Please wait a minute...
 
材料工程  2017, Vol. 45 Issue (3): 17-27    DOI: 10.11868/j.issn.1001-4381.2016.001332
  石墨烯专栏 本期目录 | 过刊浏览 | 高级检索 |
石墨烯/橡胶导电纳米复合材料的研究进展
董慧民, 钱黄海, 程丽君, 苏正涛, 刘嘉, 王文志, 牟维琦
北京航空材料研究院, 北京 100095
Research Progress in Graphene/Rubber Conducting Nanocomposites
DONG Hui-min, QIAN Huang-hai, CHENG Li-jun, SU Zheng-tao, LIU Jia, WANG Wen-zhi, MU Wei-qi
Beijing Institute of Aeronautical Materials, Beijing 100095, China
全文: PDF(13091 KB)   HTML()
输出: BibTeX | EndNote (RIS)      
摘要 介绍了石墨烯/橡胶纳米复合材料的导电机理,综述了石墨烯及其衍生物、石墨烯的处理改性、与其他材料共混以及纳米导电复合材料的制备,论述了加工方法、硫化工艺以及温度、压力、频率、介质等因素对石墨烯/橡胶纳米复合材料导电性能的影响,并指出多组分橡胶/石墨烯复合体系及其“双逾渗”行为等都将是未来导电石墨烯/橡胶研究的重点。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
董慧民
钱黄海
程丽君
苏正涛
刘嘉
王文志
牟维琦
关键词 石墨烯改性物导电橡胶导电机理电性能逾渗阈值    
Abstract:The conductive mechanism of graphene/rubber nanocomposites was introduced.Advances in the synthesis and properties of graphene and its derivatives, modifications of graphene, along with its hybrid fillers, as well as fabrication of related rubber conducting nanocomposites were reviewed.Many factors affecting the electrical properties, such as fabrication method, vulcanization, temperature, pressure, frequency and media etc. were also summarized.It was pointed out that the further research should be focused on multi-component graphene/rubber nanocomposites and its double percolation phenomenon.
Key wordsgraphene    modification    conductive rubber    conductive mechanism    electricity property    percolation threshold
收稿日期: 2016-11-09      出版日期: 2017-03-22
中图分类号:  TB324  
通讯作者: 董慧民(1986-),男,博士,工程师,研究方向:高分子复合材料,联系地址:北京市81信箱70分箱(100095),E-mail:donghm.biam@hotmail.com     E-mail: donghm.biam@hotmail.com
引用本文:   
董慧民, 钱黄海, 程丽君, 苏正涛, 刘嘉, 王文志, 牟维琦. 石墨烯/橡胶导电纳米复合材料的研究进展[J]. 材料工程, 2017, 45(3): 17-27.
DONG Hui-min, QIAN Huang-hai, CHENG Li-jun, SU Zheng-tao, LIU Jia, WANG Wen-zhi, MU Wei-qi. Research Progress in Graphene/Rubber Conducting Nanocomposites. Journal of Materials Engineering, 2017, 45(3): 17-27.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.001332      或      http://jme.biam.ac.cn/CN/Y2017/V45/I3/17
[1] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2] GEIM A K,NOVOSELOV K S.The rise of graphene[J].Nature Materials,2007,6(3):183-191.
[3] TERRONES M,MARTÍN O,GONZÁLEZ M,et al.Interphases in graphene polymer-based nanocomposites:achievements and challenges[J].Advanced Materials,2011,23(44):5302-5310.
[4] ZHANG Y B,TANG T T,GIRIT C,et al.Direct observation of a widely tunable band gap in bilayer graphene[J].Nature,2009,459(7248):820-823.
[5] WANG G,YANG J,PARK J,et al.Facile synthesis and characterization of graphene nanosheets[J].Journal of Physical Chemistry C,2008,112:8192-8195.
[6] LEE C,WEI X,KYSAR J W,et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321(5887):385-388.
[7] BALANDIN A A,GHOSH S,BAO W,et al.Superior thermal conductivity of single-layer graphene[J].Nano Letters,2008,8(3):902-907.
[8] WU J,WOJCIECH P,KLAUS M.Graphenes as potential material for electronics[J].Chemical Reviews,2007,107(3):718-747.
[9] RAO C N R,SOOD A K,VOGGU R,et al.Some novel attributes of graphene[J].The Journal of Physical Chemistry Letters,2010,1(2):572-580.
[10] LIU P B,HUANG Y,WANG L,et al.Hydrothermal synthesis of reduced graphene oxide-Co3O4 composites and the excellent microwave electromagnetic properties[J].Materials Letters,2013,107:166-169.
[11] KUESENG K,JACOB K.Natural rubber nanocomposites with SiC nanoparticles and carbon nanotubes[J].European Polymer Journal,2006,42(1):220-227.
[12] DINS T,WANG L H,WANG P.Changes in electrical resistance of carbon-black-filled silicone rubber composite during compression[J].Journal of Polymer Science Part B:Polymer Physics,2007,45:2700-2706.
[13] DEGHAIDY F S.Effect of carbon fiber on the physico-chemical properties of conductive butyl-rubber composite[J].Egyptian Journal of Solids,2000,23(1):167-177.
[14] LEA H H,ABHIJEETC S,ILISCHD S,et al.The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filled natural rubber (NR) composites[J].Polymer,2014,55(18):4738-4747.
[15] RAJAGOPAL C,SATYAM M.Studies on electrical-conductivity of insulator-conductor composites[J].Journal of Applied Physics,1978,49(11):5536-5542.
[16] SHENG P,SIEHEL E K,GITTLEMAN J I.Fluctuation-induced tunneling conduction in carbon polyvinylchloride composites[J].Physical Review Letters,1978,40(18):1197-1200.
[17] KIRKPATRICK S.Percolation and conduction[J].Reviews of Modern Physics,1973,45(4):574-588.
[18] ZALLEN R.The Physics of Amorphous Solids[M].New York:Wiley,1985.
[19] PANG H,CHEN T,ZHANG G M,et al.An electrically conducting polymer/graphene composite with a very low percolation threshold[J].Materials Letters,2010,64(20):2226-2229.
[20] 于美,李新杰,马玉骁,等.石墨烯基复合超级电容器材料研究进展[J].材料工程,2016,44(5):101-111. YU M,LI X J,MA Y X,et al.Progress in research on graphene-based composite supercapacitor materials[J].Journal of Materials Engineering,2016,44(5):101-111.
[21] LU J R,WENG W G,CHEN X F,et al.Novel piezoresistive material from directed shear-induced assembly of graphite nanosheets in polyethylene[J].Advanced Functional Materials,2005,15(8):1358-1363.
[22] ZHANG X W,PAN Y,ZHENG Q,et al.Time dependence of piezoresistance for the conductor-filled polymer composites[J].Journal of Polymer Science Part B:Polymer Physics,2000,38(21):2739-2749.
[23] KOTAL M,BANERJEE S S,BHOWMICK A K.Functionalized graphene with polymer as unique strategy in tailoring the properties of bromobutyl rubber nanocomposites[J].Polymer,2016,82:121-132.
[24] DANG T T N,MAHAPATRA S P,SRIDHAR V,et al.Dielectric properties of nanotube reinforced butyl elastomer composites[J].Journal of Applied Polymer Science,2009,113(3):1690-1700.
[25] WU Z S,PEI S F,REN W C.Field emission of single-layer graphene films prepared by electrophoretic deposition[J].Advanced Materials,2009,21(17):1756-1760.
[26] CHEN Y,ZHANG B,LIU G,et al.Graphene and its derivatives:switching ON and OFF[J].Chemical Society Reviews,2012,41(13):4688-4707.
[27] 杨文彬,张丽,刘菁伟,等.石墨烯复合材料的制备及应用研究进展[J].材料工程,2015,43(3):91-97. YANG W B,ZHANG L,LIU J W,et al.Progress in research on preparation and application of graphene composites[J].Journal of Materials Engineering,2015,43(3):91-97.
[28] ZHU Y,MURALI S,CAI W,et al.Graphene and grapheme oxide:synthesis,properties and applications[J].Advanced Materials,2010,22(35):3906-3924.
[29] PARK S,AN J,JUNG I,et al.Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents[J].Nano Letters,2009,9(4):1593-1597.
[30] MENSAH B,KIM S,AREPALLI S,et al.A study of graphene oxide-reinforced rubber nanocomposite[J].Journal of Applied Polymer Science,2014,131(16):590-600.
[31] MATOS C F,GALEMBECK F,ZARBIN A J G.Multifunctional and environmentally friendly nanocomposites between natural rubber and graphene or graphene oxide[J].Carbon,2014,78(18):469-479.
[32] ROZPLOCH F,PATYK J,STANKOWSKI J.Graphenes bonding forces in graphite[J].Acta Physica Polonica,2007,112(112):557-562.
[33] 蔡文婧,梁滔,魏绪玲,等.石墨烯补强胶乳聚合橡胶研究进展[J].功能材料,2015,46(16):16030-16036. CAI W J,LIANG T,WEI X L,et al.Progress in the study on graphene reinforcing emulsion polymerization rubber[J].Journal of Functional Materials,2015,46(16):16030-16036.
[34] WEI D Y,YU J G,HUANG H,et al.A simple quenching method for preparing graphenes[J].Materials Letters,2012,66(1):150-152.
[35] ZHANG X,WANG J,JIA H,et al.Multifunctional nanocomposites between natural rubber and polyvinyl pyrrolidone modified graphene[J].Composites Part B:Engineering,2016,84:121-129.
[36] GAN L,SHANG S M,YUEN C W M,et al.Facile preparation of graphene nanoribbon filled silicone rubber nanocomposite with improved thermal and mechanical properties[J].Composites Part B:Engineering,2015,69:237-242.
[37] JIN Y H,JIA M Q,ZHANG M,et al.Preparation of stable aqueous dispersion of graphene nanosheets and their electro-chemical capacitive properties[J].Applied Surface Science,2013,264:787-793.
[38] 李兴鳌,任明伟,任睿毅,等.铜镍合金为衬底化学气相沉积法制备石墨烯研究[J].功能材料,2012,43(23):3257-3260. LI X A,REN M W,REN R Y,et al.Study on the graphene preparation on Cu-Ni alloy substrate by chemical vapor deposition[J].Journal of Functional Materials,2012,43(23):3257-3260.
[39] 张利华,关毅.制备方法对石墨烯电化学性能的影响[J].功能材料,2012,43(16):2121-2125. ZHANG L H,GUAN Y.The effect of different preparation methods on electrochemical properties of graphene[J].Journal of Functional Materials,2012,43(16):2121-2125.
[40] SONG S H,JEONG H K,KANG Y G.Preparation and characterization of exfoliated graphite and its styrene butadiene rubber nanocomposites[J].Journal of Industrial and Engineering Chemistry,2010,16(6):1059-1065.
[41] MALAS A,PAL P,DAS C K.Effect of expanded graphite and modified graphite flakes on the physical and thermo-mechanical properties of styrene butadiene rubber/polybutadiene rubber (SBR/BR) blends[J].Materials & Design,2014,55(6):664-673.
[42] WU J R,HUANG G S,LI H,et al.Enhanced mechanical and gas barrier properties of rubber nanocomposites with surface functionalized graphene oxide at low content[J].Polymer,2013,54(7):1930-1937.
[43] LIN Y,CHEN Y,ZHANG Y,et al.The use of zinc dimethacrylate functionalized graphene as a reinforcement in rubber composites[J].Polymers for Advanced Technologies,2015,26(5):423-431.
[44] 唐征海,郭宝春,张立群,等.石墨烯/橡胶纳米复合材料[J].高分子学报,2014,(7):865-877. TANG Z H,GUO B C,ZHANG L Q,et al.Graphene/rubber nanocomposites[J].Acta Polymerica Sinica,2014,(7):865-877.
[45] ATHANASIOS B,GOURNIS D,PETRIDIS D,et al.Graphite oxide:chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids[J].Langmuir,2003,19(15):6050-6055.
[46] ZHOU Z,ZHANG X,WU X,et al.Self-stabilized polyaniline@graphene aqueous colloids for the construction of assembled conductive network in rubber matrix and its chemical sensing application[J].Composites Science and Technology,2016,125:1-8.
[47] CAI W,HUANG Y,WANG D,et al.Piezoresistive behavior of graphene nanoplatelets/carbon black/silicone rubber nanocomposite[J].Journal of Applied Polymer Science,2014,131(3):39778.
[48] STAUFFER D,AHARONY A.Introduction to Percolation Theory[M].London:Taylor & Francis,1994.
[49] ZHANG H,WANG C,ZHANG Y.Preparation and properties of styrene-butadiene rubber nanocomposites blended with carbon black-graphene hybrid filler[J].Journal of Applied Polymer Science,2015,132(3):41309.
[50] HU H,ZHAO L,LIU J,et al.Enhanced dispersion of carbon nanotube in silicone rubber assisted by graphene[J].Polymer,2012,53(15):3378-3385.
[51] DAO T D,LEE H,JEONG H M.Alumina-coated graphene nanosheet and its composite of acrylic rubber[J].Journal of Colloid and Interface Science,2014,416:38-43.
[52] 宁南英,田明,张祥龙,等.一种高导电橡胶复合材料及其制备方法[P].中国专利:CN201310199334.1,2013-09-11. NING N Y,TIAN M,ZHANG X L,et al.A high conductive rubber composite and its preparation method[P].China Patent:CN201310199334.1,2013-09-11.
[53] MONIRUZZAMAN M,WINEY K I.Polymer nanocomposites containing carbon nanotubes[J].Macromolecules,2006,39(16):543-545.
[54] CHEN L,LU L,WU D J,et al.Silicone rubber/graphite nanosheet electrically conducting nanocomposite with a low percolation threshold[J].Polymer Composites,2007,28(4):493-498.
[55] BARROSO-BUJANS F,CERVENY S,VERDEJO R,et al.Permanent adsorption of organic solvents in graphite oxide and its effect on the thermal exfoliation[J].Carbon,2010,48(4):1079-1087.
[56] JIN S K,JU H Y,KIM I,et al.Electrical properties of graphene/SBR nanocomposite prepared by latex heterocoagulation process at room temperature[J].Journal of Industrial and Engineering Chemistry,2011,17(2):325-330.
[57] WANG T,LEI C H,DALTON A B,et al.Nanocomposite pressure-sensitive adhesives with high tack energy,optical transparency,and electrical conductivity[J].Advanced Engineering Materials,2006,18(20):2730-2734.
[58] STEURER P,WISSERT R,THOMANN R,et al.Functionalized graphenes and thermoplastic nanocomposites based upon expanded graphite oxide[J].Macromolecular Rapid Communications,2009,30(4-5):316-327.
[59] PEDRONI L G,SOTO-OVIEDO M A,ROSOLEN J M,et al.Conductivity and mechanical properties of composites based on MWCNTs and styrene-butadiene-styrene blockTM copolymers[J].Journal of Applied Polymer Science,2009,112(6):3241-3248.
[60] XING W,TANG M Z,WU J R,et al.Multifunctional properties of graphene/rubber nanocomposites fabricated by a modified latex compounding method[J].Composites Science and Technology,2014,99:67-74.
[61] ARABY S,ZAMAN I,MENG Q S,et al.Melt compounding with graphene to develop functional,high-performance elastomers[J].Nanotechnology,2013,24(16):165601.
[62] DAS A,KASALIWAL G R,JURK R,et al.Rubber composites based on graphene nanoplatelets,expanded graphite,carbon nanotubes and their combination:a comparative study[J].Composites Science and Technology,2012,72(16):1961-1967.
[63] WANG L,WANG W C,FU Y,et al.Enhanced electrical and mechanical properties of rubber/graphene film through layer-by-layer electrostatic assembly[J].Composites Part B:Engineering,2016,90:457-464.
[64] ZHAN Y,LAVORGNA M,BUONOCORE G,et al.Enhancing electrical conductivity of rubber composites by constructing interconnected network of self-assembled graphene with latex mixing[J].Journal of Materials Chemistry,2012,22(21):10464-10468.
[65] ARABY S,MENG Q,ZHANG L,et al.Electrically and thermally conductive elastomer/graphene nanocomposites by solution mixing[J].Polymer,2014,55(1):201-210.
[66] ARABY S,ZHANG L Q,KUANC H C,et al.A novel approach to electrically and thermally conductive elastomers using graphene[J].Polymer,2013,54(14):3663-3670.
[67] GUO H L,WANG X F,QIAN Q Y,et al.A green approach to the synthesis of graphene nanosheets[J].ACS Nano,2009,3(9):2653-2659.
[68] WANG G,YANG J,PARK J,et al.Facile synthesis and characterization of graphene nanosheets[J].Journal of Physical Chemistry C,2008,112(22):8192-8195.
[69] AL-SOLAMY F R,AL-GHAMDI A A,MAHMOUD W E.Piezoresistive behavior of graphite nanoplatelets based rubber nanocomposites[J].Polymers for Advanced Technologies,2012,23(3):478-482.
[70] TUUKKANEN S,HOIKKANEN M,POIKELISPÄÄ M,et al.Stretching of solution processed carbon nanotube and graphene nanocomposite films on rubber substrates[J].Synthetic Metals,2014,191:28-35.
[71] SAU K P,CHAKI T K,KHASTGIR D.Conductive rubber composites from different blends of ethylene-propylene-diene rubber and nitrile rubber[J].Journal of Materials Science,1997,32(21):5717-5724.
[72] MAHMOUD W E,AL-GHAMDI A A.Charge transport mechanism of graphite-nanosheet-loaded rubber nanocomposites[J].Polymer International,2012,61(1):51-54.
[73] MOTT N F,DAVIS E A.Electronic Processes in Non-Crystalline Materials[M].Oxford:Clarendon Press,1979.
[74] PONNAMMA D,SADASIVUNI K K,STRANKOWSKI M,et al.Synergistic effect of multi walled carbon nanotubes and reduced graphene oxides in natural rubber for sensing application[J].Soft Matter,2013,9(43),10343-10353.
[75] HERNÁNDEZ M,BERNAL M D M,VERDEJO R,et al.Overall performance of natural rubber/graphene nanocomposites[J].Composites Science and Technology,2012,73(23):40-46.
[76] SCHOPP S,THOMANN R,RATZSCH K F,et al.Functionalized graphene and carbon materials as components of styrene-butadiene rubber nanocomposites prepared by aqueous dispersion blending[J].Macromolecular Materials and Engineering,2014,299(3):319-329.
[1] 吉传波, 王晓峰, 邹金文, 杨杰. 石墨烯增强镍基粉末高温合金复合材料的力学性能[J]. 材料工程, 2017, 45(3): 1-6.
[2] 胡圣飞, 魏文闵, 刘清亭, 张荣. 超临界流体剥离制备石墨烯研究进展[J]. 材料工程, 2017, 45(3): 28-34.
[3] 张林, 陈多礼, 朱旻昊, 蔡振兵, 彭金方. 氧化石墨烯对阻尼丁腈橡胶抗老化性能的影响[J]. 材料工程, 2017, 45(3): 7-12.
[4] 何聪, 欧宝立, 李政峰. 氧化石墨烯对聚丙烯/尼龙6两组分聚合物的增容作用[J]. 材料工程, 2017, 45(3): 13-16.
[5] 赵晓明, 刘元军. 铁氧体/碳化硅/石墨三层涂层复合材料介电性能[J]. 材料工程, 2017, 45(1): 33-37.
[6] 洪起虎, 燕绍九, 杨程, 张晓艳, 戴圣龙. 氧化石墨烯/铜基复合材料的微观结构及力学性能[J]. 材料工程, 2016, 44(9): 1-7.
[7] 郑辉东. 3D氧化石墨烯纳米带-碳纳米管/TPU复合材料薄膜的制备与性能[J]. 材料工程, 2016, 44(6): 1-8.
[8] 张丹丹, 战再吉. 石墨烯/金属复合材料力学性能的研究进展[J]. 材料工程, 2016, 44(5): 112-119.
[9] 于美, 李新杰, 马玉骁, 刘瑞丽, 刘建华, 李松梅. 石墨烯基复合超级电容器材料研究进展[J]. 材料工程, 2016, 44(5): 101-111.
[10] 陈昱, 王京钰, 李维尊, 鞠美庭. 新型二氧化钛基光催化材料的研究进展[J]. 材料工程, 2016, 44(3): 103-113.
[11] 吕生华, 朱琳琳, 李莹, 贺亚亚, 杨文强. 氧化石墨烯复合材料的研究现状及进展[J]. 材料工程, 2016, 44(12): 107-117.
[12] 芦佳, 王辉虎, 董一帆, 常鹰, 马新国, 董仕节. RGO/ZnO纳米棒复合材料的合成及光催化性能[J]. 材料工程, 2016, 44(12): 48-53.
[13] 郑辉东, 欧忠星, 郑玉婴, 肖东升, 曹宁宁. 功能石墨烯/热塑性聚氨酯复合材料膜的制备及性能[J]. 材料工程, 2016, 44(11): 114-119.
[14] 王婵媛, 王希晰, 曹茂盛. 轻质石墨烯基电磁屏蔽材料的研究进展[J]. 材料工程, 2016, 44(10): 109-118.
[15] 吕生华, 李莹, 杨文强, 崔亚亚. 氧化石墨烯/壳聚糖生物复合材料的制备及应用研究进展[J]. 材料工程, 2016, 44(10): 119-128.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn