量子点/碳复合材料在碱金属离子电池的应用进展

doi:10.11868/j.issn.1001-4381.2022.000285

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摘要

碱金属离子电池作为可充电电池, 是目前重要的储能设备之一。它凭借能量密度大、工作电压高、无"记忆效应"、自放电小、绿色无污染等优点在近些年来受到人们的广泛关注。电极材料是影响碱金属离子电池电化学性能的重要因素之一, 因此, 寻求比容量高、结构稳定的电极材料是推动碱金属离子电池发展的关键。量子点/碳复合材料(QDs/C)集合量子点与碳材料的优势, 是碱金属离子电池优异的候选电极材料。本文首先对量子点进行简要介绍, 然后分别综述单质量子点/碳复合材料、化合物量子点/碳复合材料及异质结构量子点/碳复合材料在碱金属离子电池中的应用进展。最后, 分析量子点/碳复合材料作为碱金属离子电池电极材料的优势与不足, 针对目前存在的问题提出了未来发展的方向: (1)探索新型方法, 解决量子点及其复合材料的团聚问题; (2)研究SEI膜的结构性能等, 解决首次库仑效率偏低的问题; (3)明确反应机理, 获取更优异的电化学性能。

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	吴立清
	冯柳
	毛晓璇
	穆洪亮
	刘志超
	牛金叶
	高蔷

关键词 ：碱金属离子电池, 量子点/碳复合材料, 异质结构, 协同作用, 电化学性能

Abstract：

As a kind of rechargeable batteries, alkali metal-ion battery is one of the important energy storage devices at present. Due to the advantages of enhanced energy density, high work potential, no "memory effect", small self-discharge, environment-friendly, alkali metal-ion batteries have attracted extensive attention in recent years. Electrode material is one of the most important factors that influence the electrochemical performances of alkali metal-ion batteries. Therefore, the key to the improvement of alkali metal-ion batteries is to seek electrode materials with high specific capacity and stable structures. Quantum dots/carbon composites (QDs/C), integrating the advantages of quantum dot materials and carbon materials have turned out to be outstanding candidates for electrode materials of alkali metal-ion batteries. In this work, a brief introduction of quantum dot materials was given at first, and then the progress of QDs/C, including element QDs/C, compound QDs/C and heterostructure QDs/C in alkali metal-ion batteries, was summarized respectively. The advantages and disadvantages of QDs/C as electrode materials of alkali metal-ion batteries were discussed in the last part.In view of the shortcoming, the future development goal was proposed: (1)Exploring the innovative approach to slove the agglomeration of quantum dots and the relative composites; (2)Researching the structure and property of SEI film to improve the initial coulombic efficiency; (3)Clarifying the reaction mechanism to obtain the better electrochemical performance.

Key words： alkali metal-ion battery quantum dots/carbon composite heterostructure synergistic effect electrochemical performance

收稿日期: 2022-04-10 出版日期: 2023-01-16

中图分类号:

TM911

基金资助:山东省自然科学基金青年基金项目(ZR2020QE145)

通讯作者: 冯柳 E-mail: willow-feng@163.com

作者简介: 冯柳(1978—)，女，教授，博士，研究方向为储能材料的制备、结构演化及性能研究，联系地址：山东省淄博市张店区马尚镇山东理工大学西校区(255000)，E-mail：willow-feng@163.com

引用本文:

吴立清, 冯柳, 毛晓璇, 穆洪亮, 刘志超, 牛金叶, 高蔷. 量子点/碳复合材料在碱金属离子电池的应用进展[J]. 材料工程, 2023, 51(1): 36-51.
Liqing WU, Liu FENG, Xiaoxuan MAO, Hongliang MU, Zhichao LIU, Jinye NIU, Qiang GAO. Recent progress of quantum dots/carbon composites in alkali metal-ion batteries. Journal of Materials Engineering, 2023, 51(1): 36-51.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2022.000285 或 http://jme.biam.ac.cn/CN/Y2023/V51/I1/36

Table 1 单质量子点/碳复合材料的制备方法和电化学性能

Fig.1 GQD@CNT的制备过程及循环性能^[15]
(a)制备过程示意图；(b)循环性能

Fig.2 合金反应型单质量子点与碳材料复合的制备过程示意图
(a)SiQDs/C^[26]；(b)3DOP Ge@N-C^[27]；(c)Sn/NS-CNFs@rGO^[32]；(d)SbQD@C^[39]

Electrode material	Synthesis method	Initial discharge capacity/(mAh·g^-1)	Initial coulombic efficiency/%	Cycling capacity/(mAh·g^-1)	Application	Reference
Oxide QDs/C
N-C@MnOQD/CNT	Chemical reaction, annealing	1367	61.0	883 at 1 A·g^-1 after 1000 cycles	LIBs, anode	[41]
MnOQD@CHNTs	Molecular beam template approach	481		223 at 2 A·g^-1 after 1000 cycles	SIBs, anode	[42]
SnO₂QDs@GF	Hydrothermal	2500	65.9	134 at 10 A·g^-1 after 5000 cycles	LIBs, anode	[8]
SnO₂/NC	Hydrothermal, self-polymerization	1716	72.9	753 at 1 A·g^-1 after 1500 cycles	LIBs, anode	[6]
SnO₂@C/GO	Ball-milling, water-phase self-assembly	1710	57.5	1156 at 1 A·g^-1 after 350 cycles	LIBs, anode	[43]
GE-Co₃O₄	Chemical reaction	1687	69.0	750 at 1 A·g^-1 after 100 cycles	LIBs, anode	[44]
2-CuO@C	Electrospinning	828	67.0	401 at 0.5 A·g^-1 after 500 cycles	SIBs, anode	[45]
TiO₂QDs@C	Reverse microemulsion, heat treament	841	54.8	68.6% at 5 A·g^-1 after 10000 cycles	LIBs, anode	[46]
ZnOQDs@CMS	Hydrothermal, annealing	1542	55.0	565 at 1 A·g^-1 after 350 cycles	LIBs, anode	[2]
Fe₂O₃QDs@rGO	Hydrothermal, annealing	1384	80.1	81.6% at 0.2 A·g^-1 after 300 cycles	LIBs, anode	[47]
Fe₃O₄@LCS-500	Microwave, annealing		65.8	1126.2 at 0.1 A·g^-1 after 250 cycles	LIBs, anode	[7]
V₂O₅QDs/rGO	Two-step solution phase synthesis	288		100 at 1 A·g^-1 after 300 cycles	LIBs, cathode	[48]
Sulfide QDs/C
SnSQDs@NC	Hydrothermal, carbonization	489	61.3	75% at 1 A·g^-1 after 500 cycles	SIBs, anode	[49]
SnS@HMCFs	Hydrothermal, electrospinning, high-temperature pyrolysis	621	68.8	245.5 at 1 A·g^-1 after 1000 cycles	PIBs, anode	[50]
MoS₂-N-C	Liquid-phase synthesis, annealing	1240		261 at 10 A·g^-1 after 1950 cycles	LIBs, anode	[51]
FeS₂QDs/FGS	Heat treatment	742	92.0	552 at 0.5 A·g^-1 after 100 cycles	SIBs, anode	[52]
FeS@SPC	Self-template method	869	51.8	232 at 1 A·g^-1 after 3000 cycles	PIBs, anode	[53]
ZnSQD@NC	Polyol-assisted pyro-synthetic method	965	83.0	620 at 1 A·g^-1 after 500 cycles	LIBs, anode	[54]
ZnSQDs-rGO	Solvothermal	720	63.0	122 at 1 A·g^-1 after 500 cycles	PIBs, anode	[55]
M-Co₉S₈@NCF	In-situ anchoring and annealing	1403	73.0	617 at 1 A·g^-1 after 500 cycles	LIBs, anode	[56]
Selenide QDs/C
a-SnSe/rGO	Hydrothermal, freeze drying	873	70.0	398 at 1 A·g^-1 after 1400 cycles	SIBs, anode	[57]
SnSe₂QDs/rGO	Hydrothermal, freeze drying, thermal annealing	1183	66.1	92.2% at 2 A·g^-1 after 3000 cycles	LIBs, anode	[58]
CSC(Co₃Se₄QDs/NC)	Solvothermal, carbonization	573	66.6	360 at 0.5 A·g^-1 after 3200 cycles	PIBs, anode	[59]
Phosphide QDs/C
FeP@OCF/CNF	In situ reductive phosphatization/carbonization	913	72.0	435 at 1 A·g^-1 after 200 cycles	SIBs, anode	[60]
FeP@NC	Annealing, phosphatization	1259	52.4	374 at 0.5 A·g^-1 after 2000 cycles	SIBs, anode	[5]
MoP@PC	Mixing, annealing		21.9	161 at 5 A·g^-1 after 1000 cycles	PIBs, anode	[61]
Ni₂P@NPC	Freeze-drying, carbonization	1351	24.7	212 at 1 A·g^-1 after 5000 cycles	PIBs, anode	[62]
Co₂PQD/NPC	Solvothermal, annealing	906	72.7	431.4 at 1 A·g^-1 after 1600 cycles	LIBs, anode	[63]
Nitride(carbide)QDs/C
VNQDs/NC	Solution-phase assisted thermal nitridation	1045	75.7	602 at 0.25 A·g^-1 after 250 cycles	LIBs, anode	[64]
VNQDs/N-C	Self-polymerization	1168	42.7	225.7 at 30 A·g^-1 after 30000 cycles	SIBs, anode	[65]
VNQDs/CM	Solution combustion synthesis method	376	72.9	215 at 0.5 A·g^-1 after 500 cycles	PIBs, anode	[66]
Mo₂N@NC	Sol-gel, calcination	1488	58.0	96.8% at 2 A·g^-1 after 3000 cycles	LIBs, anode	[67]
Mo₂NQD@MoO₃@NC	Sol-gel route	1685	61.8	700 at 1 A·g^-1 after 700 cycles	LIBs, anode	[68]
Mo₂C/NCNFs	Electrospinning	468	53.9	74% at 1 A·g^-1 after 1000 cycles	PIBs, anode	[69]
CVC_x-QDs/nFCM	Solution combustion synthesis method, carbothermal reduction	834	54.3	130 at 1 A·g^-1 after 1500 cycles	PIBs, anode	[70]
Other compound QDs/C
SbSn@NCNFs	Electrospinning	808	72.9	331 at 0.1 A·g^-1 after 500 cycles	SIBs, anode	[71]
Ni₃Sn₄-rGO	Microwave irradiation	1117	78.2	1311 at 0.1 A·g^-1 after 500 cycles	LIBs, anode	[72]
G/LFPQDs@C	Microreactor strategy			99% at 20 C after 1000 cycles	LIBs, cathode	[73]
NaVPO₄F/C	Electrospinning	126	88.0	96.5% at 2 C after 1000 cycles	SIBs, cathode	[74]
NVP-QDs-SL/HCS	Self-assemble of LCs	149		56% at 20 C after 3000 cycles	SIBs, cathode	[75]

Table 2 化合物量子点/碳复合材料的制备方法和电化学性能

Fig.3 MnOQD@CHNTs的制备及长循环性能^[42]
(a)制备、结构及量子点效应示意图；(b)LIBs中的长循环性能

Fig.4 SnSe₂QDs/rGO的制备，微观形貌及长循环性能^[58]
(a)合成示意图；(b)SEM图；(c)HRTEM图；(d)长循环性能

Fig.5 FeP@NC的循环性能及储钠机理^[5]
(a)长循环性能；(b)储钠过程示意图

Fig.6 VNQDs/N-C(a)^[65]和CVC_xQDs/nFCM(b)^[70]的制备过程示意图

Table 3 异质结构量子点/碳复合材料的制备方法和电化学性能

1	YU W J , HE W , WANG C , et al. Confinement of TiO₂ quantum dots in graphene nanoribbons for high-performance lithium and sodium ion batteries[J]. Journal of Alloys and Compounds, 2022, 898, 162856. doi: 10.1016/j.jallcom.2021.162856
2	FERNANDO J F S , ZHANG C , FIRESTEIN K L , et al. ZnO quantum dots anchored in multilayered and flexible amorphous carbon sheets for high performance and stable lithium ion batteries[J]. Journal of Materials Chemistry A, 2019, 7 (14): 8460- 8471. doi: 10.1039/C8TA12511B
3	LIU J , ZHU M , MU K , et al. Engineering a novel microcapsule of Cu₉S₅ core and SnS₂ quantum dot/carbon nanotube shell as a Li-ion battery anode[J]. Chemical Communications, 2021, 57 (98): 13397- 13400. doi: 10.1039/D1CC05657C
4	YANG Y , ZHU J , WANG P , et al. In situ implanting fine ZnSe nanoparticles into N-doped porous carbon nanosheets as an exposed highly active and long-life anode for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2021, 876, 160135. doi: 10.1016/j.jallcom.2021.160135
5	LI Z , ZHAO H , DU Z , et al. Iron phosphide@N-doped carbon nanosheets with open-framework structure as an ultralong lifespan and outstanding rate performance electrode material for sodium-ion batteries[J]. Journal of Power Sources, 2020, 465, 228253. doi: 10.1016/j.jpowsour.2020.228253
6	CHENG Y , WANG S , ZHOU L , et al. SnO₂ quantum dots: rational design to achieve highly reversible conversion reaction and stable capacities for lithium and sodium storage[J]. Small, 2020, 16 (26): 2000681. doi: 10.1002/smll.202000681
7	PENG Q , GUO C , QI S , et al. Ultra-small Fe₃O₄ nanodots encapsulated in layered carbon nanosheets with fast kinetics for lithium/potassium-ion battery anodes[J]. RSC Advances, 2021, 11 (3): 1261- 1270. doi: 10.1039/D0RA08503K
8	GAO L , WU G , MA J , et al. SnO₂ quantum dots@graphene framework as a high-performance flexible anode electrode for lithium-ion batteries[J]. ACS Applied Materials and Interfaces, 2020, 12 (11): 12982- 12989. doi: 10.1021/acsami.9b22679
9	WU M , CHEN H , LV L P , et al. Graphene quantum dots modification of yolk-shell Co₃O₄@CuO microspheres for boosted lithium storage performance[J]. Chemical Engineering Journal, 2019, 373, 985- 994. doi: 10.1016/j.cej.2019.05.100
10	GUO J , GAO F , LI D , et al. Novel strategy of constructing hollow Ga₂O₃@N-CQDs as a self-healing anode material for lithium-ion batteries[J]. ACS Sustainable Chemistry & Engineering, 2020, 8 (36): 13692- 13700.
11	LUO F , FENG X , ZENG L , et al. In situ simultaneous encapsulation of defective MoS₂ nanolayers and sulfur nanodots into SPAN fibers for high rate sodium-ion batteries[J]. Chemical Engineering Journal, 2021, 404, 126430. doi: 10.1016/j.cej.2020.126430
12	LU D , YUAN C , YU M , et al. Nanoporous composites of CoO_x quantum dots and ZIF-derived carbon as high-performance anodes for lithium-ion batteries[J]. ACS Omega, 2020, 5 (34): 21488- 21496. doi: 10.1021/acsomega.0c02037
13	汪晨阳, 张安邦, 常增花, 等. 锂离子电池用多孔电极结构设计及制备技术进展[J]. 材料工程, 2022, 50 (1): 67- 79.
13	WANG C Y , ZHANG A B , CHANG Z H , et al. Progress in structure design and preparation of porous electrodes for lithium ion batteries[J]. Journal of Materials Engineering, 2022, 50 (1): 67- 79.
14	CHEN W , ZHANG X , PENG Y , et al. One-pot scalable synthesis of pure phase Ni₃S₄ quantum dots as a versatile electrode for high performance hybrid supercapacitors and lithium ion batteries[J]. Journal of Power Sources, 2019, 438, 227004. doi: 10.1016/j.jpowsour.2019.227004
15	ZHAO X , WU Y , WANG Y , et al. High-performance Li-ion batteries based on graphene quantum dot wrapped carbon nanotube hybrid anodes[J]. Nano Research, 2020, 13 (4): 1044- 1052. doi: 10.1007/s12274-020-2741-9
16	HAN K , ZHAO W , YU Q , et al. Marcasite-FeS₂@carbon nanodots anchored on 3D cell-like graphenic matrix for high-rate and ultrastable potassium ion storage[J]. Journal of Power Sources, 2020, 469, 228429. doi: 10.1016/j.jpowsour.2020.228429
17	KUMAR R , SAHOO S , JOANNI E , et al. Heteroatom doped graphene engineering for energy storage and conversion[J]. Materials Today, 2020, 39, 47- 65. doi: 10.1016/j.mattod.2020.04.010
18	ELSAYED M H , JAYAKUMAR J , ABDELLAH M , et al. Visible-light-driven hydrogen evolution using nitrogen-doped carbon quantum dot-implanted polymer dots as metal-free photocatalysts[J]. Applied Catalysis B, 2021, 283, 119659. doi: 10.1016/j.apcatb.2020.119659
19	LIN X , LIU C , WANG J , et al. Graphitic carbon nitride quantum dots and nitrogen-doped carbon quantum dots co-decorated with BiVO₄ microspheres: a ternary heterostructure photocatalyst for water purification[J]. Separation and Purification Technology, 2019, 226, 117- 127. doi: 10.1016/j.seppur.2019.05.093
20	LI S , SU W , WU H , et al. Targeted tumour theranostics in mice via carbon quantum dots structurally mimicking large amino acids[J]. Nature Biomedical Engineering, 2020, 4 (7): 704- 716. doi: 10.1038/s41551-020-0540-y
21	GAO Z , XU B , MA M , et al. Electrostatic self-assembly synthesis of ZnFe₂O₄ quantum dots (ZnFe₂O₄@C) and electromagnetic microwave absorption[J]. Composites: Part B, 2019, 179, 107417. doi: 10.1016/j.compositesb.2019.107417
22	LI M , CHEN T , GOODING J J , et al. Review of carbon and graphene quantum dots for sensing[J]. ACS Sensors, 2019, 4 (7): 1732- 1748. doi: 10.1021/acssensors.9b00514
23	XIE J , LU Y C . A retrospective on lithium-ion batteries[J]. Nature Communications, 2020, 11 (1): 2499. doi: 10.1038/s41467-020-16259-9
24	吴怡芳, 崇少坤, 柳永宁, 等. 碳纳米材料构建高性能锂离子和锂硫电池研究进展[J]. 材料工程, 2020, 48 (4): 25- 35.
24	WU Y F , CHONG S K , LIU Y N , et al. Research progress on carbon nano-materials to construct Li-ion and Li-S batteries of high performance[J]. Journal of Materials Engineering, 2020, 48 (4): 25- 35.
25	WANG H , AN D , TIAN P , et al. Incorporating quantum-sized boron dots into 3D cross-linked rGO skeleton to enable the activity of boron anode for favorable lithium storage[J]. Chemical Engineering Journal, 2021, 425, 130659. doi: 10.1016/j.cej.2021.130659
26	WEI Y , YU H , LI H , et al. Liquid-phase plasma synthesis of silicon quantum dots embedded in carbon matrix for lithium battery anodes[J]. Materials Research Bulletin, 2013, 48 (10): 4072- 4077. doi: 10.1016/j.materresbull.2013.06.030
27	WANG Y , LUO S , CHEN M , et al. Uniformly confined germanium quantum dots in 3D ordered porous carbon framework for high-performance Li-ion battery[J]. Advanced Functional Materials, 2020, 30 (16): 2000373. doi: 10.1002/adfm.202000373
28	GUO Y , FENG Y , LI H , et al. Carbon quantum dots in hard carbon: an approach to achieving PIB anodes with high potassium adsorption[J]. Carbon, 2022, 189, 142- 151. doi: 10.1016/j.carbon.2021.12.038
29	ZHANG E , JIA X , WANG B , et al. Carbon dots@rGO paper as freestanding and flexible potassium-ion batteries anode[J]. Advanced Science, 2020, 7 (15): 2000470. doi: 10.1002/advs.202000470
30	CHEN B , ZU L , LIU Y , et al. Space-confined atomic clusters catalyze superassembly of silicon nanodots within carbon frameworks for use in lithium-ion batteries[J]. Angewandte Chemie International Edition, 2020, 59 (8): 3137- 3142. doi: 10.1002/anie.201915502
31	ZHANG G , ZHU J , ZENG W , et al. Tin quantum dots embedded in nitrogen-doped carbon nanofibers as excellent anode for lithium-ion batteries[J]. Nano Energy, 2014, 9, 61- 70. doi: 10.1016/j.nanoen.2014.06.030
32	LUO L , SONG J , SONG L , et al. Flexible conductive anodes based on 3D hierarchical Sn/NS-CNFs@rGO network for sodium-ion batteries[J]. Nano-Micro Letters, 2019, 11 (1): 63. doi: 10.1007/s40820-019-0294-9
33	GONG D , WANG B , ZHU J , et al. An iodine quantum dots based rechargeable sodium-iodine battery[J]. Advanced Energy Materials, 2017, 7 (3): 1601885. doi: 10.1002/aenm.201601885
34	ZHU C , CHAO D , SUN J , et al. Enhanced lithium storage performance of CuO nanowires by coating of graphene quantum dots[J]. Advanced Materials Interfaces, 2015, 2 (2): 1400499. doi: 10.1002/admi.201400499
35	DARYABARI S , MANSOURI S , BEHESHTIAN J , et al. A computational study on the novel defects of graphene quantum dot as a promising anode material for sodium ion battery[J]. Materials Chemistry and Physics, 2021, 265, 124484. doi: 10.1016/j.matchemphys.2021.124484
36	LI Y , WU F , JIN X , et al. Preparation and electrochemical properties of graphene quantum dots/biomass activated carbon electrodes[J]. Inorganic Chemistry Communications, 2020, 112, 107718. doi: 10.1016/j.inoche.2019.107718
37	CHEN Y , ZOU Y , SHEN X , et al. Ge nanoparticles uniformly immobilized on 3D interconnected porous graphene frameworks as anodes for high-performance lithium-ion batteries[J]. Journal of Energy Chemistry, 2022, 69, 161- 173. doi: 10.1016/j.jechem.2021.12.051
38	ZHANG Y , YAN D , LIU Z , et al. A SnO_x quantum dots embedded carbon nanocage network with ultrahigh Li storage capacity[J]. ACS Nano, 2021, 15 (4): 7021- 7031. doi: 10.1021/acsnano.1c00088
39	QIU T , YANG L , XIANG Y , et al. Heterogeneous interface design for enhanced sodium storage: Sb quantum dots confined by functional carbon[J]. Small Methods, 2021, 5 (7): 2100188. doi: 10.1002/smtd.202100188
40	LUO B , WANG B , LI X , et al. Graphene-confined Sn nanosheets with enhanced lithium storage capability[J]. Advanced Materials, 2012, 24 (26): 3538- 3543. doi: 10.1002/adma.201201173
41	HUANG S , YANG L , GAO M , et al. Well-dispersed MnO-quantum-dots/N-doped carbon layer anchored on carbon nanotube as free-standing anode for high-performance Li-ion batteries[J]. Electrochimica Acta, 2019, 319, 302- 311. doi: 10.1016/j.electacta.2019.06.155
42	LI H , JIANG L , FENG Q , et al. Ultra-fast transfer and high storage of Li⁺/Na⁺ in MnO quantum dots@carbon hetero-nanotubes: appropriate quantum dots to improve the rate[J]. Energy Storage Materials, 2019, 17, 157- 166. doi: 10.1016/j.ensm.2018.07.021
43	LI B , BAO S , TAN Q , et al. Engineering tin dioxide quantum dots in a hierarchical graphite and graphene oxide framework for lithium-ion storage[J]. Journal of Colloid and Interface Scicnce, 2021, 600, 649- 659. doi: 10.1016/j.jcis.2021.05.070
44	PARK Y J , LEE K S , SHIM J , et al. Suppression of volume expansion by graphene encapsulated Co₃O₄ quantum dots for boosting lithium storage[J]. Journal of Industrial and Engineering Chemistry, 2021, 95, 333- 339. doi: 10.1016/j.jiec.2021.01.004
45	WANG X , LIU Y , WANG Y , et al. CuO quantum dots embedded in carbon nanofibers as binder-free anode for sodium ion batteries with enhanced properties[J]. Small, 2016, 12 (35): 4865- 4872. doi: 10.1002/smll.201601474
46	YIN J , YU J , SHI X , et al. TiO₂ quantum dots confined in 3D carbon framework for outstanding surface lithium storage with improved kinetics[J]. Journal of Colloid and Interface Science, 2021, 582, 874- 882. doi: 10.1016/j.jcis.2020.08.076
47	MA M , CAO L , LI J , et al. Tailoring mulberry-like Fe₂O₃ architecture assembled by quantum dots on rGO to enable high pseudocapacitance and controllable solid electrolyte interphase[J]. Chemical Engineering Journal, 2020, 388, 124119. doi: 10.1016/j.cej.2020.124119
48	HAN C , YAN M , MAI L , et al. V₂O₅ quantum dots/graphene hybrid nanocomposite with stable cyclability for advanced lithium batteries[J]. Nano Energy, 2013, 2 (5): 916- 922. doi: 10.1016/j.nanoen.2013.03.012
49	VEERASUBRAMANI G K , PARK M S , CHOI J Y , et al. Ultrasmall SnS quantum dots anchored onto nitrogen-enriched carbon nanospheres as an advanced anode material for sodium-ion batteries[J]. ACS Applied Materials and Interfaces, 2020, 12 (6): 7114- 7124. doi: 10.1021/acsami.9b18997
50	HE Y , XU Y , ZHANG M , et al. Confining ultrafine SnS nanoparticles in hollow multichannel carbon nanofibers for boosting potassium storage properties[J]. Science Bulletin, 2022, 67 (2): 151- 160. doi: 10.1016/j.scib.2021.09.020
51	SUN L , WANG C , LI H , et al. Crystalline coordination polymer-derived MoS₂ quantum dot-doped carbon nanoflakes with ultrafast Li⁺ transfer[J]. Chemical Communications, 2021, 57 (66): 8151- 8153. doi: 10.1039/D1CC01601F
52	SHAO Y , YUE J , SUN S , et al. Facile synthesis of FeS₂ quantum-dots/functionalized graphene-sheet composites as advanced anode material for sodium-ion batteries[J]. Chinese Journal of Chemistry, 2017, 35 (1): 73- 78. doi: 10.1002/cjoc.201600637
53	YAN Z , LIU J , WEI H , et al. Embedding FeS nanodots into carbon nanosheets to improve the electrochemical performance of anode in potassium ion batteries[J]. Journal of Colloid and Interface Science, 2021, 593, 408- 416. doi: 10.1016/j.jcis.2021.03.015
54	LEE S , KIM S , GIM J , et al. Ultra-small ZnS quantum dots embedded in N-doped carbon matrix for high-performance Li-ion battery anode[J]. Composites: Part B, 2022, 231, 109548. doi: 10.1016/j.compositesb.2021.109548
55	QI Y , YANG Y , HOU Q , et al. Uniform-dispersed ZnS quantum dots loading on graphene as a promising anode for potassium-ion batteries[J]. Chinese Chemical Letters, 2021, 32 (3): 1117- 1120. doi: 10.1016/j.cclet.2020.08.030
56	ZHANG P , CAO M , FENG Y , et al. Uniformly growing Co₉S₈ nanoparticles on flexible carbon foam as a free-standing anode for lithium-ion storage devices[J]. Carbon, 2021, 182, 404- 412. doi: 10.1016/j.carbon.2021.06.032
57	WANG M , PENG A , XU H , et al. Amorphous SnSe quantum dots anchoring on graphene as high performance anodes for battery/capacitor sodium ion storage[J]. Journal of Power Sources, 2020, 469, 228414. doi: 10.1016/j.jpowsour.2020.228414
58	HUANG Z X , LIU B , KONG D , et al. SnSe₂ quantum dot/rGO composite as high performing lithium anode[J]. Energy Storage Materials, 2018, 10, 92- 101. doi: 10.1016/j.ensm.2017.08.008
59	HUSSAIN N , LI M , TIAN B , et al. Co₃Se₄ quantum dots as an ultrastable host material for potassium-ion intercalation[J]. Advanled Materials, 2021, 33 (26): 2102164. doi: 10.1002/adma.202102164
60	SHI S , SUN C , YIN X , et al. FeP quantum dots confined in carbon-nanotube-grafted P-doped carbon octahedra for high-rate sodium storage and full-cell applications[J]. Advanced Functional Materials, 2020, 30 (10): 1909283. doi: 10.1002/adfm.201909283
61	YAN Z , HUANG Z , ZHOU H , et al. Facile fabrication of MoP nanodots embedded in porous carbon as excellent anode material for potassium-ion batteries[J]. Journal of Energy Chemistry, 2021, 54, 571- 578. doi: 10.1016/j.jechem.2020.06.037
62	YAN Z , HUANG Z , YAO Y , et al. Monodispersed Ni₂P nanodots embedded in N, P co-doped porous carbon as super stable anode material for potassium-ion batteries[J]. Journal of Alloys and Compounds, 2021, 858, 158203. doi: 10.1016/j.jallcom.2020.158203
63	MA X , JI C , YU X , et al. A covalent heterostructure of metal phosphide quantum dots anchored in N, P co-doped carbon nanocapsules for fast and durable lithium storage[J]. ACS Applied Materials and Interfaces, 2021, 13 (45): 53965- 53973. doi: 10.1021/acsami.1c16730
64	MURALIDHARAN P , YUN J H , PONRAJ R , et al. Melamine-assisted synthesis of vanadium nitride quantum dots: application for full-cell lithium-ion batteries[J]. Journal of Alloys and Compounds, 2021, 888, 161522. doi: 10.1016/j.jallcom.2021.161522
65	ZENG F , LU T , HE W , et al. In-situ carbon encapsulation of ultrafine VN in yolk-shell nanospheres for highly reversible sodium storage[J]. Carbon, 2021, 175, 289- 298. doi: 10.1016/j.carbon.2021.01.025
66	WU H , YU Q , LAO C Y , et al. Scalable synthesis of VN quantum dots encapsulated in ultralarge pillared N-doped mesoporous carbon microsheets for superior potassium storage[J]. Energy Storage Materials, 2019, 18, 43- 50. doi: 10.1016/j.ensm.2018.09.025
67	YI H , HUANG Y , SHA Z , et al. Facile synthesis of Mo₂N quantum dots embedded N-doped carbon nanosheets composite as advanced anode materials for lithium-ion batteries[J]. Materials Letters, 2020, 276, 128205. doi: 10.1016/j.matlet.2020.128205
68	ZHENG C , LUO N , HUANG S , et al. Nanocomposite of Mo₂N quantum dots@MoO₃@nitrogen-doped carbon as a high-performance anode for lithium-ion batteries[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (12): 10198- 10206.
69	MIN H , ZHANG X , SHU H , et al. Mo₂C quantum dots inlaid in nitrogen-doped carbon nanofibers as free-standing anodes with long-term stability K-ion storage[J]. Journal of Alloys and Compounds, 2021, 888, 161498. doi: 10.1016/j.jallcom.2021.161498
70	WU H , ZHANG Z , QIN M , et al. Tuning vacancy and size of metallic VC_x quantum dots for capacitive potassium-ion batteries[J]. Chemical Engineering Journal, 2021, 404, 126315. doi: 10.1016/j.cej.2020.126315
71	YANG L , YANG B , CHEN X , et al. Bimetallic alloy SbSn nanodots filled in electrospun N-doped carbon fibers for high performance Na-ion battery anode[J]. Electrochimica Acta, 2021, 389, 138246. doi: 10.1016/j.electacta.2021.138246
72	ESFANDIARI A , HAGHIGHAT S S , NAZARIAN S M , et al. Defect-rich Ni₃Sn₄ quantum dots anchored on graphene sheets exhibiting unexpected reversible conversion reactions with exceptional lithium and sodium storage performance[J]. Applied Surface Science, 2020, 526, 146756. doi: 10.1016/j.apsusc.2020.146756
73	WANG B , XIE Y , LIU T , et al. LiFePO₄ quantum-dots composite synthesized by a general microreactor strategy for ultra-high-rate lithium ion batteries[J]. Nano Energy, 2017, 42, 363- 372. doi: 10.1016/j.nanoen.2017.11.040
74	JIN T , LIU Y , LI Y , et al. Electrospun NaVPO₄F/C nanofibers as self-standing cathode material for ultralong cycle life Na-ion batteries[J]. Advanced Energy Materials, 2017, 7 (15): 1700087. doi: 10.1002/aenm.201700087
75	ZHANG Q , ZHANG X , HE W , et al. In situ fabrication of Na₃V₂(PO₄)₃ quantum dots in hard carbon nanosheets by using lignocelluloses for sodium ion batteries[J]. Journal of Materials Science & Technology, 2019, 35 (10): 2396- 2403.
76	陶丽华, 蔡燕, 李在均, 等. 石墨烯/CdS量子点复合材料的电化学性能研究[J]. 无机材料学报, 2011, 26 (9): 912- 916.
76	TAO L H , CAI Y , LI Z J , et al. Electrochemical properties of graphene/CdS quantum dot composites[J]. Journal of Inorganic Materials, 2011, 26 (9): 912- 916.
77	ZHAO W , MA X , LI Y , et al. Achieving ultrastable cyclability and pseudocapacitive sodium storage in SnSe quantum-dots sheathed in nitrogen doped carbon nanofibers[J]. Applied Surface Science, 2020, 504, 144455. doi: 10.1016/j.apsusc.2019.144455
78	LIU Z , HAN K , LI P , et al. Tuning metallic Co_0.85Se quantum dots/carbon hollow polyhedrons with tertiary hierarchical structure for high-performance potassium ion batteries[J]. Nanomicro Lett, 2019, 11 (1): 96.
79	王利霞, 张振华, 李雷, 等. Mo₂N量子点@N-掺杂石墨烯复合材料的制备及储锂性能[J]. 化工学报, 2020, 71 (12): 5854- 5862.
79	WANG L X , ZHANG Z H , LI L , et al. Preparation and lithium storage properties of Mo₂N quantum dots@nitrogen-doped graphene composite[J]. CIESC Journal, 2020, 71 (12): 5854- 5862.
80	LIU Z , ZHANG S , QIU Z , et al. Tin nanodots derived from Sn²⁺/graphene quantum dot complex as pillars into graphene blocks for ultrafast and ultrastable sodium-ion storage[J]. Small, 2020, 16 (38): 2003557. doi: 10.1002/smll.202003557
81	HUANG M , XI B , SHI N , et al. Quantum-matter Bi/TiO₂ heterostructure embedded in N-doped porous carbon nanosheets for enhanced sodium storage[J]. Small Structures, 2020, 2 (4): 2000085.
82	GUO Q , MA Y , CHEN T , et al. Cobalt sulfide quantum dot embedded N/S-doped carbon nanosheets with superior reversibility and rate capability for sodium-ion batteries[J]. ACS Nano, 2017, 11 (12): 12658- 12667. doi: 10.1021/acsnano.7b07132
83	HUANG S , WANG M , JIA P , et al. N-graphene motivated SnO₂@SnS₂ heterostructure quantum dots for high performance lithium/sodium storage[J]. Energy Storage Materials, 2019, 20, 225- 233. doi: 10.1016/j.ensm.2018.11.024
84	LIU W , YUAN J , HAO Y , et al. Heterogeneous structured MoSe₂-MoO₃ quantum dots with enhanced sodium/potassium storage[J]. Journal of Materials Chemistry A, 2020, 8 (44): 23395- 23403. doi: 10.1039/D0TA08674F

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