相变储湿复合材料及其应用研究进展

doi:10.11868/j.issn.1001-4381.2020.000792

摘要
图/表
参考文献
相关文章
Metrics

全文: PDF(5793 KB)

HTML ( 0 )
输出: BibTeX | EndNote (RIS)

摘要

人类在面临化石能源枯竭的同时，对能量的利用率依然还停留在较低的水平。因此，在大力发展新能源的同时，着力研发具有"自身被动调节能力"的新材料具有十分重要的意义。相变储湿复合材料是一种具有相变调温性能和储湿调湿性能的复合材料，它在建筑墙体材料领域具有大规模商业应用的潜力。本文首先对相变储湿复合材料的作用原理、相变材料的封装技术、调湿材料的分类与选择等方面作了简要的介绍；并就相变储湿复合材料在建筑墙体材料中的应用情况进行了具体的分析，详细指出了双壳微纳米相变胶囊、多元脂肪酸/SiO₂相变储湿复合材料和癸酸-棕榈酸@Ce-La/TiO₂复合材料的特点，详细评述了相变储湿复合材料存在的主要问题及其研究现状。在此基础上，指出优化相变储湿复合材料的耐久性、开发多功能型相变储湿复合材料是相变储湿复合材料未来的主要发展方向。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	张浩
	臧君杰
	李海丽
	宗志芳

关键词 ：相变储湿复合材料, 相变调温性能, 储湿调湿性能, 建筑墙体材料, 节能

Abstract：

Currently, the utilization efficiency of energy still remains at low level, although the depletion of fossil fuel is approaching. Therefore, while vigorously developing new energy, it is of great significance to develop new materials with "passive self-adjustment ability". Phase change humidity storage composite materials is a kind of composite material with phase change and temperature controlling property and humidity storage and humidity controlling property, which are very promising in the field of building wall material. In this paper, the action principle of phase change humidity storage composite materials, packaging technique of phase change material, classification and selection of humidity-controlling material were introduced briefly in the first section. And then the application of phase change humidity storage composite materials in building wall material were reviewed and analyzed in detail. In the third part, characteristics of double-shell phase change micro-nano capsules, polyfatty acid/SiO₂ phase change and humidity storage composite materials and decanoic acid-palmitic acid @ Ce-La/TiO₂ composites were pointed out. Main problems and research status of phase change humidity storage composite materials were pointed. Finally, it was pointed out the optimized durability of phase change humidity storage composite materials, developing multi-functional phase change humidity storage composite materials are the main development directions of phase change humidity storage composite materials.

Key words： phase change humidity storage composite materials phase change and temperature controlling property humidity storage and humidity controlling property building wall material energy saving

收稿日期: 2020-08-20 出版日期: 2021-05-21

中图分类号:

TK11

基金资助:国家自然科学基金青年基金资助项目(51206002);中国博士后科学基金资助项目(2017M612051);高校优秀青年骨干人才国外访学研修项目(gxgwfx2018021);安徽省博士后研究人员科研活动经费资助项目(2017B168)

通讯作者: 张浩 E-mail: fengxu19821018@163.com

作者简介: 张浩(1982-), 男, 博士, 副教授, 研究方向为环保型建筑节能材料研究, 联系地址: 安徽省马鞍山市雨山区安徽工业大学(东校区)建筑工程学院(243032), fengxu19821018@163.com

引用本文:

张浩, 臧君杰, 李海丽, 宗志芳. 相变储湿复合材料及其应用研究进展[J]. 材料工程, 2021, 49(5): 56-65.
Hao ZHANG, Jun-jie ZANG, Hai-li LI, Zhi-fang ZONG. Research status and application of phase change humidity storage composite materials. Journal of Materials Engineering, 2021, 49(5): 56-65.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2020.000792 或 http://jme.biam.ac.cn/CN/Y2021/V49/I5/56

Fig.1 相变储湿复合材料原理图

Table 1 相变微胶囊性能

Fig.2 双壳微纳米相变胶囊的FTIR(a)与SEM(b)测试结果^[41]

Table 2 石膏基双壳微纳米相变胶囊复合材料的储放热性能^[41]

Fig.3 石膏基双壳微纳米相变胶囊复合材料的吸放湿性能^[41] (a)吸湿过程; (b)放湿过程

Fig.4 癸酸-棕榈酸/SiO₂相变储湿复合材料的SEM(a)与LPSA(b)测试结果^[44]

Fig.5 石膏基相变储湿复合材料的性能^[43]
(a)步冷曲线; (b)吸湿过程的平衡含湿量; (c)放湿过程的平衡含湿量

Fig.6 癸酸-棕榈酸@Ce-La/TiO₂复合材料的SEM(a)与吸附/脱附等温(b)测试结果^[48]

Fig.7 癸酸-棕榈酸@Ce-La/TiO₂复合材料用于面层抹灰石膏的性能协同示意图^[48-49]

1	HUYNH C K . Building energy saving techniques and indoor air quality: a dilemma[J]. International Journal of Ventilation, 2010, 9 (1): 93- 98. doi: 10.1080/14733315.2010.11683872
2	BAUGHMAN A X , ARENS A E . Indoor humidity and human health: part1 literature review of health effects of humidity-influenced indoor pollutants[J]. ASHRAE Transactions, 1996, 102 (1): 193- 198.
3	ZHU N , MA Z J , WANG S W . Dynamic characteristics and energy performance of buildings using phase change materials: a review[J]. Energy Conversion and Management, 2009, 50 (12): 3169- 3181. doi: 10.1016/j.enconman.2009.08.019
4	DENG A Z , LI S B , ZHUANG C L , et al. Research on lightweight PCM thermal-storing wall-material[J]. Journal of Building Materials, 2008, 11 (5): 541- 544.
5	ZHANG H , FANG Y . Temperature dependent photoluminescence of surfactant assisted electrochemically synthesized ZnSe nanostructures[J]. Journal of Alloys and Compounds, 2019, 781, 201- 208. doi: 10.1016/j.jallcom.2018.11.375
6	尚建丽, 张浩. 相变蓄能材料在建筑中应用现状与展望[J]. 化工新型材料, 2014, 42 (9): 197- 199.
6	SHANG J L , ZHANG H . Application situation and prospect of phase change thermal energy storage materials in building[J]. New Chemical Materials, 2014, 42 (9): 197- 199.
7	尚燕, 张雄. 新型相变储能技术的应用与发展[J]. 建筑节能, 2006, 34 (2): 21- 23.
7	SHANG Y , ZHANG X . Application and development on the technology of phase change energy storage[J]. Construction Conserves Energy, 2006, 34 (2): 21- 23.
8	RUBEN B , ARILD G . Phase change materials for building applications: a state-of-the-art review[J]. Energy and Buildings, 2010, 42, 1361- 1368. doi: 10.1016/j.enbuild.2010.03.026
9	MONDAL S . Phase change materials for smart textiles-an overview[J]. Applied Thermal Engineering, 2008, 28 (11/12): 1536- 1550.
10	HUANG M J , EAMES P C , HEWITT N J . The application of a validated numerical model to predict the energy conservation potential of using phase change materials in the fabric of a building[J]. Solar Energy Materials & Solar Cells, 2006, 90 (13): 1951- 1960.
11	YOSHINARI T , HIROSHI Y , HIDEO K , et al. Preparation of PCM microencapsules by using oil absorbable polymer particles[J]. Colloids and Surfaces A, 2007, 301 (1-3): 41- 47. doi: 10.1016/j.colsurfa.2006.12.019
12	CHO J S , KWON A , CHO C G . Micro encapsulation of octadecane as a phase-change material by interfacial polymerization in an emulsion system[J]. Colloid and Polymer Science, 2002, 280 (3): 260- 266. doi: 10.1007/s00396-001-0603-x
13	CEMIL A , SAN A , KARAIPEKLI A , et al. Preparation characterization and thermal properties of micro-encapsulated phase change material for thermal storage[J]. Solar Energy Material & Solar Cells, 2009, 93 (1): 143- 147.
14	HE F , WANG X D , WU D Z . New approach for sol-gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor[J]. Energy, 2014, 67 (4): 223- 233.
15	OANA P , RICARD G V , MARTA G . Interfacial polymerization of an epoxy resin and carboxylic acids for the synthesis of micro-capsules[J]. Polymer International, 2008, 57 (8): 995- 1006. doi: 10.1002/pi.2438
16	陈春明, 陈中华, 曾幸荣. 细乳液聚合法制备正十二醇/聚合物相变纳米胶囊及其性能研究[J]. 功能材料, 2011, 11 (42): 2112- 2115.
16	CHEN C M , CHEN Z H , ZENG X R . Synthesis and characterization of dodecanol/polymer phase change nanocapsules via miniemulsion polymerization[J]. Journal of Functional Materials, 2011, 11 (42): 2112- 2115.
17	余飞, 陈中华, 曾幸荣. 正十二醇相变储热微胶囊的制备与表征[J]. 高分子材料科学与工程, 2009, 25 (6): 135- 138. doi: 10.3321/j.issn:1000-7555.2009.06.038
17	YU F , CHEN Z H , ZENG X R . Preparation and characterization of thermal energy storage microcapsulated n-dodecanol by phase change[J]. Polymer Materials Science & Engineering, 2009, 25 (6): 135- 138. doi: 10.3321/j.issn:1000-7555.2009.06.038
18	单晓辉, 裴广玲, 付中玉. 乳液聚合法制备正十八烷相变材料微胶囊[J]. 天津纺织科技, 2011, (1): 25- 27.
18	SHAN X H , PEI G L , FU Z Y . Preparation of microPCMs by coating n-octadecane with emulsion polymerization[J]. Tianjin Textile Science & Technology, 2011, (1): 25- 27.
19	林怡辉, 张正国, 王世平. 溶胶-凝胶法制备新型蓄能复合材料[J]. 太阳能学报, 2001, 22 (3): 334- 336. doi: 10.3321/j.issn:0254-0096.2001.03.019
19	LIN Y H , ZHANG Z G , WANG S P . Sol-gel process for new heat storage composite materials preparation[J]. Acta Energiae Solaris Sinica, 2001, 22 (3): 334- 336. doi: 10.3321/j.issn:0254-0096.2001.03.019
20	尚燕, 张雄. 相变储能材料应用研究[J]. 西华大学学报(自然科学版), 2005, 24 (2): 87- 90. doi: 10.3969/j.issn.1673-159X.2005.02.025
20	SHANG Y , ZHANG X . Study progress on phase change energy storage materials[J]. Sichuan University of Science and Technology, 2005, 24 (2): 87- 90. doi: 10.3969/j.issn.1673-159X.2005.02.025
21	凌双梅, 高学农, 尹辉斌. 低温相变蓄热材料研究进展[J]. 广东化工, 2007, 34 (3): 48- 51. doi: 10.3969/j.issn.1007-1865.2007.03.016
21	LING S M , GAO X N , YIN H B . State-of-the-art of PCMs for heat storage at low temperature[J]. Guangdong Chemical Industry, 2007, 34 (3): 48- 51. doi: 10.3969/j.issn.1007-1865.2007.03.016
22	宋婧, 曾令可, 刘平安, 等. 蓄热材料中的纳米技术[J]. 中国陶瓷工业, 2007, 14 (5): 35- 38. doi: 10.3969/j.issn.1006-2874.2007.05.010
22	SONG J , ZENG L K , LIU P A , et al. Nano technology applied in heat storage materials[J]. China Ceramic Industry, 2007, 14 (5): 35- 38. doi: 10.3969/j.issn.1006-2874.2007.05.010
23	ZHANG Z G , ZHANG N , PENG J , et al. Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material[J]. Applied Energy, 2012, 91, 426- 431. doi: 10.1016/j.apenergy.2011.10.014
24	仇影, 吴其胜, 黎水平, 等. 二元有机/煤系高岭土复合相变储能材料的制备及其热性能[J]. 材料科学与工程学报, 2013, 31 (2): 269- 272.
24	QIU Y , WU Q S , LI S P , et al. Preparation and thermal properties of binary organic/kaolin composites as shape-stabilized phase change material for thermal energy storage[J]. Journal of Materials Science and Engineering, 2013, 31 (2): 269- 272.
25	李玉红, 焦庆影, 夏定国, 等. 常低温相变储热材料的研究和应用[J]. 化学教育, 2004, 25 (10): 9- 13. doi: 10.3969/j.issn.1003-3807.2004.10.004
25	LI Y H , JIAO Q Y , XIA D G , et al. The study and applications of normal and low temperature phase change and heat storage materials[J]. Journal of Chemical Education, 2004, 25 (10): 9- 13. doi: 10.3969/j.issn.1003-3807.2004.10.004
26	姜勇, 丁恩勇, 黎国康. 化学法和共混法制备的PEG/CDA相变材料的性能比较-储热性能与链结构的关系[J]. 纤维素科学与技术, 2000, 8 (1): 17- 25. doi: 10.3969/j.issn.1004-8405.2000.01.003
26	JIANG Y , DING E Y , LI G K . Contrast studies on phase change materials of PEG/CDA prepared by chemical reactions or blendings-relationships between heat storage properties and structures[J]. Journal of Cellulose Science and Technology, 2000, 8 (1): 17- 25. doi: 10.3969/j.issn.1004-8405.2000.01.003
27	周建伟, 刘星. 相变储能材料的研究及应用新进展[J]. 河南化工, 2004, (10): 7- 10. doi: 10.3969/j.issn.1003-3467.2004.10.003
27	ZHOU J W , LIU X . New progress on research and application of phase change energy storage materials[J]. Henan Chemical Industry, 2004, (10): 7- 10. doi: 10.3969/j.issn.1003-3467.2004.10.003
28	INADA H , YONEDA A , HORIBE A , et al. High density polyethylene as a thermal energy storage materials[J]. Nippon Kikai Gakkai Ronbunshu B, 1997, 63 (605): 282- 289.
29	施韬, 孙伟, 王倩楠. 凹凸棒土吸附相变储能复合材料制备及其热物理性能表征[J]. 复合材料学报, 2009, 26 (5): 143- 147. doi: 10.3321/j.issn:1000-3851.2009.05.023
29	SHI T , SUN W , WANG Q N . Study on preparation and thermal performance tests of attapulgite-based phase change composites for energy storage[J]. Acta Materiae Compositae Sinica, 2009, 26 (5): 143- 147. doi: 10.3321/j.issn:1000-3851.2009.05.023
30	FANG X M , ZHANG Z G , CHEN Z H . Study on preparation of montmorillonite-based composite phase change materials and their applications in thermal storage building materials[J]. Energy Conversion and Management, 2008, 49 (4): 718- 723. doi: 10.1016/j.enconman.2007.07.031
31	黄沛增. 被动式绿色调湿材料性能的试验研究[D]. 西安: 西安建筑科技大学, 2007.
31	HUANG P Z. Properties of passive green humidity-controlling materials[D]. Xi'an: Xi'an University of Architecture And Technology, 2007.
32	栾聪梅. 石膏基自调湿材料的制备与性能[D]. 武汉: 武汉理工大学, 2008.
32	LUAN C M. The preparation and performance of gypsum-based humidity controlling materials[D]. Wuhan: Wuhan University of Technology, 2008.
33	邓妮. 多孔矿物基复合调湿材料的制备及性能[D]. 杭州: 浙江大学, 2014.
33	DENG N. Preparation and performance of composite humidity control materials based on porous minerals[D]. Hangzhou: Zhejiang University, 2014.
34	马斌齐. 调湿建筑材料调节室内湿环境的机理和评价指标研究[D]. 西安: 西安建筑科技大学, 2007.
34	MA B Q. Research on humidity controlling material adjustment room humidity environment mechanism and appraisal target[D]. Xi'an: Xi'an University of Architecture and Technology, 2007.
35	邓妮, 武双磊, 陈胡星. 调湿材料的研究概述[J]. 材料导报, 2013, 27 (增刊2): 368- 371.
35	DENG N , WU S L , CHEN H X . Overview on research of humidity-controlling materials[J]. Materials Review, 2013, 27 (Suppl 2): 368- 371.
36	蒋正武. 调湿材料的研究进展[J]. 材料导报, 2001, 20 (10): 8- 11.
36	JIANG Z W . Research progress of humidity-controlling materials[J]. Materials Review, 2001, 20 (10): 8- 11.
37	吴宏伟. 住宅外窗遮阳与调湿材料节能实验研究[D]. 重庆: 重庆大学, 2009.
37	WU H W. Hygroscopic materials' energy-saving[D]. Chongqing: Chongqing University, 2009.
38	尚建丽, 王思, 董莉. PAR/POL/SOD复合微胶囊的制备及热湿性能研究[J]. 功能材料, 2013, 44 (8): 1- 5.
38	SHANG J L , WANG S , DONG L . Prepared of PAR/POL/SOD-composite-wall microencapsulated and research of energy[J]. Journal of Functional Materials, 2013, 44 (8): 1- 5.
39	尚建丽, 董莉. 双壳微纳胶囊的制备及热湿性能的试验研究[J]. 建筑材料学报, 2015, 18 (3): 428- 432. doi: 10.3969/j.issn.1007-9629.2015.03.012
39	SHANG J L , DONG L . Preparation of double-shell micronano-capsule and its thermal and moisture performance[J]. Journal of Building Materials, 2015, 18 (3): 428- 432. doi: 10.3969/j.issn.1007-9629.2015.03.012
40	尚建丽, 张浩, 董莉, 等. 双壳微纳米相变胶囊/石膏复合材料等温吸放湿特性及机理研究[J]. 功能材料, 2015, 46 (2): 2084- 2088. doi: 10.3969/j.issn.1001-9731.2015.02.018
40	SHANG J L , ZHANG H , DONG L , et al. Study on isothermal sorption property and mechanism of gypsum-based composite with double-shell phase change micro-nano capsules[J]. Journal of Functional Materials, 2015, 46 (2): 2084- 2088. doi: 10.3969/j.issn.1001-9731.2015.02.018
41	尚建丽, 张浩, 董莉. 石膏基双壳微纳米相变胶囊复合材料制备及调温调湿性能研究[J]. 太阳能学报, 2016, 37 (6): 1481- 1487. doi: 10.3969/j.issn.0254-0096.2016.06.018
41	SHANG J L , ZHANG H , DONG L . Preparation of composite material of gypsum-based double-shell micro-nano phase change capsules and performance research of temperature-humidity control[J]. Acta Energiae Solaris Sinica, 2016, 37 (6): 1481- 1487. doi: 10.3969/j.issn.0254-0096.2016.06.018
42	尚建丽, 张浩, 熊磊, 等. 基于傅里叶红外光谱的癸酸-棕榈酸/SiO₂相变储湿复合材料制备机理研究[J]. 光谱学与光谱分析, 2016, 36 (6): 1690- 1695.
42	SHANG J L , ZHANG H , XIONG L , et al. Study on preparation mechanism of decanoic acid-palmitic acid/SiO₂ phase change and humidity storage composite materials by Fourier transform infrared spectrum[J]. Spectroscopy and Spectral Analysis, 2016, 36 (6): 1690- 1695.
43	张浩, 黄新杰, 刘秀玉, 等. 癸酸-棕榈酸-SiO₂/石膏相变储湿复合材料的制备及性能[J]. 复合材料学报, 2017, 34 (2): 406- 413.
43	ZHANG H , HUANG X J , LIU X Y , et al. Preparation and comprehensive performance of decanoic acid-palmitic acid-SiO₂/gypsum phase change and humidity storage composites[J]. Acta Materiae Compositae Sinica, 2017, 34 (2): 406- 413.
44	张浩. 建筑相变储湿材料的制备、热湿性能及应用模拟研究[D]. 西安: 西安建筑科技大学, 2016.
44	ZHANG H. Preparation, thermal-humidity property and application simulation of phase change and humidity storage materials[D]. Xi'an: Xi'an University of Architecture and Technology, 2016.
45	张浩, 黄新杰, 刘秀玉, 等. 优化制备棕榈醇-棕榈酸-月桂酸/SiO₂复合相变调湿材料[J]. 材料研究学报, 2015, 29 (9): 671- 678.
45	ZHANG H , HUANG X J , LIU X Y , et al. Optimization for preparation of phase change and humidity control composite materials of hexadecanol-palmitic acid-lauric acid/SiO₂[J]. Chinese Journal of Materials Research, 2015, 29 (9): 671- 678.
46	SHANG J L , ZONG Z F , ZHANG H . Synthesis and analysis of new humidity-controlling composite materials[J]. International Journal of Minerals, Metallurgy and Materials, 2017, 24 (5): 594- 602. doi: 10.1007/s12613-017-1441-2
47	宗志芳, 杨麟, 熊磊, 等. 环境协调型Ce-La/TiO₂复合材料的制备及光-湿-热性能[J]. 材料工程, 2018, 46 (5): 145- 150.
47	ZONG Z F , YANG L , XIONG L , et al. Preparation of environment coordination Ce-La/TiO₂ composites and photocatalytic-moisture-heat properties[J]. Journal of Materials Engineering, 2018, 46 (5): 145- 150.
48	宗志芳. 建筑多功能复合材料的制备及光-热-湿协同性能研究[D]. 西安: 西安建筑科技大学, 2018.
48	ZONG Z F. Preparation of construction multi-functional composites and photocatalysis-heat-moisture property study[D]. Xi'an: Xi'an University of Architecture and Technology, 2018.
49	ZHANG H . Magnetic properties and thermal stability of SrFe₁₂O₁₉/gamma-Fe₄N composites with effective magnetic exchange coupling[J]. Ceramics International, 2020, 46 (7): 9972- 9977.
50	ZHANG Z , ZHANG N , PENG J , et al. Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material[J]. Applied Energy, 2012, 91, 426- 431.
51	WU W , ZHANG G Q , KE X , et al. Preparation and thermal conductivity enhancement of composite phase change materials for electronic thermal management[J]. Energy Conversion and Management, 2015, 101, 278- 284.
52	GOLI P , LEGEDZA S , DHAR A , et al. Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries[J]. Journal of Power Sources, 2014, 248, 37- 43.
53	SAMIMI F , BABAPOOR A , AZIZI M , et al. Thermal management analysis of a Li-ion battery cell using phase change material loaded with carbon fibers[J]. Energy, 2016, 96, 355- 371.
54	HUSSAIN A , ABIDI I H , TSO C Y , et al. Thermal management of lithium ion batteries using graphene coated nickel foam saturated with phase change materials[J]. International Journal of Thermal Sciences, 2018, 124, 23- 35.
55	NAIK S P , CHIANG A S , THOMPSON R . Synthesis of zeolitic mesoporous materials by dry gel conversion under controlled humidity[J]. The Journal of Physical Chemistry B, 2003, 107 (29): 7006- 7014.
56	GONZALEZ J C , MOLINA-SABIO M , RODRIGUEZ-REINOSO F . Sepiolite-based adsorbents as humidity controller[J]. Applied Clay Science, 2001, 20 (3): 111- 115.
57	GAO N F , KUME S , WATARI K . Carbon composites prepared from industrial wastes: (Ⅰ) effects of processing parameters[J]. Materials Science & Engineering A, 2005, 404 (122): 274- 281.
58	LI B X , LIU T X , HU L Y , et al. Fabrication and properties of microencapsulated paraffin@SiO₂ phase change composite for thermal energy storage[J]. ACS Sustainable Chemistry & Engineering, 2013, 1 (3): 374- 380.
59	FANG G Y , CHEN Z , LI H . Synthesis and properties of microencapsulated paraffin composites with SiO₂ shell as thermal energy storage materials[J]. Chemical Engineering Journal, 2010, 163 (1/2): 154- 159.
60	WANG L Y , TSAI P S , YANG Y M . Preparation of silica microspheres encapsulating phase-change material by sol-gel method in O/W emulsion[J]. Microencapsule, 2006, 23 (1): 3- 14.

[1]	陈颖, 姜庆辉, 辛集武, 李鑫, 孙兵杨, 杨君友. 相变储能材料及其应用研究进展[J]. 材料工程, 2019, 47(7): 1-10.
[2]	宗志芳, 杨麟, 张浩, 熊磊. 环境协调型Ce-La/TiO₂复合材料的制备及光-湿-热性能[J]. 材料工程, 2018, 46(5): 145-150.

Viewed

Full text

Abstract

Cited

Shared

Discussed