J].Tribology International,2019,137:228-235.  PANG W C, NI Z F, WU J L, et al. Investigation of tribological properties of graphene oxide reinforced ultrahigh molecular weight polyethylene under artificial seawater lubricating condition[J]. Applied Surface Science, 2018, 434:273-282.  SINGH S, CHEN X, ZHANG C, et al. Investigation on the lubrication potential of graphene oxide aqueous dispersion for self-mated stainless steel tribo-pair[J].Vacuum,2019,166:307-315.  GAN C, LIANG T, LI W, et al. Hydroxyl-terminated ionic liquids functionalized graphene oxide with good dispersion and lubrication function[J]. Tribology International, 2020,148:106350.  LIANG H, XU M, BU Y, et al. Confined interlayer water enhances solid lubrication performances of graphene oxide films with optimized oxygen functional groups[J]. Applied Surface Science, 2019, 485:64-69.  LIU Y, ZHENG F, WU Y X, et al. Grain refinement induced friction reduction and anti-wear performances of electrodeposited graphene/Ni composites with low content reduced graphene oxide[J]. Journal of Alloys and Compounds, 2020, 826:154080.  SHUANG Y, LI J, ZHU J, et al. Investigation of machining Ti-6Al-4V with graphene oxide nanofluids:tool wear, cutting forces and cutting vibration[J]. Journal of Manufacturing Processes, 2019, 49:35-49.