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材料工程  2010, Vol. 0 Issue (3): 25-28,92    
  表面工程 本期目录 | 过刊浏览 | 高级检索 |
钝化方式对镀锡钢板耐蚀性及铬含量的影响
孙杰1,2, 安成强1,2, 谭勇2
1. 沈阳理工大学环境与化工学院, 沈阳, 110168;
2. 东北大学金属防护技术工程研究中心, 沈阳, 110004
Effect of Chromium Content and Corrosion Resistance for Tinplate with Different Passivation Methods
SUN Jie1,2, AN Cheng-qiang1,2, TAN Yong2
1. School of Environmental and Chemical Engineering, Shenyang Institute of Technology, Shenyang, 110168, China;
2. Research Center for Corrosion and Protection of Metal, Northeast University, Shenyang, 110004, China
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摘要 使用化学分析、X射线光电子能谱分析以及电化学测试等试验方法,研究化学钝化以及电化学钝化得到的镀锡板的铬含量、铬元素组成及耐蚀性.结果表明:对于镀锡钢板铬酸盐钝化膜,电解钝化膜的总铬含量高于化学钝化膜的总铬含量.钝化膜中主要含有Cr,O以及Sn元素.不同钝化方式得到的钝化膜中铬元素的的价态、组成均不同,化学钝化膜及电解钝化膜中铬元素的组成分别为Cr2O3,Cr(OH)3以及Cr2O3,Cr(OH)3,Cr.电化学钝化膜的耐蚀性高于化学钝化膜.
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孙杰
安成强
谭勇
关键词 镀锡板钝化铬含量XPS耐蚀性    
Abstract:The tests,which consisted of chemical analysis,X-ray Photoelectron Spectroscopy(XPS) and electrochemistry method,were carried out to investigate the corrosion resistance,chemical state of element chromium and the chromium content for tinplate using chemical and electrochemical passivation methods.It was shown that there existed Cr,O and Sn in the passivation film.The total chromium content obtained by electrochemical method was higher than that of the chemical method by the analysis of chemistry.The chemical value and the composition in chromate passivation film were different between chemical and cathode passivation.The composition of the chemical passivation film were Cr2O3 and Cr(OH)3,while the composition of the electrochemical passivation film were Cr2O3,Cr(OH)3 and Cr.The corrosion resistance of the passivation film obtained by electrochemistry method was better than that of the passivation film obtained by chemistry method.
Key wordstinplate    passivation    Cr content    XPS    corrosion resistance
收稿日期: 2008-09-19      出版日期: 2010-03-20
中图分类号:  TG174.4  
作者简介: 孙杰(1971- ),男,副教授,博士,从事腐蚀科学与防护新技术、耐热耐磨涂层、电磁功能材料的制备与应用研究等,联系地址:沈阳理工大学环境与化工学院(110168),E-mail:jiersun2000@yahoo.com.cn
引用本文:   
孙杰, 安成强, 谭勇. 钝化方式对镀锡钢板耐蚀性及铬含量的影响[J]. 材料工程, 2010, 0(3): 25-28,92.
SUN Jie, AN Cheng-qiang, TAN Yong. Effect of Chromium Content and Corrosion Resistance for Tinplate with Different Passivation Methods. Journal of Materials Engineering, 2010, 0(3): 25-28,92.
链接本文:  
http://jme.biam.ac.cn/CN/      或      http://jme.biam.ac.cn/CN/Y2010/V0/I3/25
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