Fe基非晶合金粉末的研究进展

doi:10.11868/j.issn.1001-4381.2020.000953

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摘要

非晶合金粉末是指快冷雾化合金液滴所制得的合金粉末，其中Fe基非晶合金粉末因具有生产成本低廉和应用前景广阔等优势，一直备受青睐。同时，Fe基非晶合金粉末的应用也为块体Fe基非晶合金应用难的问题提供了一条崭新的途径。本文综述了Fe基非晶合金粉末的研究进展，对其在涂层制备、磁性材料、激光3D打印、废水处理4个方面的研究现状进行了归纳分类与总结，并分析了Fe基非晶合金粉末在各领域的应用优势。最后指出Fe基非晶合金粉末在制备高质量涂层、老化磁性粉末再利用及增材制造领域的研究方向，并展望了作为传感、控制等功能性器件的应用前景。此外，在薄膜等小尺寸、低维材料及柔性电子领域也展现出巨大的应用潜力。

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	王海博
	李春燕
	李金玲
	王顺平
	寇生中

关键词 ： Fe基非晶合金粉末, 涂层制备, 磁性材料, 激光3D打印, 废水处理

Abstract：

Amorphous alloy powder can be obtained by rapid cooling atomization of certain alloy droplets. Fe-based amorphous alloy powder has been favored because of its low production cost and wide application range. Moreover, the application of Fe-based amorphous alloy powder provides a new solution for the application of bulk Fe-based amorphous alloys.The research progress of Fe-based amorphous alloy powder was reviewed, and its research status was summarized in four aspects: coating preparation, magnetic materials, laser 3D printing, and wastewater treatment. The advantages of Fe-based amorphous alloy powder in various fields were analyzed, and the research directions of Fe-based amorphous alloy powder in the fields of preparing high-quality coatings, reuse of aging magnetic powders and additive manufacturing were pointed out. Moreover, the application prospects of Fe-based amorphous alloy powder as sensing, control and other functional devices were prospected.In addition, it also shows great application potential in the fields of small size, low dimentional materials such as thin films and flexible electronics.

Key words： Fe-based amorphous alloy powder coating preparation magnetic material laser 3D printing wastewater treatment

收稿日期: 2020-10-15 出版日期: 2021-04-21

中图分类号:

TG139⁺8

基金资助:国家自然科学基金资助项目(51861021);国家自然科学基金资助项目(51661016);国家自然科学基金资助项目(51571105)

通讯作者: 李春燕 E-mail: licywz@163.com

作者简介: 李春燕(1979-), 女, 教授, 博士, 主要从事非晶态合金涂层的制备及性能研究, 联系地址: 甘肃省兰州市七里河区兰工坪路287号兰州理工大学材料科学与工程学院(730000), E-mail: licywz@163.com

引用本文:

王海博, 李春燕, 李金玲, 王顺平, 寇生中. Fe基非晶合金粉末的研究进展[J]. 材料工程, 2021, 49(4): 34-51.
Hai-bo WANG, Chun-yan LI, Jin-ling LI, Shun-ping WANG, Sheng-zhong KOU. Research progress in Fe-based amorphous alloy powder. Journal of Materials Engineering, 2021, 49(4): 34-51.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2020.000953 或 http://jme.biam.ac.cn/CN/Y2021/V49/I4/34

Table 1 非晶合金涂层、钢和某些耐磨涂层的摩擦学性能总结

Fig.1 非晶合金涂层在6 mol/L NaCl溶液浸泡不同时间的TEM腐蚀形貌^[16] (a)1 h; (b)2 h

Fig.2 Fe基非晶合金涂层点蚀发生过程的原理图^[16]

Fig.3 喷涂后涂层中析出的纳米晶^[20]

Fig.4 非晶涂层、Al₂O₃增强的非晶复合涂层和316L不锈钢在3.5% NaCl溶液中的摩擦腐蚀电位极化曲线^[26]

Fig.5 不同非晶涂层和基材的磨损率与滑动速率的关系^[59]

Table 2 不同基体表面制备的平均R_a值^[68]

Table 3 Fe₆₅，Fe₇₀ ^[88]和Fe₇₅^[84]粉末在不同研磨时间下的H_c和M_s值

Fig.6 壳体包覆的Fe-Si-B-C-Cr/TiO₂非晶磁粉芯的合成过程示意图^[96]

Fig.7 CAD程序中生成的3D支架结构(a)及位于底板(316L钢)顶部的支架(b)^[101]

Fig.8 不同激光线能量密度下制备非晶合金构建微裂纹的演变^[104] (a)SLM制造的3D打印Fe基非晶合金样品；(b)3D打印样品的侧视图(插图显示了完全非晶结构)；(c)~(f)在各种激光线能量密度下熔池的SEM图像(图像显示了微孔周围微裂纹的分布)

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