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材料工程  2017, Vol. 45 Issue (10): 59-64    DOI: 10.11868/j.issn.1001-4381.2016.001112
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
含氢硅油制备SiC晶须的研究
王瑶1,2, 陈旸1,2, 乔宁1,2, 李欣3, 张文婷1,2
1 华北理工大学 材料科学与工程学院, 河北 唐山 063009;
2 河北省无机非金属材料重点实验室, 河北 唐山 063009;
3 华北理工大学 建筑工程学院, 河北 唐山 063009
Research on SiC Whisker Prepared by H-PSO
WANG Yao1,2, CHEN Yang1,2, QIAO Ning1,2, LI Xin3, ZHANG Wen-ting1,2
1 College of Materials Science and Engineering, North China University of Science and Technology, Tangshan 063009, Hebei, China;
2 Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, Tangshan 063009, Hebei, China;
3 College of Civil and Architectual Engineering, North China University of Science and Technology, Tangshan 063009, Hebei, China
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摘要 以高含氢硅油为原料,在石墨基体上生长出SiC晶须。主要研究石墨基体的表面状态和加热温度对SiC晶须生长的影响,探究SiC晶须形成过程。影响SiC晶须形核和生长的主要因素为热处理温度,随着热处理温度的升高,SiC晶须的结晶产量也相应增高。石墨基体的表面状态对SiC晶须的形成也有一定的影响,随着石墨基体缺陷提供形核点的增多,SiC晶须的结晶产量提高,并且出现相互搭接的现象。SiC晶须的形成过程分为形核和生长两个部分,低温形核,高温生长,遵循VLS(气-液-固)生长机理。
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王瑶
陈旸
乔宁
李欣
张文婷
关键词 SiC晶须热处理温度基体表面状态生长机理    
Abstract:SiC whiskers were prepared on the matrix of graphite by using high hydrogenous silicone oil(PSO) as raw material. The effect of surface conditions of graphite and heating temperature on the growth of SiC whisker was mainly studied in this paper. The main factor which affects the nucleation and growth of SiC whisker is the heating temperature, with the heating temperature rising, the production of SiC whisker increases. The surface condition of graphite matrix also influences the growth of SiC whisker. With the nucleation points provided by graphite matrix defects increasing, the production of SiC whisker incleases and SiC whisker starts to overlap with each other. The formation process of SiC whisker includes two steps:nucleation and growth. SiC whisker nucleates at low temperature and grows at high temperature, which follows the VLS (vapor-liquid-solid) growth mechanism.
Key wordsSiC whisker    heating temperature    the condition of matrix    growth mechanism
收稿日期: 2016-09-22      出版日期: 2017-10-18
中图分类号:  TB33  
通讯作者: 陈旸(1983-),女,讲师,博士,研究方向为无机非金属复合材料、碳化硅晶须及其复合材料、碳纤维及其复合材料,联系地址:河北省唐山市新华西道46号华北理工大学材料科学与工程学院(063009),E-mail:360266139@qq.com     E-mail: 360266139@qq.com
引用本文:   
王瑶, 陈旸, 乔宁, 李欣, 张文婷. 含氢硅油制备SiC晶须的研究[J]. 材料工程, 2017, 45(10): 59-64.
WANG Yao, CHEN Yang, QIAO Ning, LI Xin, ZHANG Wen-ting. Research on SiC Whisker Prepared by H-PSO. Journal of Materials Engineering, 2017, 45(10): 59-64.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.001112      或      http://jme.biam.ac.cn/CN/Y2017/V45/I10/59
[1] 金培鹏, 周文胜, 丁雨田. 晶须在复合材料中的应用及其作用机理[J]. 盐湖研究, 2005, 13(2):1-6. JIN P P, ZHOU W S, DING Y T. Application of whiskers in composites and their reinforcement mechanism[J]. Journal of Salt Lake Research, 2005, 13(2):1-6.
[2] 聂立芳, 张玉军, 魏红康. 碳化硅晶须增韧陶瓷基复合材料的研究进展[J]. 山东陶瓷, 2006, 29(2):16-19. NIE L F, ZHANG Y J, WEI H K. Recent researches and developments of SiC whisker-reinforced ceramic-matrix composites[J]. Shandong Ceramics, 2006, 29(2):16-19.
[3] JIANG J F, WANG Y. Microstructure and mechanical properties of the rheoformed cylindrical part of 7075 aluminum matrix composite reinforced with nano-sized SiC particles[J]. Materials and Design, 2015, 79(3):32-41.
[4] LI X K, LIU L, ZHANG Y X, et al. Synthesis of nanometer silicon carbide whiskers from binary carbonaceous silica aerogels[J]. Carbon, 2001,39(2):159-165.
[5] SHIN Y, WANG C M, SAMUELS W D. Synthesis of SiC nanorods from bleached wood pulp[J]. Materials Letters, 2007, 61(13):2814-2817.
[6] DHIMAN R, JOHNSON E, MORGEN P. Growth of SiC nanowhiskers from wooden precursors,separation, and characterization[J]. Ceramics International, 2011, 37(8):3759-3764.
[7] DHAGE S, LEE H C, HASSAN M S, et al. Formation of SiC nanowhiskers by carbothermic reduction of silica with activated carbon[J]. Materials Letters, 2009, 63(2):174-176.
[8] PANDA S K, SENGUPTA J, JACOB C. Synthesis of β-SiC/SiO2 core-sheath nanowires by CVD technique using Ni as catalyst[J]. Journal of Nanoscience and Nanotechnology, 2010, 10(5):3046-3052.
[9] 李小宏, 辜丽欢, 陈善华, 等. 原位反应法制备晶须增强多孔陶瓷研究进展[J]. 材料导报, 2015, 29(3):35-31. LI X H, GU L H, CHEN S H, et al. Research progress of producing whisker reinforced porous ceramics by in-site synthesis technique[J]. Materials Review, 2015, 29(3):35-31.
[10] CETINKAYA S, EROGLU S. Chemical vapor deposition of C on SiO2 and subsequent carbothermal reduction for the synthesis of nanocrystalline SiC particles/whiskers[J]. Journal of Refractory Metals and Hard Materials, 2011, 29(2):566-572.
[11] 吴艳军, 张亚非, 杨忠学, 等. 碳纤维无催化剂法制备尽β-SiC纳米晶须[J]. 无机材料学报, 2005, 20(3):740-744. WU Y J, ZHANG Y F,YANG Z X, et al. Catalyst-free method of preparing β-SiC nanowhiskers by using carbon whiskers[J]. Journal of Inorganic Materials, 2005, 20(3):740-744.
[12] 李心慰, 曲殿利, 李志坚. 以硅灰、白炭黑、硅溶胶为硅源合成碳化硅晶须的研究[J]. 耐火材料, 2011, 45(2):105-102. LI X W, QU D L, LI Z J. Preparation of SiC whiskers from silica fume,amorphous silica,and silica sol[J]. Refractories, 2011, 45(2):105-102.
[13] 古卫俊, 贾素秋, 邱敬东, 等. 稻壳制备碳化硅晶须[J]. 硅酸盐学报, 2014, 42(1):29-32. GU W J, JIA S Q, QIU J D, et al. Preparation of SiC whiskers from rice husk[J]. Journal of the Chinese Ceramic Society, 2014, 42(1):29-32.
[14] 汪耀祖, 郭梦熊. 稻壳SiC晶须的生长工艺及机理[J]. 硅酸盐学报, 2013, 21(1):22-28. WANG Y Z, GUO M X. Growth technology and mechanism of SiC whisker by use of rice hulls[J]. Journal of the Chinese Ceramic Society, 2013, 21(1):22-28.
[15] 黄凤萍, 李贺军, 卢锦花, 等. 碳纤维诱导法制备SiC晶须的工艺及机理[J]. 硅酸盐学报, 2007, 35(5):643-647. HUANG F P, LI H J, LU J H, et al. Growth process and mechanism of SiC whiskers by induction of carbon fiber[J]. Journal of the Chinese Ceramic Society, 2007, 35(5):643-647.
[16] 张军战, 张颖, 蒋明学, 等. 不同原料合成SiC晶须的形貌结构特征和生长机理研究[J]. 功能材料, 2012, 13(43):1782-1785. ZHANG J Z, ZHANG Y, JIANG M X, et al. Microstructure and growth mechanism of SiC whiskers synthesized by using different raw materials[J]. Journal of Functional Materials, 2012, 43(13):1782-1785.
[17] CHEN Y F, LIU X Z, DENG X W. Factors affecting the growth of SiC nano-whiskers[J]. Journal of Materials Science & Technology, 2010, 26(11):1041-1046.
[18] CHEN Y, WANG C G, ZHU B, et al. Growth of SiC whiskers from hydrogen silicone oil[J]. Journal of Crystal Growth, 2012, 357:42-47.
[19] GRILL A, PATEL V. Low dielectric constant films prepared by plasma-enhanced chemical vapor deposition from tetramethylsilane[J]. Journal of Applied Physics, 1999, 85(6):3314-3318.
[20] KIM M T, LEE J. Characterization of amorphous SiC:H films deposited from hexamethyldisilazane[J]. Thin Solid Films, 1997, 303(1/2):173-179.
[21] 陈友存, 王启宝. SiC晶须VLS生长机理及生长动力学研究[J]. 化学物理学报, 1998, 11(3):258-260. CHEN Y C, WANG Q B. Studies on the growth mechanism and the kinetics of synthesizing SiC whiskers by VLS process[J]. Chinese Journal of Chemical Physics, 1998, 11(3):258-260.
[22] 陈旸, 王成国, 高冉冉. SiC晶须制备工艺的研究[J]. 无机材料学报, 2013, 28(7):758-762. CHEN Y, WANG C G, GAO R R. Research of the preparation technology for the SiC whisker[J]. Journal of Inorganic Materials, 2013, 28(7):758-762.
[23] LI X, ZHANG G Q. Synthesis of SiC whiskers by VLS and VS process[J]. Ceramics International, 2016, 42(5):5668-5676.
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